• Title/Summary/Keyword: viscosity-evolution

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Development of Phenolic SMC for The Rail (철도차량 및 지하철 불연 내장재 페놀 SMC 개발)

  • Kim Young-keun;Shin Dong-hyok;Kim Young-min;Park Joung-wuk;Min Jae-Jun
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2004.04a
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    • pp.55-58
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    • 2004
  • Phenolin resin, prepared form phenol and formaldehyde, is one of the oldest thermosetting resins available. Phenolic resins are cured via condensation polymerization with evolution of water, which in molding process is a big problem. The use of phenolic resins in glass fiber composites is growing, primarily due to their low flame spread, low smoke generation and low smoke toxicity properties. SMC of phenolics has been rearched since the 1986. The technology challenge was to match resin viscosity, handling and cure with those for the polyester SMC to avoid any special processing for fabricators and end users. Phenolic SMC was chosen because of the ease of molding to the required shape with light- weight, thin wall structure and with excellent fire protection.

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Reactive Hot Melt Polyurethane Adhesives Modified by Acrylic Copolymer Nanocomposites

  • Cho, Youn-Bok;Jeong, Han-Mo;Kim, Byung-Kyu
    • Macromolecular Research
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    • v.17 no.11
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    • pp.879-885
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    • 2009
  • A macroazoinitiator (MAI) containing a poly(ethylene glycol) (PEG) segment was intercalated in the gallery of sodium montmorillonite (Na-MMT). Acrylic monomers were polymerized using this MAI intercalated in Na-MMT to prepare the acrylic copolymer nanocomposite (AN), which is a multiblock copolymer composed of two segments, an acrylic copolymer and PEG intercalated in Na-MMT (Na-MMT/PEG). When AN was used to modify the reactive hot melt polyurethane adhesive (RHA), the acrylic copolymer segment and Na-MMT/PEG synergistically enhanced the initial bond strength evolution and reduced the set time, even when the amount of Na-MMT in RHA was < 1 wt%. The viscosity of RHA increased and the tensile properties of the cured RHA film decreased due to modification with AN. These variations were more evident as the Na-MMT content in AN was increased.

Rheological Models for Describing Fine-laden Debris Flows: Grain-size Effect (세립토 위주의 토석류에 관한 유변학적 모델: 입자크기 효과)

  • Jeong, Sueng-Won
    • Journal of the Korean Geotechnical Society
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    • v.27 no.6
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    • pp.49-61
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    • 2011
  • This paper presents the applicability of rheological models for describing fine-laden debris flows and analyzes the flow characteristics as a function of grain size. Two types of soil samples were used: (1) clayey soils - Mediterranean Sea clays and (2) silty soils - iron ore tailings from Newfoundland, Canada. Clayey soil samples show a typical shear thinning behavior but silty soil samples exhibit the transition from shear thinning to the Bingham fluid as shear rate is increased. It may be due to the fact that the determination of yield stress and plastic viscosity is strongly dependent upon interstructrual interaction and strength evolution between soil particles. So grain size effect produces different flow curves. For modeling debris flows that are mainly composed of fine-grained sediments (<0.075 mm), we need the yield stress and plastic viscosity to mimic the flow patterns like shape of deposition, thickness, length of debris flow, and so on. These values correlate with the liquidity index. Thus one can estimate the debris flow mobility if one can measure the physical properties.

A study on Production of Al Foam by Using of Al Return Scrap for Sound and Vibration Absorption Materials

  • Hur, Bo-Young;Kim, Sang-Youl;Park, Dae-Chol;Jeon, Sung-Hwan;Park, Chan-Ho;Yoon, Ik-Sub
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.198-201
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    • 2001
  • Porous structures of aluminum foam have been studied by using return aluminum scrap. The apparent foam shape, foam height, density, pore size and their distributions in various section areas of the experimental samples have been investigated. The sample have been cast into metallic mold, using aluminum foam prepared from a precursor based on pure Al ingot and return aluminum scrap mixed with various amounts of 1-2wt% increasing viscosity and foam agent materials. The process provides for flexibility in design of foam structures via relatively easy control over the amount of hydrogen evolution and the drainage processes which occur during foam formation. This is facilitated by manipulating parameters such as the foaming agent, thermal histories during solidification and mix melt viscosities. A metal for producing the foamed are decomposing a foaming agent in a molten metal such that there is an initial and a subsequent expansion due to foaming agent. It has been found that the Al porous foaming with variation amount of 1∼2wt% foam agent and at 2min holding time, which melting temperature has appeared homogeneous pore size at 650∼700$^{\circ}C$. The compression strength were 10-13 kg/min at 125ppi, and increased by higher pore density. The acoustical performance of the panel made with the foamed aluminum is considerably improved; its absorption coefficient shows NRC 0.6-0.8. It has been found that the Al foam is very preferable for the compactness of the thermal system.

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Influence of Design Parameters of Grout Injection in Rock Mass using Numerical Analysis (암반 그라우팅 주입 설계변수가 주입성능에 미치는 영향의 수치해석적 평가)

  • Lee, Jong Won;Kim, Hyung Mok;Yazdani, Mahmoud;Park, Eui-Seob
    • Tunnel and Underground Space
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    • v.27 no.5
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    • pp.324-332
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    • 2017
  • In this paper, a numerical analysis of one-dimensional viscous fluid flow in a rock joint using UDEC code is performed to evaluate the effect of design parameters on injection performance. We consider injection pressure, fluid compressibility, time dependence of yield strength and viscosity of injected grout fluid, and mechanical deformation of joint as the design parameters, and penetration length and flow rate of injection are investigated as the injection performance. Numerical estimations of penetration length and flow rate were compared to analytical solution and were well comparable with each other. We showed that cumulative injection volume can be over-estimated by 1.2 times than the case that the time-dependent viscosity evolution is not considered. We also carried out a coupled fluid flow and mechanical deformation analysis and demonstrated that injection-induced joint opening may result in the increment of cumulative volume by 4.4 times of that from the flow only analysis in which joint aperture is kept constant.

A new geopolymeric grout blended completely weathered granite with blast-furnace slag

  • Zhang, Jian;Li, Shucai;Li, Zhaofeng;Li, Hengtian;Du, Junqi;Gao, Yifan;Liu, Chao;Qi, Yanhai;Wang, Wenlong
    • Advances in concrete construction
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    • v.9 no.6
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    • pp.537-545
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    • 2020
  • In order to reduce the usage of cement slurry in grouting engineering and consume the tunnel excavation waste soil, a new geopolymeric grouting material (GGM) was prepared by combine completely weathered granite (CWG) and blast-furnace slag (BFS), which can be applied to in-situ grouting treatment of completely weathered granite strata. The results showed CWG could participate in the geopolymerization process, and GGM slurry has the characteristics of short setting time, high flowability, low viscosity, high stone rate and high mechanical strength, and a design method of grouting pressure based on viscosity evolution was proposed. By adjusted the content of completely weathered granite and alkali activator concentration, the setting time of GGM were ranged from 5 to 30 minutes, the flowability was more than 23.5 cm, the stone rate was higher than 90%, the compressive strength of 28 days were 7.8-16.9 MPa, the porosity were below 30%. This provides a novel grouting treatment and utilizing excavated soil of tunnels in the similar strata.

Acoustic Abosrption Characteristic and Fabrication process of Foamed Aluminum (발포알루미늄의 제조공정 및 흡음특성)

  • Hur, Bo-Young;Ahn, Hyo-Jun;Jeon, Sung-Hwan;Choi, Dae-Choul;Kim, Sang-Youl;Hur, Yoon
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2000.11a
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    • pp.396-402
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    • 2000
  • Porous structures of aluminum foam have been studied. The apparent foam shape, foam hight, density, pore size, shape, and their distributions in various section areas of the experimental samples have been investigated. The sample have been cast into metallic mold, using aluminum foam prepared from a precursor based on pure Al ingot mixed with various amount of 1-2wt% increasing viscosity and foam agent materials. The process provides for flexibility in design of foam structures via relatively easy control over the amount of hydrogen evolution and the drainage processes which occur during foam formation. This is facilitated by manupulating parameters such as the foaming agent, thermal histories during solidification and mix melt viscosities. The acoustical performance of the panel made with the foamed aluminum is considerably improved; its absorption coefficient shows NRC 0.6-0.8. It has been found that the Al foam is very preferable for the compactness of the thermal system.

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Particle Based Discrete Element Modeling of Hydraulic Stimulation of Geothermal Reservoirs, Induced Seismicity and Fault Zone Deformation (수리자극에 의한 지열저류층에서의 유도지진과 단층대의 변형에 관한 입자기반 개별요소법 모델링 연구)

  • Yoon, Jeoung Seok;Hakimhashemi, Amir;Zang, Arno;Zimmermann, Gunter
    • Tunnel and Underground Space
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    • v.23 no.6
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    • pp.493-505
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    • 2013
  • This numerical study investigates seismicity and fault slip induced by fluid injection in deep geothermal reservoir with pre-existing fractures and fault. Particle Flow Code 2D is used with additionally implemented hydro-mechanical coupled fluid flow algorithm and acoustic emission moment tensor inversion algorithm. The output of the model includes spatio-temporal evolution of induced seismicity (hypocenter locations and magnitudes) and fault deformation (failure and slip) in relation to fluid pressure distribution. The model is applied to a case of fluid injection with constant rates changing in three steps using different fluid characters, i.e. the viscosity, and different injection locations. In fractured reservoir, spatio-temporal distribution of the induced seismicity differs significantly depending on the viscosity of the fracturing fluid. In a fractured reservoir, injection of low viscosity fluid results in larger volume of induced seismicity cloud as the fluid can migrate easily to the reservoir and cause large number and magnitude of induced seismicity in the post-shut-in period. In a faulted reservoir, fault deformation (co-seismic failure and aseismic slip) can occur by a small perturbation of fracturing fluid (<0.1 MPa) can be induced when the injection location is set close to the fault. The presented numerical model technique can practically be used in geothermal industry to predict the induced seismicity pattern and magnitude distribution resulting from hydraulic stimulation of geothermal reservoirs prior to actual injection operation.

Evolution of Phase Morphology During Compounding of Ternary Blends in a Twin Screw Extruder (이축 압출기를 이용한 혼련에서 삼성분계 블렌드의 상구조 형성과정)

  • Kim, Hyungsu;Lee, Shi-Choon;D .Y. Yu;C. G. Gogos
    • The Korean Journal of Rheology
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    • v.10 no.4
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    • pp.247-255
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    • 1998
  • The morphological changes during melt compounding of ternary blends containing various combinations of acrylonitrile-butadiene-styrene(ABS), methyl methacrylate-butadiene-ethyl acrylate(MBE), styrene-acrylonitrile(SAM) copolymers, and poly(methyl methacrylate)(PMMA) as dispersed components in a fixed matrix of polycarbonate(PC) have been investigated. Depending on the composition of the blend, MBE particles and PMMA phase appear to locate at the PC-SAN interface under the influence of interfacial tensions and motion induced coalescence. The interfacial viscosity is found to be a critical factor that affects the amount of coalescence.

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A Study on Spray Characteristics of Biodiesel Derived from Waste Cooking Oil (폐식용유 바이오디젤 연료의 분무특성에 관한 연구)

  • Ahn, Sangyeon;Kim, Woong Il;Lee, Chang Sik
    • Journal of ILASS-Korea
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    • v.18 no.4
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    • pp.182-187
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    • 2013
  • This study was performed to investigate the effect of biodiesel derived from waste cooking oil on the spray behavior and macroscopic spray characteristics. To analyze quantitative characteristics of test fuels, injection quantity was measured at various injection pressures and the spray images of injected fuels in the pressurized chamber were obtained by using a high speed camera and image analysis system. Based on the measured spray images, the spray tip penetration and spray cone angle were investigated at various energizing timings and injection pressures. In this work, the experimental results showed that the injection quantity of waste cooking biodiesel indicated the higher quantities than diesel at high injection pressure. As the injection pressure was increased, the spray tip penetrations of biodiesel were higher value than diesel. The difference of penetration between biodiesel and conventional diesel fuel was reduced in accordance with the increase of injection pressure. Also, the spray angles of diesel were larger than that of biodiesel because diesel fuel has lower viscosity than biodiesel. In addition, the spray evolution processes of biodiesel fuel at various injection pressures and the elapsed time after the injection were compared to the conventional diesel fuel.