• Journal of the Korean Chemical Society
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• v.9 no.4
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• pp.211-214
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• 1965

The partition function of liquid methyl chloride and methyl bromide are developed by applying the significant structure theory of liquid.$^{(1-3)}$ The parameters therein are determined by the modified significant structure theory of liquid.$^{(4)}$ The molar volume, the vapor pressure, and the entropy of vaporization of the liquids are calculated over a wide temperature range. The critical properties for the liquids are also calculated. The results show good agreement with experimental observations.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.11 no.9
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• pp.693-699
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• 1998

In this work $Cd_4GeS_6:Co^{2+}$(0.5mole%) single crystals were grown by the chemical transporting reactiov(CTR) method using high purity(6N) elements. The grown single crystals crystallized in a monoclinic structure(space group Cc). The direct optical energy gap of this single crystals was found to be 2.445eV at 300K and the temperature dependence of optical energy gap was fitted well to Varshni equation. But at temperatures lower than 70K an anomalous temperature dependence of the optical energy gap was obtained. This anomalous temperature dependence accored well with the anomalous temperature dependence of the unit cell volume. Also, the entropy, enthalpy and heat capacity were deduced from the temperature dependence of optical energy gaps.

• Journal of the Korean Chemical Society
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• v.8 no.2
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• pp.65-67
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• 1964

The partition function of liquid fluorine were developed by applying the theory of significant structures in liquids. The molar volume, vapor pressure, entropy of vaporization and surface tension of the liquid were calculated over a wide temperature range. The critical properties for the liquid were also calculated. The results show good agreement with experimental observations.

• Nuclear Engineering and Technology
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• v.12 no.3
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• pp.180-193
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• 1980

Subroutines to enable fast and accurate generation of water properties-enthalpy, specific volume, viscosity, thermal conductivity and saturation entropy-which are usually basic requirements for nuclear calculation of LWR, have been developed. The sources of data were quoted from “ASME Steam Tables (1967)” and their Revision (1975). It is ensured that the obtained values from this routine fall within 0.2% difference compared with the reference data, in the ranges of temperature and pressure for LWR nuclear calculation.

• Bulletin of the Korean Chemical Society
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• v.2 no.3
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• pp.90-96
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• 1981

The significant structure theory of liquids has been successfully applied to the sodium ammonia solution. In applying the theory to sodium ammonia solution, we assumed there were four species in solution, i.e., sodium cation, solvated electron, triple ion, and free electron and equilibria existed between them. Based on these assumptions, we set up the model explaining the anomalous properties of sodium ammonia solution. The partition function for sodium ammonia solution is composed of the partition functions for the above four species and also for the Debye-Huckel excess free energy term. Agreements between calculated and experimental values of the thermodynamic quantities, such as molar volume, vapor pressure, partial molar enthalpy and entropy, and chemical potential as well as viscosity are quite satisfactory.

• Bulletin of the Korean Chemical Society
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• v.12 no.5
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• pp.495-499
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• 1991

The changes in the free energy and hydration free energy of N-acetyl-N'-methylalaninamide in the unhydrated and hydrated states were calculated with ECEPP/2 and the hydration shell model. The configurational entropy change of each conformation in both states were computed by a harmonic method. To understand the hydration structure of each hydrated conformation, the hydration-shell coordination numbers of functional. groups of the molecule were estimated from water-accessible volumes, and the contributions of water-accessible volume and polarization of each group to the hydration free energy were analyzed. The results show a reasonable agreement with those of recent theoretical studies and experiments.

• Bulletin of the Korean Chemical Society
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• v.20 no.10
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• pp.1209-1212
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• 1999

The entropies and chemical potentials of hard-sphere solutes solvated in hard-sphere solids were calculated by Monte Carlo method using the radial free-space distribution function. This method is based on calculating the entropy by comparing the free volume of a molecule with that of an ideal gas, and is applicable even when the size of solute is very large and the solvent is a solid. When the diameter of hard-sphere solute is small the solute molecule behaves as like as a fluid in solid structures, but when the diameter of solute becomes large, a fluid-to-solid phase transition takes place. The fluid-to-solid phase transition occurs at the region of the smaller size of solute with the more increase of solvent density. The least square fit values of analytical form of the radial free-space distribution functions of solute molecules are presented for future uses.

• The Magazine of the Society of Air-Conditioning and Refrigerating Engineers of Korea
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• v.16 no.5
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• pp.477-483
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• 1987

A FORTRAN code has been developed to calculate thermodynamic properties of 12 kinds of refrigerants. Input variables are temperature and pressure or temperature only depending on the saturation. The program output properties are specific volume, saturation pressure, enthalpy, entropy, specific heats and speed of sound. Sample calculations show that output properties are in very good agreements with thermodynamic tables and charts.

• Korean Journal of Remote Sensing
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• v.28 no.1
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• pp.21-28
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• 2012

In this study, detection of icebergs that have various scattering characteristics around Wilkinson glacier in West Antarctica is investigated using C-band fully-polarimetric RADARSAT-2 SAR data. Various polarimetric analyses including Freeman-Durden decomposition, H/A/$\bar{\alpha}$ decomposition, entropy (H) and anisotropy (A) method, and Wishart unsupervised classification, were applied for the RADARSAT-2 data used in this study. The polarimetric decomposition methods were successfully classified most of the iceberg, yet some iceberg with similar intensity of volume and surface scattering as sea ice were indistinguishable. Unsupervised classification with a combination of the polarimetric parameter, [1-H][1-A], gave a possibility to distinguish those unclassified iceberg.

• Journal of Biomedical Engineering Research
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• v.10 no.3
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• pp.253-260
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• 1989

The time domain methods of estimating the attenuation coefficient are generally based on the analysis of statisical properties of the reflected echoes form an attenuating medium. Hence, it is often required to have a large number of data samples in order to obtain a statistically stable estimation result. In the attenuation estimation problem, this means that many different speckle patterns are required in the spatial resolution volume of an attenLlation image. In this paper, by using the fact that the speckle pattern Is sensitive to the point spread function of the ultrasound beam, we suggest a method to generate the statiscally uncorrelated or slightly correlated data samples in a given region by rotating a linear transducer and carrying out lateral scans for all rotating angles. This technique is applied to the entropy method for attenuation estimation proposed recently by the authors where the performance is verified by experiments using a tissue equivalent phantom.