• Analytical Science and Technology
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• v.24 no.6
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• pp.493-502
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• 2011

The catalyst works for visible-light region was characterized. Toluene, xylene, MEK and ammonia were used as reactants. The decomposition efficiency was compared between visible-light photocatalyst and UV-light one. UV-photocatalyst can be activated with UV-light wave length of 280~360 nm. However, visible-light photocatalyst can be activated with visible wave length of 400~750 nm. This result was found by using UV-Vis absorbance. A lot of materials were doped to visible light photocatalyst in order to increase its performance. Platinum was added to visible light photocatalyst with manganese in order to increase performance of the visible light photocatalyst. MTMS (Methyl tri methoxy silane) was used as a binder. Contact angle was analyzed varying with amount of binder. Contact angle was increased with increasing the amount of MTMS. As a result, the hydrophilic property of photocatalyst with MTMS binder was decreased due to its hydrophobic one. And Mn-$TiO_2$ catalyst had an excellent anti-bacterial property.

• Clean Technology
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• v.18 no.4
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• pp.419-425
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• 2012

This work explored the characteristics and the photocatalytic activities of S element-doped $TiO_2$ (S-$TiO_2$) and N element-doped $TiO_2$ (N-$TiO_2$) for the decomposition of gas-phase isopropyl alcohol (IPA) at sub-ppm concentrations, using a plug-flow reactor irradiated by 8-W daylight lamp or visible light-emitting-diodes (LEDs). In addition, the generation yield of acetone during photocatalytic processes for IPA at sub-ppm levels was examined. The surface characteristics of prepared S- and N-$TiO_2$ photocatalysts were analyzed to indicate that they could be effectively activated by visible-light irradiation. Regarding both types of photocatalysts, the cleaning efficiency of IPA increased as the air flow rate (AFR) was decreased. The average cleaning efficiency determined via the S-$TiO_2$ system for the AFR of 2.0 L $min^{-1}$ was 39%, whereas it was close to 100% for the AFR of 0.1 L $min^{-1}$. Regarding the N-$TiO_2$ system, the average cleaning efficiency for the AFR of 2.0 L $min^{-1}$ was above 90%, whereas it was still close to 100% for the AFR of 0.1 L $min^{-1}$. In contrast to the cleaning efficiencies of IPA, both types of photocatalysts revealed a decreasing trend in the generation yields of acetone with decreasing the AFR. Consequently, the N-$TiO_2$ system was preferred for cleaning of sub-ppm IPA to S-$TiO_2$ system and should be operated under low AFR conditions to minimize the acetone generation. In addition, 8-W daylight lamp exhibited higher cleaning efficiency of IPA than for visible LEDs.

• Journal of Environmental Science International
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• v.27 no.11
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• pp.967-974
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• 2018

In this study, we evaluated the photocatalytic oxidation efficiency of aromatic volatile hydrocarbons by using $WO_3$-doped $TiO_2$ nanotubes (WTNTs) under visible-light irradiation. One-dimensional WTNTs were synthesized by ultrasonic-assisted hydrothermal method and impregnation. XRD analysis revealed successful incorporation of $WO_3$ into $TiO_2$ nanotube (TNT) structures. UV-Vis spectra exhibited that the synthesized WTNT samples can be activated under visible light irradiation. FE-SEM and TEM images showed the one-dimensional structure of the prepared TNTs and WTNTs. The photocatalytic oxidation efficiencies of toluene, ethylbenzene, and o-xylene were higher using WTNT samples than undoped TNT. These results were explained based on the charge separation ability, adsorption capability, and light absorption of the sample photocatalysts. Among the different light sources, light-emitting-diodes (LEDs) are more highly energy-efficient than 8-W daylight used for the photocatalytic oxidation of toluene, ethylbenzene, and o-xylene, though the photocatalytic oxidation efficiency is higher for 8-W daylight.

• KSII Transactions on Internet and Information Systems (TIIS)
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• v.8 no.4
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• pp.1276-1291
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• 2014

In the field of visible light communication (VLC), light-emitting diodes (LEDs) are used for transmitting data via visible light. In this study, we analyze pulse dual slope modulation (PDSM) as a means of delivering information in VLC. PDSM involves the modulation of symmetrical slope pulses to encode binary 0s and 1s, and owing to the moderately increasing and decreasing pulse shapes that are created, this method enables more spectral efficiency than the variable pulse position modulation (VPPM) technique currently adopted in IEEE 802.15.7. In particular, PDSM allows for the avoidance of intra-frame flicker by providing idle pulses in a spectrum-efficient way. A simple detection scheme is proposed for PDSMsignals, and its bit error rate (BER) is analyzed mathematically at varying slopes to validate the process through simulation. The BER performance of PDSM detection using dual sampling is compared to the performances of PDSM and VPPM using correlation detection. It is found that, when the probability of idle pulse transmission is less than 0.08 and higher than 0, the BER of dual sampling PDSM is lower than that of PDSM using correlation detection over the entire light intensity range.

• Korean Chemical Engineering Research
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• v.61 no.4
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• pp.627-634
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• 2023

Graphitic carbon nitride (g-C₃N₄) has attracted considerable attention since its discovery for its catalysis of water splitting to hydrogen and oxygen under visible light irradiation. However, pristine g-C₃N₄ confers only low photocatalytic efficiency and requires surface cocatalysts to reach moderate activity due to a lack of accessible surface active sites. Inspired by the high specific surface area and superior electron transfer of graphene, we developed a strongly coupled binary structure of graphene and g-C₃N₄ aerogel with 3D porous skeleton. The as-prepared 3D structure photocatalysts achieve a high surface area that favors efficient photogenerated charge separation and transfer, enhances the light-harvesting efficiency, and significantly improves the photocatalytic hydrogen evolution rate as well. The photocatalyst performance is observed to be optimized at the ratio 3:7 (g-C₃N₄:GO), leading to photocatalytic H₂ evolution of 16125.1 mmol. g^-1. h^-1 under visible light irradiation, more than 161 times higher than the rate achieved by bulk g-C₃N₄.

• The Transactions of the Korean Institute of Electrical Engineers C
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• v.50 no.9
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• pp.444-449
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• 2001

In this paper, a novel ultraviolet sensor is presented based on a photoluminescent porous silicon. Porous silicon layer was formed by chemical etching of surface of pn junction in a $HF(48%)-HNO_3(60%)-H_20$ solution. Incident ultraviolet(UV) light is converted to visible light by photoluminescent porous silicon layer, and then this visible light generates electron-hole pairs in the pn junction, which produces a photocurrent flow through the device. In order to maximize detection efficiency, the peak sensitivity wavelength of the pn junction diode was matched with the peak wavelength of Photoluminescence from porous silicon layer. The porous silicon ultraviolet sensor showed a large output current as UV intensity increases and but very low sensitivity to visible light. The detection sensitivity of porous silicon sensor was calculated as 2.91mA/mW. These results are expected to open up a possibility that the present porous silicon sensor can be used for detecting UV light in a visible background, compared to silicon UV detectors which have an undesirable response to visible light.

• Transactions on Electrical and Electronic Materials
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• v.11 no.5
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• pp.238-241
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• 2010

The purpose of this study is to solve the problems of radio frequency bandwidth frequency depletion, confusion possibilities, and security that are in current wireless communications systems, and to confirm the possibility of applying those solutions for the next generation network. To solve the problems of the current wireless communications system, a visible light communications system for power line communication (PLC) via 8-bit microcontroller is created and the capacity is analyzed. The exclusive PLC chip APLC-485MA, an 8-bit ATmega16 microcontroller, high brightness 5pi light emitting diodes (LEDs), and the LLS08-A1 visible light-receiving sensor were used for the transmitter and receiver. The performance was analyzed using a designed program and an oscilloscope. The voltage change was measured as a function of distance from 10-50 cm. Blue LEDs showed the best performance among the measured LED types, with 0.47 V of voltage loss, but for a distance over 50 cm, precise data was not easy to obtain due to the weak light. To overcome these types of problems, specific values such as the changing conditions and efficiency value relevant to the light emitting parts and the visible light-receiving sensor should be calculated, and continuous study and improvements should also be realized for better communication conditions.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.59 no.11
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• pp.2043-2047
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• 2010

This study is to solve problems of depletion of RF bandwidth frequency, confusion possibility, security that current wireless communications system have and is to confirm possibility of applying next generation network. To solve problems of current wireless communications system, visible light communications system for power line communications using ATmega16 Microcontroller is was realized and receiver property was analyzed. PLC exclusive chip APLC-485MA, Microcontroller ATmega16, 5pi bulb type LED and high flux LED, visible light receiving sensor LLS08-A1 were used for transmitter and receiver. Performance was analyzed by designed program and an oscilloscope. It was showed average 20% improved receiver rate rather than bulb type LED in the case of high flux LED through voltage change rate on communication distance and LED type of distance between 10 to 50 cm. The blue LED showed the best performance among measured LED types with above 10% of voltage decreasing rate. But As it gradually becomes more distant, the precise date was difficult to obtain due to weak light. To overcome these sort of problems, specific values such as changing conditions and efficiency value relevant to light emitting parts and visible light receiving sensor should be calculated and continuous study and improvements should also be accomplished for the better communications condition.

• Korean Journal of Materials Research
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• v.30 no.12
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• pp.641-649
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• 2020

A facile microwave assisted solvothermal process is designed for fabricating SnS nanoparticles decorated on graphene nanosheet, which used as visible light driven photocatalyst. Some typical characterization techniques such as XRD, FT-IR, SEM with EDX analysis, and TEM and BET analysis are used to analyse the physical characteristics of as-prepared samples. Spherical SnS nanoparticles are uniformly dispersed on the surface of graphene nanosheet due to ammonia, which can prevent the aggregation of graphene oxide. Meanwhile, microwave radiation provides fast energy that promotes the formation of spherical SnS nanoparticles within a short time. The visible light photocatalytic activity of as-prepared SnS-GR nanocomposites is analysed through photodegradation efficiency of methylene blue with high concentration. According to the higher photocatalytic property, the as-prepared SnS-GR nanocomposites can be expected to be an efficient visible light driven photocatalyst. After five cycles for decolorization, the rate decreases from 87 % to 78 % (about 9 %). It is obvious that the photocatalytic activity of SnS-GR nanocomposite has good repeatability.

• 한국정보디스플레이학회:학술대회논문집
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• 2008.10a
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• pp.887-890
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• 2008

We present 2D slab silicon-based photonic crystal optical insulator to enhance light emission efficiency of light-emitting diode (LED). A 2D slab silicon photonic crystal is designed in such a way that light emitting diode die can be placed in the middle of the silicon photonic crystal. The device creates light propagation forbidden region in horizontal plane for Transverse Electric (TE) light with the wavelength range of 450 nm to 600 nm.