• 한국응용과학기술학회지
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• 제20권3호
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• pp.237-242
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• 2003

The high-solid coatings were prepared by blending the synthesized acrylic resin in the previous paper and hexamethylene diisocyanate-trimer and curing it at room temperature. The characterization of the films of the prepared coatings was performed. The impact resistance, $60^{\circ}C$ specular gloss, cross-hatch adhension, and heat resistance of the films proved to be good, and the pencil hardness and drying time proved to be slightly poor. Especially, there was a remarkable improvement in the heat resistance. This improvement may stem from the regular arrangement of ethyl groups introduced into the acrylic resin. From a viscoelastic measurement using a rigid-body pendulum, curing was accelerated with the $T_g$ value. With the increase in $T_g$, log damp value was lowered and dynamic viscoelasic $T_g$ of a cured film was increased.

• 한국세라믹학회지
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• 제44권4호
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• pp.198-201
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• 2007

Multi-walled carbon nanotube (M-CNT)/Nafion nanocomposites were prepared by solution casting to elucidate the effect of M-CNT addition, from 0 to 7 wt%, on the viscoelastic behavior of the composites. The M-CNT bundles induced by the Nafion polymer were determined to be uniformly distributed for the 1 wt% M-CNT/Nafion nanocomposites. The 1 wt% M-CNT/Nafion composite exhibited the highest blocking stress of 2.3 kPa due to its high elastic modulus of 0.485 GPa. From a dynamic mechanical analysis, the 1 wt% M-CNT had the highest storage and loss moduli compared with the other samples in all frequency and temperature ranges. From the storage modulus data, the M-CNT loaded composites had similar $T_g$ values near $120^{\circ}C$. The glass transition temperatures of the M-CNT loaded composites were $120^{\circ}C$ (1 wt%), $117^{\circ}C$ (3 wt%), $117^{\circ}C$ (5 wt%), and $135^{\circ}C$ (7 wt%), suggesting that the effect of the M-CNTs on the Nafion film begins at 1 wt%. Thus, it has been concluded that the 1 wt% M-CNT disported composite is attractive for actuator applications.

• Korea-Australia Rheology Journal
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• 제20권1호
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• pp.1-6
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• 2008

Absorption rate of carbon dioxide was measured in the aqueous xanthan gum (XG) solution in the range of 0-0.15 wt% containing 2-amino-2-methyl-1-propanol (AMP) of $0-2\;kmol/m^3$ in a flat-stirred vessel with an impeller of 0.05m and agitation speed of 50rpm at $25^{\circ}C$ and 0.101 MPa. The volumetric liquid-side mass transfer coefficient ($k_La$) of $CO_2$, which was correlated with the viscosity and the elastic behavior of XG solution containing Deborah number as an empirical formula, was used to estimate the chemical absorption rate of $CO_2\;(R_A)$. $R_A$, which was estimated by mass transfer mechanism based on the film theory using the physicochemical properties and the kinetics of reaction between $CO_2$ and AMP, was compared with the measured rate. The aqueous XG solution with elastic property of non-Newtonian liquid made $R_A$ increased compared with Newtonian liquid based on the same viscosity of the solution.

• 한국염색가공학회지
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• 제5권4호
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• pp.60-66
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• 1993

IPDI, PTAd 및 DMPA(음이온 중심)을 사용하여 폴리우레탄 아이오노머를 합성하고 여기에 물을 첨가하여 수분산 폴리우레탄을 제조하였다. 폴리올 분자량(Mn)이 분산상태 및 에멀젼 주사 필름의 열적, 기계적, 점탄성적 성질 및 팽윤에 미치는 영향을 측정하였다. 폴리올 분자량이 증가할수록 에멀젼 입경과 soft segment $T_{g}$는 감소하였으며, 용매팽윤, 에멀젼 점도, hard segment $T_{g}$는 증가하였다. 필름의 인장강도는 Mn = 1000에서 최소치를 나타냈으며, 파단신율은 폴리올 분자량 증가와 더불어 증가하였는데 이러한 결과는 soft-hard segment 상분리와 고분자량 PTAd의 결정화로 적절히 설명할 수 있었다.

• 대한화장품학회지
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• 제24권3호
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• pp.129-133
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• 1998

We have studied a relationship between the pattern of complex modulus change versus internal phase volume ratio and the rheological consistency of concentrated W/O emulsions with Magnesium Sulfate in the range 0.0 to 0.5 wt% and with different oil polarities, respectively. The rheological consistency with time of concentrated W/O emulsion was checked using Fudoh Rheometer and the coalescence of deformed water droplets was examined using polarized light microscope(LEICA DMRP). To find the pattern of complex modulus change of the concentrated emulsions versus internal phase volume ratio, the effect of varying water phase volume fraction from 0.78 up to 0.85 on viscoelastic measurements was investigated using rotational rheometer (HAAKE Rheostress RS 50). The rheological consistency was mainly destroyed by the coalescence of the deformed water droplets. The greater the increase of complex modulus was, the less coalescence occurred and the more consistent the concentrated emulsions were. And the pattern of complex modulus increase versus volume ratio has been explained with the resistance to coalescence of the deformed interfacial film of water droplets in concentrated W/O emulsion.

• Tribology and Lubricants
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• 제36권1호
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• pp.1-10
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• 2020

Large-area two-dimensional (2D) materials synthesized by chemical vapor deposition on donor substrates are promising functional materials for conductors, semiconductors, and insulators in flexible and transparent devices. In most cases, 2D materials should be transferred from a donor substrate to a target substrate; however, 2D materials are prone to damage during the transfer process. The damages to 2D materials during transfer are caused by contamination, tearing, and chemical doping. For the commercialization of 2D materials, a damage-free, large-area, and productive transfer process is needed. However, a transfer process that meets all three requirements has yet to be developed. In this paper, we review the recent progress in the development of transfer processes for 2D materials, and discuss the principles, advantages, and limitations of each process. The future prospects of transfer processes are also discussed. To simplify the discussion, the transfer processes are classified into four categories: wet transfer, dry transfer, mechanical transfer, and electro-chemical transfer. Finally, the "roll-to-roll" and "roll-to-plate" dry transfer process is proposed as the most promising method for the commercialization of 2D materials. Moreover, for successful dry transfer of 2D materials, it is necessary to clearly understand the adhesion properties, viscoelastic behaviors, and mechanical deformation of the transfer film used as a medium in the transfer process.

• 한국응용과학기술학회지
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• 제17권3호
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• pp.158-166
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• 2000

A conductimetric study of foam formed from mixture of the protein, ${\beta}-lactoglobulin$, and the nonioinc surfactant, SML, revealed that their stability was reduced at concentrations of SML in the range $3{\sim}10mM$. The interaction of SML with ${\beta}-lactoglobulin$ was investigated by fluorimetry and a dissociation constant of $0.2{\mu}M$ was calculated for the complex. Surface tension studies confirmed the presence of interaction between the two components and provided evidence for the progressive displacement of ${\beta}-lactogloblin$ from the air/water interface with increasing SML concentration. Experiments using air-suspended microscopic thin liquid films revealed transitions in the chainage characteristics and thickness of the film at SML concentrations below that which resulted in destabilization of the foam. However, measurements of surface mobility of fluorescent-labeled ${\beta}-lactoglobulin$ by a photobleaching method identified that a transition to a mobile system occurred at a SML concentration which correlated with the onset of instability in the disperse phase. The results would indicate that maintenance of the viscoelastic properties of the surface is paramount importance in determining the stability of interfaces comprising mixtures of protein and surfactant.

• 폴리머
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• 제30권3호
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• pp.230-237
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• 2006

단량체로 methyl methacrylate, n-butyl acrylate, 2-hydroxyethyl acrylate와 도막물성 향상 및 가교밀도를 극대화시켜 줄 관능성 단량체인 acetoacetoxyethyl methacrylate (AAEM)를 반응시켜 4원공중합체인 고형분 80%의 아크릴수지 (HSA-98-20, HSA-98-0, HSA-98+20)를 합성하였다. AAEM 성분이 함유된 아크릴수지의 점성도는 $1420\sim5760cps$, 수평균분자량 $2080\sim2300g/mol$, 다분산도 $2.07\sim2.19$ 및 전환율 $88\sim93%$이었다. 고형분 80%인 아크릴수지와 이소시아네이트 경화제를 상온에서 경화시켜 하이솔리드 도료(HSA-98-20C, HSA-98-0C, HSA-98+20C)를 제조하고 도막시편을 제작하여 각종 물성 시험을 수행한 결과, 제조된 하이솔리드 도료내에 AAEM 도입 전후의 도막물성이 비교실험에서 AAEM 도입후에 내마모성과 내용제성이 증진됨으로써 자동차 상도용 도료에의 적용이 가능케 되었다. 또한 점탄성 측정에 의한 도막의 경화거동에서 HSA-98+20C > HSA-98-0C > HSA-98-20C의 순서로 경화가 빨리 진행됨으로써, 유리 전이 온도 값의 증가함에 따라 경화속도가 빨라짐을 알 수 있었다.

• 대한치과보철학회지
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• 제52권2호
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• pp.82-89
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• 2014

연구 목적: 본 연구의 목적은 중합 과정 중 치과용 레진 시멘트의 점탄성 성질의 변화를 관찰하기 위한 것이다. 연구 재료 및 방법: 6 종류의 레진시멘트(Clearfil SA luting, Panavia F 2.0, Zirconite, Variolink N, RelyX Unicem clicker, RelyX U200)가 이번 실험에 사용되었다. AR1500 stress controlled rheometer를 이용해 $32^{\circ}C$에서 동적 시간 경과 시험(dynamic oscillation time sweep test)이 시행되었다. 각각의 레진시멘트의 전단 저장 계수(G'), 전단 손실 계수(G"), 손실 탄젠트(tan ${\delta}$), 변위량을 20분 동안 3번씩 반복 측정하였다. 측정 결과는 일원배치분석 및 Tukey's hoc test로 사후 검정을 시행하였다(${\alpha}$=0.05). 결과: 모든 레진 시멘트는 혼합 후 시간에 따라 G' 값이 증가하였고, 최종적으로 안정상태에 도달하였다. 실험 종료 시점에서 RelyX U200은 가장 높은 G'값을 나타냈고, RelyX Unicem (clicker type)과 Variolink N이 가장 낮은 G'값을 나타냈다. Tan ${\delta}$와 변위량은 일정 수준의 값을 유지하다가 G'이 증가하기 시작하는 시점에서 0에 도달하였다. 이는 변위량이 0에 도달하는 지점과 거의 일치하였으며, 그 시간은 6분 내외였다. 결론: 본 연구에서 RelyX U200은 다른 레진 시멘트와 비교하여 가장 오랜 시간 동안 소성을 유지하고, 경화 완료 후 가장 높은 강도(rigidity)를 보였다. 따라서 여러 개의 보철물을 동시에 합착해야 하는 경우에 RelyX U200이 유용할 것으로 사료된다.