• 한국정보전자통신기술학회논문지
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• 제13권5호
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• pp.397-402
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• 2020

타입 1 콜라겐 단백질은 인체 내에서 가장 많이 존재하는 단백질이다. 이 단백질은 점탄성 거동을 보이며 이는 힘줄에서도 찾아볼 수 있다. 분자동역학 시뮬레이션 방법에는 rescaling 방법과 reassignment 방법으로 온도를 조절할 수 있다. rescaling 방법은 온도를 주어진 온도로 책정하는 방법이고, reassignment 방법은 원하는 온도로 맥스웰 분포를 이용하여서 온도를 책정하는 방법이다. 우리는 reassignment 방법에서 콜라겐 단백질의 거동이 시간에 따라서 변화하는 현상을 찾아내었다. 반면에 rescaling 방법에서는 시간에 무관하게 거동하였다. 콜라겐에 다른 속도로 인장을 가하였을 경우, 예를 들어 0.5, 1, 2, 5 Å/ps의 속도로 40 Å까지 힘을 가했을 경우, rescaling 방법에서는 속도에 따른 변화가 거의 없었던 반면, reassignment 방법의 경우 대략 80nm, 100nm, 130nm, 180nm까지 인장이 되었음을 보여준다. 이 현상에 대한 물리학적 의미를 명확하게 규명하지는 못하였지만, 단백질에 관한 시뮬레이션을 실행하는데 있어서 주의를 기울여 수행하여야 한다는 점에서 이 논문의 가치가 있다고 생각한다.

• 대한화장품학회지
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• 제47권1호
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• pp.85-92
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• 2021

각질층은 각질세포와 세포간지질로 형성되고, 세포간지질의 주성분으로 세라마이드가 있다. 세라마이드는 세포간지질이 라멜라 구조를 형성하는데 중요한 성분 중 하나지만 난용성 물질이기 때문에 피부로의 직접적인 적용은 적합하지 않다. 그래서 약물전달시스템 중 꾸준한 관심을 받는 pluronic lecithin organogel (PLO gel) 제형에 세라마이드를 적용하고자 하였다. 제형에 적합한 오일을 선택하였고, 세라마이드를 함유한 PLO gel을 제조하였다. 편광현미경을 이용하여 액정 형성과 변화를 관찰하였고, 제형의 점탄성 거동을 알아보기 위해 점탄성 분석을 진행하였다. 그리고 제형 내의 구조들을 확인하기 위해 small-angle X-ray scattering (SAXS) 및 wide-angle X-ray scattering (WAXS) 분석을 진행하였다. 결과, 세라마이드를 함유한 PLO gel에서의 세라마이드와 레시틴의 함량비에 따라 액정 형성 여부, 액정의 크기와 안정성에서 차이를 보였다. 또한 점탄성 분석 결과로 제형의 안정성을 알 수 있었고, SAXS/WAXS 분석을 통해 세라마이드를 함유하지 않은 PLO gel은 사방정계 배열의 헥사고날 구조, 세라마이드를 함유한 PLO gel은 사방정계 배열의 라멜라 구조를 갖는 것을 확인하였다.

• Composites Research
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• 제32권6호
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• pp.382-387
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• 2019

상대습도와 온도가 PET 필름의 점탄성 특성에 미치는 영향을 조사하기 위해 RH-DMA를 이용하여 single frequency strain mode 시험, stress relaxation mode 시험, creep 시험을 수행하였다. 상대습도는 10%, 30%, 50%, 70%, 90%를 적용하고 온도는 single frequency strain mode 시험의 경우 30~95℃, stress relaxation mode 시험의 경우 30℃ 와 70℃, creep 시험의 경우 5~95℃를 고려하였다. 연구결과에 따르면 상대습도가 높아지면 저장탄성계수와 손실탄성계수는 낮아지며 손실탄성계수의 최대값은 상대습도의 변화에 큰 영향을 받지 않고 거의 일정해진다. 이완탄성계수는 초기에 급격히 감소하다가 일정한 값을 가지며 높은 온도에서는 상대습도의 변화에 민감해진다. 변형률 회복는 초기에 급격히 증가하며 온도가 높아지면 이완 탄성계수와 마찬가지로 상대습도에 민감하게 변한다. 크리프 컴플라이언스의 증가 정도는 온도가 높아지면 커지며 유리전이온도보다 온도가 높아지면 증가 정도는 더욱 커진다. 시간-온도 중첩법을 통해 구해지는 마스터 선도를 이용하면 상대습도와 온도 등의 운용 조건에서의 장기 성능을 예측할 수 있는 정보를 얻을 수 있다.

• Applied Biological Chemistry
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• 제32권4호
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• pp.332-337
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• 1989

재수화한 동결건조 즉석미반의 리올로지 성질을 통상법으로 취반한 미반과 비교하면서 조사하였다. 온도$(60{\sim}90^{\circ}C)$를 달리한 복원시간에 따른 미립 경도의 역수(연화도)는 복원온도에 상관없이 1차 반응 속도식에 따라 감소하였고, 경도반응의 속도 상수 값은 온도에 따라 증가하였으며, 이의 활성화 에너지는 6.1 kcal/g-mol이었다. 여러 온도 $(60{\sim}90^{\circ}C)$에서 복원시킨 즉석미반의 압축응력 완화 곡선은 통상법으로 취반한 미반과 마찬가지로 일반화된 Maxwell의 6요소 역학모형으로 설명되었고, 즉석미반은 취반미보다 완화되기 쉬우나 복원온도가 높을수록 탄력성이 높아지는 특성을 나타내었다.

• 소음진동
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• 제8권6호
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• pp.1093-1102
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• 1998

The success of controllability of smart structures depends on the quality of the bonding along the interface between the main structure and the attached sensing and acuating elements. Generally, the analysis procedures neglect the effect of the interfacial bond layer or assume that this bond layer behaves like viscoelastic material. Three different bond layers. two modified epoxy adhesives, and one isocyanate adhesive were prepared for their toughness and moduli. Bond layer of the chosen adhesive provides an almost perfect bonding condition between the composite structure and the PZT while bended significantly like arrow-shape. The perfect bonding condition is tested by considering various material properties of the bond layers. and based on this perfect bonding condition, the effects of the interfacial bond layer on the dynamic behavior and controllability of the test structure is experimentally studied. Once the perfect bonding condition is achieved. dynamic effects of the bond layer itself on the dynamic characteristics of the main structure is negligible. but the contribution of the attached PZT elements on the stiffness of the multi-layered structure becomes significant when the thickness of the bond layer increased.

• 한국안전학회지
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• 제27권5호
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• pp.117-125
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• 2012

In recent years, polymer concrete based on polyester resin have been widely generalized and the research of polymer concrete have been actively pursued by the technical innovations. Polymer concrete is a composite consisting of aggregates and an organic resin binder that hardens by polymerization. Polymer concrete are stronger by a factor of three or more in compression, a factor of four to six in tension and flexural and a factor of two in impact when compared with portland cement concrete. In view of the growing use of polymer concrete, it is important to study the physical characteristics of the material, emphasizing the short term properties as well as long term mechanical behavior. If polymer concrete is to be used in flexural load-bearing application such as in beam, it is imperative to understand the deformation of the material under sustained loading conditions. This study is proposed to empirical and mechanical model of polymer concrete tension creep using long-term experimental results and mathematical development. The test results showed that proposed model has been used successfully to predict creep deformations at a stress level that was 20 percent of the ultimate strength and viscoelastic behavior of recycled-PET polymer concrete is linear of stress level up to 30 percent. It is expected that the present model allows more realistic evaluation of varying stresses in polymer concrete structures with a constant loading.

• Structural Engineering and Mechanics
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• 제62권3호
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• pp.325-344
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• 2017

The present paper investigates the propagation of Love-type wave in a composite structure comprised of imperfectly bonded piezoelectric layer with lower fiber-reinforced half-space with rectangular shaped irregularity at the common interface. Closed-form expression of phase velocity of Love-type wave propagating in the composite structure has been deduced analytically for electrically open and short conditions. Some special cases of the problem have also been studied. It has been found that the obtained results are in well-agreement to the Classical Love wave equation. Significant effects of various parameters viz. irregularity parameter, flexibility imperfectness parameter and viscoelastic imperfectness parameter associated with complex common interface, dielectric constant and piezoelectric coefficient on phase velocity of Love-type wave has been reported. Numerical computations and graphical illustrations have been carried out to demonstrate the deduced results for various cases. Moreover, comparative study has been performed to unravel the effects of the presence of reinforcement and piezoelectricity in the composite structure and also to analyze the existence of irregularity and imperfectness at the common interface of composite structure in context of the present problem which serves as a salient feature of the present study.

• Journal of Biosystems Engineering
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• 제18권3호
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• pp.262-269
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• 1993

Stress relaxation behaviors of the cucumber under bending moment were tested with UTM at three levels of loading rate and initial deflection ratio. Sample cucumber was selected from three cultivars of cucumber, Cheongjangmadi, Baekdadagi, and Gyeousalicheongjang, because these cultivars are the most popular grown cultivars in Korea. When the bending moment was applied to the cucumber sample, the effective span between simple supports was held a constant value of 116mm with consideration of the selected sample length. The objectives of this study were to develop the rheological models such as linear and nonlinear models of the stress relaxation for the cucumber samples, and to investigate the effects of loading rate and initial deflection ratio on the stress relaxation behavior of the cucumber. The results of this study may be summarized as follows : 1. Stress relaxation behavior of the cucumber could be well described by the generalized Maxwell model for each level of deflection ratio. But the stress relaxation behavior of the sample was found to be initial deflection ratio and time dependent, and it was represented the nonlinear viscoelastic model as a function of initial deflection ratio and time. 2. Stress relaxation behavior of the cucumber samples was very highly affected by the loading rate and the initial deflection ratio. The more loading rate and initial deflection ratio resulted in the more initial bending stress and after stress relaxation progressed more rapidly. 3. At the same test conditions, it was found that the stress relaxation rate of Cheongjangmadi was faster than that of other cultivars.

• Journal of the Korean Wood Science and Technology
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• 제22권1호
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• pp.85-90
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• 1994

The flow properties of binder latices for paper coating were investigated, together with dynamic viscoelastic properties of latex films and electron micrographs of latices, under various conditions. The amphoteric latex, binder pigment latex and anionic latex were used in this work. The amphoteric latex has both anionic and cationic functional group on its surface. The binder-pigment with a core-shell structure has dual functions : plastic pigment and binder. The low shear viscosity of binder latices and clay slurry were measured with Brookfield vis cometer. At low-shear rates. the viscosity decreased with increasing particle size of latex. On the amphoteric latex surface, the carboxyl groups are assumed to be fully dissociated over the region of pH 9~12, but the density of negative groups seems to be increased because of the gradual decrease in the degree of dissociation of amino groups. Since the apparent particle size of latex increases with surface charge, the electroviscous effect can be observed. On the anionic latex surface, the charge density is assumed to be nearly constant above pH 8. However, below pH 8 the coagulation of particles could be observed probably because of the decrease in the charge density.

• Journal of Biosystems Engineering
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• 제18권4호
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• pp.402-409
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• 1993

During all mechanical processes rice plants are subjected to verious forces such as natural load of wind and mechanical load of agricultural machines. A force is always accompanied by deformation, which must be either sufficiently great for pressing or sufficiently slight in order to avoid damage. The mechanical behavior of the rice plants is determined by three variables : force, deformation and time. And they must be studied using rheological methods to determine their viscoelastic properties. This study is conducted to experimentally determine the mechanical and rheological properties of the rice stalks subjected to radial load. The force relaxation tests are performed under constant deformation, during which the reduction of forces over time is measured. The mechanical models were developed from the abtained data. The results were as follows : 1. The relaxation behavior of a rice stalk in radial compession may be described by a generalized Maxwell model consisting of 3 Maxwell elements in parallel. 2. Relaxatiom intensity always decreased with increased time of relaxation. 3. The rate of deformation has a significant effect on the relaxation behavior. having increasing pattern with an increase in rate of deformation. 4. The relaxation intensity and residual deformation increased with increased initial load. 5. The relaxtion of the intermediate portion of stalk was bigger tham that of the upper and lower portions.