• Fire Science and Engineering
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• v.22 no.5
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• pp.79-82
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• 2008

Biodiesel is manufactured from vegetable oils, etc. in reaction with methanol so that the product of biodiesel may be dangerous due to the methanol remained of it. The risks of methanol remained in biodiesel were studied by measuring flash points and dynamic viscosity to some samples of biodiesel by adding methanol to a certain percentage of. The results of flash points of biodiesel are decreased in accordance with increasing of methanol in biodiesel and also decreasing the dynamic viscosity. It was shown that the risks of explosion of biodiesel are significantly high due to lower flash points resulted from methanol remained in biodiesel fuel as a reactant or adding to biodiesel for reduction of viscosity.

• Journal of ILASS-Korea
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• v.9 no.3
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• pp.1-7
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• 2004

This experiment was undertaken to investigate the atomization characteristics of the low viscosity biodiesel blended fuel and ultrasonic energy added one. Test fuels were conventional diesel fuel and biodiesel fuel. We compared to the characteristics of viscosity and surface tension, SMD between low viscosity biodiesel blended fuel and ultrasonic energy added one. Sauter mean diameter was measured under the variation of the spray distance. Viscosity and surface tension was measured under the variation of the time trace. To measure the droplet size, we used the Malvern system 2600C. Droplet size distribution was analyzed from the result data of Malvern system. Through this experiment, we found that the condition of the ultrasonic energy added situation had smaller Sauter mean diameter of droplet, viscosity and surface tension than that of the conventional situation.

• Journal of Energy Engineering
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• v.13 no.4
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• pp.235-241
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• 2004

This experiment was undertaken to investigate the atomization characteristics of the high viscosity biodiesel blended fuel and ultrasonic energy irradiation one. Test fuels were conventional diesel fuel and biodiesel one. We compared to the characteristics of viscosity and surface tension, SMD between high viscosity biodiesel blended fuel and ultrasonic energy irradiation one. Sauter mean diameter was measured under the variation of the spray distance. Viscosity and surface tension were measured under the variation of the time trace. To measure the droplet size, we used the Malvern system 2600c. Droplet size distribution was analyzed from the result data of Malvern system. Through this experiment, we found that the condition of the ultrasonic energy irradiation situation had smaller Sauter mean diameter of droplet, viscosity and surface tension than those of the conventional situation.

• Transactions of the Korean Society of Automotive Engineers
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• v.12 no.2
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• pp.62-68
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• 2004

To comply with stringent exhaust emission standards, it is necessary to reserch on some better quality of automotive fuels. Sulfur in fuels is sulfur compound by DOC and then it caused to the increase of PM on the surface of the catalyst. This research is focused on diesel emission characteristics and poisoning effect on Diesel Oxidation Catalyst when Ultra Low Sulfur Diesel(ULSD) and biodiesel are applied simultaneously. The biodiesel is used to improve viscosity of fuel specially in fuel injection system of engine since the introduction of ULSD may degrade viscosity in the process of desulfurization. Furthermore, this study may provide some basic data for the design of emissions reduction technology.

• Journal of the Korean Applied Science and Technology
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• v.23 no.4
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• pp.300-306
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• 2006

The esterification of palmitic acid in rapeseed oil and methanol emulsified by propylene glycol with PTSA(p-toluene sulfonic acid) was followed by the transesterification of rapeseed oil into biodiesel with 1(w/v)% GMS(glycerol monostearate) as an emulsifier using TMAH(tetramethyl ammonium hydroxide) catalysts at $60^{\circ}C$. The former reaction was optimized at the 1:20 of molar ratio of oil to methanol and 5wt% PTSA, and the latter was optimized at the 1:8 of molar ratio of oil to methanol and 0.8wt% TMAH. The overall conversion into biodiesel was 98% after 60min of reaction time at the 1:8 of molar ratio, 0.8wt% TMAH and $60^{\circ}C$. TMAH was a good catalyst to control the viscosity of biodiesel mixture.

• Journal of ILASS-Korea
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• v.19 no.4
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• pp.155-166
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• 2014

This review will be concentrated on the spray characteristics of bioethanol and its derived fuels such as ethanol-diesel, ethanol-biodiesel in compression ignition (CI) engines. The difficulty in meeting the severe limitations on NOx and PM emissions in CI engines has brought about many methods for the application of ethanol because ethanol diffusion flames in engine produce virtually no soot. The most popular method for the application of ethanol as a fuel in CI engines is the blending of ethanol with diesel. The physical properties of ethanol and its derivatives related to spray characteristics such as viscosity, density and surface tension are discussed. Viscosity and density of e-diesel and e-biodiesel generally are decreased with increase in ethanol content and temperature. More than 22% and 30% of ethanol addition would not satisfied the requirement of viscosity and density in EN 590, respectively. Investigation of neat ethanol sprays in CI engines was conducted by very few researchers. The effect of ambient temperature on liquid phase penetration is a controversial topic due to the opposite result between two studies. More researches are required for the spray characteristics of neat ethanol in CI engines. The ethanol blended fuels in CI engines can be classified into ethanol-diesel blend (e-diesel) and ethanol-biodiesel (e-biodiesel) blend. Even though dodecanol and n-butanol are rarely used, the addition of biodiesel as blend stabilizer is the prevailing method because it has the advantage of increasing the biofuel concentration in diesel fuel. Spray penetration and SMD of e-diesel and e-biodiesel decrease with increase in ethanol concentration, and in ambient pressure. However, spray angle is increased with increase in the ethanol percentage in e-diesel. As the ambient pressure increases, liquid phase penetration was decreased, but spray angle was increased in e-diesel. The increase in ambient temperature showed the slight effect on liquid phase penetration, but spray angle was decreased. A numerical study of micro-explosion concluded that the optimum composition of e-diesel binary mixture for micro-explosion was approximately E50D50, while that of e-biodiesel binary mixture was E30B70 due to the lower volatility of biodiesel. Adding less volatile biodiesel into the ternary mixture of ethanol-biodiesel-diesel can remarkably enhance micro-explosion. Addition of ethanol up to 20% in e-biodiesel showed no effect on spray penetration. However, increase of nozzle orifice diameter results in increase of spray penetration. The more study on liquid phase penetration and SMD in e-diesel and e-biodiesel is required.

• Transactions of the Korean Society of Automotive Engineers
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• v.17 no.1
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• pp.105-113
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• 2009

The performance of a direct-injection type diesel engine often depends on the strength of swirl or squish, shape of combustion chamber, the number of nozzle holes, etc. This is of course because the combustion in the cylinder was affected by the mixture formation process. In this paper, combustion process of biodiesel fuel was studied by employing the piston which has several grooves with inclined plane on the piston crown to generate swirl during the compression stroke in the cylinder in order to improve the atomization of high viscosity fuel such as biodiesel fuel and toroidal type piston generally used in high speed diesel engine. To take a photograph of flame, single cylinder, four stroke diesel engine was remodeled into two stroke visible engine and high speed video camera was used. The results obtained are summarized as follows; (1) In the case of toroidal piston, when biodiesel fuel was supplied to plunger type injection system which has very low injection pressure as compared with common-rail injection system, the flame propagation speed was slowed and the maximum combustion pressure became lower. These phenomena became further aggravated as the fuel viscosity gets higher. (2) In the case of swirl groove piston, early stage of combustion such as rapid ignition timing and flame propagation was activated by intensifying the air flow in the cylinder. (3) Combustion process of biodiesel fuel was improved by the reason mentioned in paragraph (2) above. Consequently, the swirl grooves would also function to improve the combustion of high viscosity fuel.

• Transactions of the Korean Society of Automotive Engineers
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• v.15 no.6
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• pp.81-86
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• 2007

Biodiesel fuel that consists of saturated and unsaturated long-chain fatty acid alkyl esters is an alternative diesel fuel produced from vegetable oils or animal fats. However, air causes autoxidation of biodiesel fuel during storage, which can reduce fuel quality by adversely affecting its properties, such as the kinematic viscosity and acid value. One approach for improving the resistance of fatty derivatives to autoxidation is to mix them with antioxidants. This study investigated the effectiveness of five such antioxidants in mixtures with biodiesel fuels produced by three biodiesel manufacturers : tert-butylhydroquinone (TBHQ), butylated hydroxyanisole (BHA), butylated hydroxytoluene (BHT), propyl gallate (PrG) and $\alpha$-tocopherol. Oxidation stability was determined using Rancimat equipment. The results show that TBHQ, BHA, and BHT were the most effective and $\alpha$-tocopherol was the least effective at increasing the oxidation stability of biodiesel. This study recommends that TBHQ and PrG be used for safeguarding biodiesel fuel from the effects of autoxidation during storage.

• Transactions of the Korean Society of Automotive Engineers
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• v.15 no.5
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• pp.97-104
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• 2007

The object of this work is to analyze the macroscopic spray performance and atomization characteristics between diesel and biodiesel fuels. In this study, the effects of mixture ratios of biodiesel fuel on the spray tip penetration, fuel injection rate, spray cone angle, and the atomization characteristics such as droplet size, droplets distribution, and spray arrival time according to the axial distance were investigated at various injection parameters. It is revealed that the injection rate is more affected by injection pressure than mixture ratio. And, the spray development process is closely matched between diesel and biodiesel fuels. However, the droplet atomization characteristics of biodiesel shows deteriorated results as the mixture ratio of biodiesel increased because of the high viscosity and density.

• Journal of ILASS-Korea
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• v.14 no.3
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• pp.117-121
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• 2009

Biodiesel fuel has different spray patterns, because viscosity and surface tension of biodiesel fuel are higher than that of diesel fuel. The diesel combustion is strongly controlled by the fuel spray behavior in combustion chamber. So, it was needed to understand the spay characteristics of non-esterification biodiesel fuel. In this study, the spray characteristics of non-esterification biodiesel fuel was investigated to confirm of an effect of WDP. The characteristics of fuel atomization was analyzed with SMD and span factor through laser diffraction particle analyzer (LDPA), and the process of spray injection was visualized through the visualization system composed of a halogen lamp and high speed camera. It was found that injection delay time and SMD of blended fuel with WDP get shoter and smaller than that of non-esterification biodiesel fuel.