• Food Science and Preservation
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• v.6 no.2
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• pp.200-205
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• 1999

This experiment was carried out to search mm reasonable and scientific method to distinguish Korean sesame with Chinese sesame. Sesame samples used in this study were Korean variety cultivated in Chochiwon City of Korea (KvKc), Chinese variety cultivated in Jilin Province of China (CvCc), Chinese variety cultivated in Chochiwon city of Korea (CvKc) and Korean variety cultivated in Jilin Province of China (KvCc). In volatile flavor components analysis, 41 component were identified from KvKc and 39 components from CvCc. Major flavor components were pyrazines and furans. Pyrazines compositions of KvKc and CvCc were 55.4% and 56.8%, respectively while furans compositions of KvKc and CvCc were 27.0% and 20.4%, respectively. Other flavor components pattern showed no difference. When the headspace volatiles of sesame oils were analyzed using Electronic Nose System and the obtained data were interpreted using statistical method of MANOVA and Discriminant analysis, characteristic patterns of sesame oil odors were different from each other according to variety as well as cultivated area. These results suggest that Korean sesame oils may be distinguished from Chinese sesame oils by using Electronic Nose System.

• Journal of Korean Society for Atmospheric Environment
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• v.32 no.3
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• pp.320-328
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• 2016

Among biogenic volatile organic compounds (BVOCs) in the natural ecosystem, monoterpenes, along with isoprene, play important roles in atmospheric chemistry and make significant impacts on air pollution and climate change, especially due to their contribution to secondary organic aerosol production and photochemical ozone formation. It is essential to measure monoterpene concentrations accurately for understanding their oxidation processes, emission processes and estimation, and interactions between biosphere and atmosphere. Thus, traceable calibration standards are crucial for the accurate measurement of monoterpenes at ambient levels. However, there are limited information about developing calibrations standards for monoterpenes in pressured cylinders. This study describes about developing primary standard gas mixtures (PSMs) for monoterpenes at about 2 nmol/mol, near ambient levels. The micro-gravimetric method was applied to prepare monoterpene (${\alpha}$-pinene, 3-carene, R-(+)-limonene, 1,8-cineole) PSMs at $10{\mu}mol/mol$ and then the PSMs were further diluted to 2 nmol/mol level. To select an optimal cylinder for the development of monoterpene PSMs, three different kinds of cylinders were used for the preparation and were evaluated for uncertainty sources including long-term stability. Results showed that aluminum cylinders with a special internal surface treatment (Experis) had little adsorption loss on the cylinder internal surface and good long-term stability compared to two other cylinder types with no treatment and a special treatment (Aculife). Results from uncertainty estimation suggested that monoterpene PSMs can be prepared in pressured cylinders with a special treatment (Experis) at 2 nmol/mol level with an uncertainty of less than 4%.

• Proceedings of the Korean Environmental Health Society Conference
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• 2005.06a
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• pp.254-258
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• 2005

The purpose of this study is to characterize the indoor-outdoor relationship of airborne pollutants and recognize probable sources in inside and outside individual apartments in Seoul metropolitan. Simultaneous air monitoring in inside and outside of the 16 Korean Apartments classified into 2groups: less than 1 year old and more than 4 years old from October, 2004 to February, 2005were sampled f3r airborne pollutants(volatile organic compounds, formaldehyde, respiratory particles, carbon dioxide and bacteria) using the Korean Indoor Air Quality Official Method. The concentrations of $CO_2$, TVOCs, HCHO, bacteria and PM10 in the less than 1 year old apartments were determined to be $773.6{\pm}422.3ppm$, $4,393.8{\pm}2,758.2{\mu}g/m^3$, $98.0{\pm}56.4{\mu}g/m^3$, $254.0{\pm}186.3CFU/m^3$ and $31.7{\pm}14.8{\mu}g/m^3$, respectively, Also, the concentrations of those in the more than 4 years old apartments were determined to be $798.9{\pm}266.5ppm$, $792.7{\pm}398.3{\mu}g/m^3$, $70.0{\pm}30.7{\mu}g/m^3$, $245.6{\pm}122.0CFU/m^3$, $49.7f28.7{\pm}g/m^3$, respectively. The average ratios of the indoor and outdoor concentrations of $CO_2$, TVOCs, HCHO, bacteria and PM10 were 2.2, 3.6, 3.1, 3.9 and 1.4, respectively. These results of this analysis is suggested that $CO_2$, TVOCs, HCHO, bacteria and PM10 in indoor air are both emitted from source within the apartment environment and partly come from outdoor air. With the above considerations in mind, it is suggested that the research for source contribution of indoor air pollutants should be expanded and the detailed interpretation of the results on these needed further study(using principal component analysis(PCA).

• Journal of the Korea Organic Resources Recycling Association
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• v.23 no.4
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• pp.86-94
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• 2015

Torrefaction is a thermochemical process proceeded at the temperature around $250^{\circ}C$ in an inert gas condition. By torrefaction, the hemicellulose portions contained in biomass are broken down to change into the volatile gas which is removed from biomass eventually. The main purpose of biomass torrefaction is to improve the energy density of the biomass to minimize the transport energy consumption, though the flammability can be elevated for transportation. In this study two types of solid biomass fuel, waste wood and rice straw, were torrefied at various temperature range from $200^{\circ}C$ to $300^{\circ}C$ to evaluate the torrefied biomass characteristics. In addition torrefied biomass were tested to evaluate the combustion characteristics using TGA (Thermogravimetric Analysis). After the torrefaction of biomass, the C/H (carbon to hydrogen ratio) and C/O (carbon to oxygen ratio) were measured for aquisition of bio-stability as well as combustion pattern. Generally C/H ratio implies the soot formation during combustion, and the C/O ratio for bio-stability. By torrefaction temperature at $300^{\circ}C$, C/H ratio and C/O ratio were increased by two times for C/H and three times for C/O. The torrefied biomass showed similar TGA pattern to coal compared to pure biomass; that is, less mass decrease at lower temperature range for torrefied biomass than the pure biomass.

• Microbiology and Biotechnology Letters
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• v.44 no.3
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• pp.400-407
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• 2016

A unicellular green alga, Chlorella vulgaris KNUA027, was isolated from the roots of Panax ginseng seedlings and its biotechnological potential was investigated. The results of GC/MS analysis showed that C. vulgaris KNUA027 was rich in nutritionally important polyunsaturated fatty acids (PUFAs) such as alpha-linolenic acid (C_18:3 ω3, 45.8%, 50.8 mg/g) and hexadecatrienoic acid (C_16:3 ω3, 11.8%, 13.1 mg/g). Therefore, this Korean indigenous microalga may have potential as a source of omega-3 PUFAs. It was also found that the saturated palmitic acid (C_16:0, 37.1%, 41.2 mg/g), which is suitable for biodiesel production, was one of the major fatty acids produced by strain KNUA027. The proximate analysis showed that the volatile matter content was 88.5%, and the ultimate analysis indicated that the higher heating value was 19.8 MJ/kg. Therefore, the results from this research with C. vulgaris KNUA027 may provide the basis for the production of microalgae-based biofuels and biomass feedstock.

• Journal of The Korean Society of Agricultural Engineers
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• v.62 no.2
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• pp.17-29
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• 2020

The objective of this study was to find an optimum methane yield condition in anaerobic digestion of sewage sludge with microwave pretreatment. The pretreatment process was carried out using a lab scale industrial microwave unit (2,450 MHz frequency). The digestion efficiency of pretreated sludge was evaluated by biochemical methane potential (BMP) test. Box-Behnken design and Response Surface Analysis (RSA) were applied to determine the optimal combination of sludge mixing ratio (0 to 100%), power (400 to 1600 W), holding time (0 to 10 min) and pretreatment temperature (60 to 100℃). BMP test results showed that Volatile Solid (VS) removal efficiency was up to 48% at a condition of 0% for mixing ratio, 1600 W for power, 5 min for holding time, and 80℃ for pretreatment temperature. Methane production was up to 832.3 mL/g VS_removed at a condition of 50% for mixing ratio, 1000 W for power, 5 min for holding time, and 80℃ for pretreatment temperature. The results of the variance analysis (ANOVA) showed that the p-value of the power and pretreatment temperature among the independent variables were significant (p<0.05), and in particular, the pretreatment temperature significantly affected on the solubilization and methane production. The optimum condition for the maximum methane yield (847 mL/g VS_removed) was consist of 38.4% of mixing ratio, 909.1 W of power, 4.1 min of holding time, and 80℃ of temperature within the design boundaries.

• Analytical Science and Technology
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• v.27 no.2
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• pp.108-113
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• 2014

The harmful materials as volatile organic compounds (VOCS) that is easy for gas to be changed from liquid on ambient temperature, those should be controlled by Korea Chemicals Management Association. The VOCs samples should be collected directly in place so that those could be analyzed. Generally but it couldn't avoid to have the risk of analyst. Moreover, if there is the place limited to entrance, it is impossible to collect directly and measure. Owing to such problem, it tried to be solved by open path FT-IR spectrometer that could be studied on the combustion gases within long path and VOCs samples were tried to measure to large volume by remote and real time. Firstly, it was to investigate optimized measured length between the system and benzene sample of VOCs. As result, The optimized measured length was confirmed with 15 meter length and the qualitative analysis could be measured on seven VOC samples. The calibration curve as quantitative analysis of benzene samples could be worked. On the basis of the result, the system as remote monitor could show to have potentiality.

• Korean Chemical Engineering Research
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• v.47 no.2
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• pp.230-236
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• 2009

Sewage sludge cake(SSC) is seriously concerned because ocean dumping, which is the cheapest treatment method now, will be banned in 2012. On the basis of this reason, recycling of SSC is emphasized to convert the treatment method. One of the method to recycling SSC could be carbonization process which also can be reduced greenhouse gas effectively. And carbonization residue of SSC produced by carbonization process can become a renewable energy source. However, carbonization process has not been evaluated by considering basic operating data such as heating value, yield and fuel ratio. In this study, the basic characteristics of SSC such as proximate analysis, elementary analysis and heating value are analyzed. In carbonization process, the effect of carbonization temperature and time on the residue of SSC are estimated. And the analysis is carried out to obtain basic properties of the residue of SSC. From the result of chemical composition of SSC residue, there is 27% of phosphate in SSC. Phosphate will take a role of reductant to convert from hazardous substance to non-hazardous material. As increased carbonization temperature and time, heating value and yield are decreased but fuel ratio(fixed carbon/volatile combustible) of the residue is increased. In the carbonization process, the optimum temperature and time in carbonization test for SSC can be decided by $250^{\circ}C$ and 15 min, respectively. However, the carbonization residue of SSC can not be deserved to use one of renewable energy sources because the heating value at the optimum condition is relatively low. Hence, it is desirable that SSC can be mixed with other organic waste to carbonize.

• Journal of the Korean Society of Food Science and Nutrition
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• v.35 no.6
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• pp.761-767
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• 2006

To determine freshness and quality change of chicken products during storage, we manufactured freshness indicator and monitored the surface pH, volatile basic nitrogen (VBN), thiobarbituric acid reacted substance (TBARS), total bacterial counts, electronic nose analysis, and sensory evaluation. All chicken products (drum, wing, thigh) had a change in color of freshness indicator after storage of 3 days at $4^{\circ}C$, indicating poor quality at the time. VBN, TBARS values, and total bacterial counts reached the decay point at the time of color change of freshness indicator attached to the surface of chicken samples. The sensory evaluation also indicated sample was not acceptable by off-odor at day 4 of storage. According to electronic nose analysis to examine off-odor, there were significant differences in terms of principal component analysis values among chicken samples of day 0, day 3, and day 5 of storage. These results suggest that freshness indicator should be useful in determining expiration date of chicken products during marketing by indicating the microbial safety as well as physicochemical and sensory change.

• Korean Journal of Food Science and Technology
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• v.5 no.3
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• pp.183-187
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• 1973

Soong-Neung is a Korean traditional beverage served after meals and is made from Soong-Neung producing rice (Noo-Roon-Bap) which is cooked and toasted rice produced on the bottom of the container during the rice cooking process. In order to study the chemical changes occurring in Soong-Neung producing rice with temperature$(20{\sim}220^{\circ}C)$ during the cooking process, thermal analysis, total sugars, total nitrogen, reducing sugars, water soluble nitrogen, total acid, carbonyl content, phenolic compounds were determined. Thermal analysis showed that decrease of weight and endothermic reaction caused by evaporation of water in the sample appeared at $95{\sim}130^{\circ}C.$ The production of volatile compounds increased gradually beginning at $130^{\circ}C$, however, those compounds increased markedly at $160^{\circ}C$ and above. Maximum absorption of ultraviolet spectra of an aqueous distillate occurred at about $273m{\mu}$. Organoleptic analysis showed that an acceptable flavor was produced in the temperature range of $125{\sim}155^{\circ}C.$