• Elastomers and Composites
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• 제57권4호
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• pp.129-137
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• 2022

Low molecular weight liquid butadiene rubber (LqBR) is a processing aid that can resolve the migration problem of tire tread compounds. Various studies are being conducted to replace the petroleum-based processing oil with LqBR. However, the effect of the loading time of LqBR in the compounding process on silica dispersion and vulcanizate properties is not well known. In this study, we analyzed silica dispersion, vulcanizate properties, and viscoelastic properties of silica-filled tire tread compound according to the processing aid type (TDAE oil, non-functional LqBR) and, silane terminated LqBR) and input timing. In the non-functional LqBR compounds, the 'with TESPT' mixing procedure showed excellent dynamic viscoelastic properties while silane-terminated LqBR compounds showed that the 'after TESPT' mixing procedure was good for 300% modulus and abrasion resistance.

• Journal of Mechanical Science and Technology
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• 제20권3호
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• pp.409-417
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• 2006

Polymer nanofibers can be generated by a electrospinning process. The process involves electrically charged jet of polymer solutions evolving from a droplet. The jet stretches in vertical direction due to the difference between charged particle and constant current located at the collector, while the Coulomb and viscoelastic forces start to contribute to radial and azimuthal (torsional) stretching. In this paper, the unstable dynamics of the liquid polymer jet is examined experimentally and theoretically. A complex viscoelastic rheological model has been adopted to analyze the behavior of a charged liquid jet. The model includes complex phenomena of stress relaxation of the liquid jet resulting from the competing force components. The experimental data of the jet paths captured by high-speed videocamera also confirm the similar behavior with the predictions.

• Journal of the Korean Society for Industrial and Applied Mathematics
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• 제9권2호
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• pp.17-27
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• 2005

The problem of the onset stability in an inclined layer of dielectric viscoelastic fluid (Walter's liquid B') is studied. The analysis is made under the simultaneous action of a normal a.c. electric field and the natural convection flow due to uniformly distributed internal heat sources. The power series method used to obtain the eigen value equation which is then solved numerically to obtain the stable and unstable solutions. Numerical results are given and illustrated graphically.

• Korea-Australia Rheology Journal
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• 제18권2호
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• pp.41-49
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• 2006

A modified Volume-of-Fluid (VOF) numerical method is used to predict the dynamics of a liquid drop of a low viscosity dilute polymer solution, forming in air from a circular nozzle. Viscoelastic effects are rep-resented using an Oldroyd-B model. Predicted drop shapes are compared with experimental observations. The main features, including the timing of the shape evolution and the 'bead-on-a-string' effect, are well reproduced by the simulations. The results confirm published conclusions of the third author, that the deformation is effectively Newtonian until near the time of Newtonian pinch-off and that the elastic stress becomes large in the pinch region due to the higher extensional flow there.

• 한국분무공학회지
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• 제24권3호
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• pp.145-151
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• 2019

Viscoelastic fluid is used in various industrial sites because its cost reduction and environmental benefits by preventing formation of fine droplets that scattered around. However, viscoelastic fluids, unlike newtonian fluids, contain a shear thinning characteristic that decrease in viscosity as shear rate increases and elastic characteristic, making it difficult to predict spray breakup process. In this study we made three test fluids. Boger fluid with viscoelastic characteristics, and two newtonian fluids, were prepared to exclude shear thinning characteristics and study the effects of elastic characteristic only. Flow visualization, spray angle, and SMD were measured for three test fluids using laboratory scale impinging jet test apparatus. As a result, it was confirmed that Boger fluid, unlike the newtonian fluid, was not formed fine droplets that scattered around and the breakup process appeared differently. In addition, SMD was found to be large in Boger fluid, and the SMD according to pressure was confirmed that there is no significant difference.

• Korea-Australia Rheology Journal
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• 제18권3호
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• pp.133-141
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• 2006

Carbon dioxide was absorbed into the aqueous nanometer sized colloidal silica solution of 0-31 wt% and 2-amino-2-methyl-1-propanol of $0-2kmol/m^3$ in a flat-stirred vessel with the impeller of various sizes and speeds at $25^{\circ}C$ and 0.101 MPa to measure the absorption rate of $CO_2$. The volumetric liquid-side mass transfer coefficient$(k_La)\;of\;CO_2$ was used to obtain the empirical correlation formula containing the rheological behavior of the aqueous colloidal silica solution. Reduction of the measured $k_La$ was explained by the viscoelastic properties of the aqueous colloidal silica solution. The theoretical value of the absorption rate of $CO_2$ was estimated from the model based on the film theory accompanied by chemical reaction and compared with the measured value.

• Geomechanics and Engineering
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• 제15권2호
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• pp.793-803
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• 2018

Based on the theory of porous media, an interaction system of a floating pile and a saturated soil in cylindrical coordinates subjected to vertical harmonic load is presented in this paper. The surrounding soil is separated into two distinct layers. The upper soil layer above the level of pile base is described as a saturated viscoelastic medium and the lower soil layer is idealized as equivalent spring-dashpot elements with complex stiffness. Considering the cylindrically symmetry and the pile-soil compatibility condition of the interaction system, a frequency-domain analytical solution for dynamic impedance of the floating pile embedded in saturated viscoelastic soil is also derived, and reduced to verify it with existing solutions. An extensive parametric analysis has been conducted to reveal the effects of the impedance of the lower soil base, the interaction coefficient and the damping coefficient of the saturated viscoelastic soil layer on the vertical vibration of the pile-soil interaction system. It is shown that the vertical dynamic impedance of the floating pile significantly depends on the real stiffness of the impedance of the lower soil base, but is less sensitive to its dynamic damping variation; the behavior of the pile in poro-visco-elastic soils is totally different with that in single-phase elastic soils due to the existence of pore liquid; the effect of the interaction coefficient of solid and liquid on the pile-soil system is limited.

• Korea-Australia Rheology Journal
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• 제14권4호
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• pp.161-174
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• 2002

A new technique for numerical calculation of viscoelastic flow based on the combination of Neural Net-works (NN) and Brownian Dynamics simulation or Stochastic Simulation Technique (SST) is presented in this paper. This method uses a "universal approximator" based on neural network methodology in combination with the kinetic theory of polymeric liquid in which the stress is computed from the molecular configuration rather than from closed form constitutive equations. Thus the new method obviates not only the need for a rheological constitutive equation to describe the fluid (as in the original Calculation Of Non-Newtonian Flows: Finite Elements St Stochastic Simulation Techniques (CONNFFESSIT) idea) but also any kind of finite element-type discretisation of the domain and its boundary for numerical solution of the governing PDE's. As an illustration of the method, the time development of the planar Couette flow is studied for two molecular kinetic models with finite extensibility, namely the Finitely Extensible Nonlinear Elastic (FENE) and FENE-Peterlin (FENE-P) models.P) models.

• 청정기술
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• 제14권4호
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• pp.281-286
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• 2008

Polyacrylamide (PAA) 수용액의 유변학적 특성이 $CO_2$의 흡수속도에 미치는 영향을 고찰하기 위해 $25^{\circ}C$, 1기압에서 평판조의 흡수기(교반조의 임펠러 크기 0.05 m, 교반속도 50 rpm)를 사용하여 PAA 수용액에 $CO_2$의 흡수실험을 행하였다. 제시한 Deborah수와 $CO_2$의 물질전달계수와의 상관관계식으로부터 물질전달계수를 구하여 triethanolamine을 첨가한 PAA수용액에서 $CO_2$의 화학흡수속도의 산출에 사용하였다. PAA수용액에서 $CO_2$의 흡수속도는 동일점도의 기준에서 뉴튼액체에서의 값보다 감소하였다.

• Korea-Australia Rheology Journal
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• 제16권1호
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• pp.35-45
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• 2004

Rates of chemical absorption of $CO_2$ in water-in-oil (w/o) emulsion were measured in a flat-stirred vessel at $25^{\circ}C$. The w/o emulsion was composed of aqueous monoethanolamine (MEA) droplets as a dispersed phase and non-Newtonian viscoelastic benzene solutions of polybutene (PB) and polyisobutylene (PIB) as a continuous phase. The liquid-side-mass transfer coefficient ($k_L$) was obtained from the dimensionless empirical equation containing Deborah number expressed as the properties of pseudoplasticity of the non-Newtonian liquid. $k_L$ was used to estimate the enhancement factor due to chemical reaction between $CO_2$ and MEA in the aqueous phase. PIB with elastic property of non-Newtonian liquid made the rate of chemical absorption of $CO_2$ accelerate compared with Newtonian liquid.