• 제목/요약/키워드: vinyl acetate

검색결과 384건 처리시간 0.027초

A Study on the Preparation of Wood-Plastic Combinations(III) Preparation of Wood-Plastic Combinations by Thermal Curing Method

  • Kim, Jaerok;Lee, Kyung-Hee;Pyun, Hyung-Chick
    • Nuclear Engineering and Technology
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    • 제4권4호
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    • pp.301-305
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    • 1972
  • 육송 미송 포플라 등 국산 연질 목재에 단량체 또는 단량체 혼합물을 촉매와 함께 침투시키고 열중합함에 있어서 시간에 따르는 중합율을 구하고 이것을 방사선 중합으로 WPC를 제조할 때 얻은 간과 비교 검토하여 다음과 같은 결론을 얻었다. (1) 중합율로 보아서는 육송, 미송이 포플라보다 좋으며 M.M.A.가 다른 단량체보다 효과적이다. (2) 비닐아세테이트는 일반적으로 열중합에 의한 중합율이 저조한 편이며 특히 포플라에 침투된 경우 매우 낮아 W.P.C.를 만들기 곤란하다. 그러나 비닐아세테이트와 M.M.A.를 같이 침투시키면 나무종류나 중합방법에 별 관계없이 매우 빨리 중합하여 가장 효과적이다. (3) 나무에 침투된 단량체나 단량체 혼합물의 중합의 경향은 나무가 많은량의 수지를 함유하지 않는다면 중합방법에 관계없이 단량체나 단량체 혼합물 자체만일때의 중합의 경향과 같다.

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Influence of Surface Finishing Material Types to Formaldehyde and Volatile Organic Compounds Emission from Plywood

  • Kim, Ki-Wook;Oh, Jin-Kyoung;Lee, Byoung-Ho;Kim, Hyun-Joong;Lee, Young-Kyu;Kim, Sung-Hun;Kim, Gwan-Eui
    • Journal of the Korean Wood Science and Technology
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    • 제36권2호
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    • pp.39-45
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    • 2008
  • Formaldehyde and volatile organic compounds (VOCs) are emitted from wood-based panels that have been made using wood particles, wood fiber, wood chips, formaldehyde-based resins and so on. In this study, we examined formaldehyde and total VOCs (TVOC) emission behaviors for plywood overlaid with water-soluble phenolic resin impregnated linerboard (PL), and two kinds of surface materials (decorative veneer and pre-impregnated finishing foil) that were adhered onto the PL that named DPL and PPL. EVA (ethyl vinyl acetate) was used to overlay the decorative veneer and pre-impregnated finishing foil on the plywood with water-soluble phenolic resin impregnated linerboard by a hot press instrument. The debonding test and accelerated aging test were conducted to assess their mechanical properties. Formaldehyde and TVOC emission concentrations were measured using the FLEC method and a VOC Analyzer, respectively. The debonding test results of PL, DPL and PPL were 1.2, 1.5, and $0.5N/mm^2$, respectively. The surface appearance of the samples were not changed after the accelerated aging test. The PL and DPL exhibited reduced formaldehyde and TVOC emission levels, respectively. In the case of PPL, the VOC value was relatively higher than those of PL and DPL.

The impact fracture behaviors of CFRP/EVA composites by drop-weight impact test

  • Go, Sun-Ho;Kim, Hong-Gun;Shin, Hee-Jae;Lee, Min-Sang;Yoon, Hyun-Gyung;Kwac, Lee-Ku
    • Carbon letters
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    • 제21권
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    • pp.23-32
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    • 2017
  • A drop weight impact test was conducted in this study to analyze the mechanical and thermal properties caused by the changes in the ratio of carbon fiber reinforced plastic (CFRP) to ethylene vinyl acetate (EVA) laminations. The ratios of CFRP to EVA were changed from 10:0 (pure CFRP) to 9:1, 8:2, 6:4, and 5:5 by manufacturing five different types of samples, and at the same time, the mechanical/thermal properties were analyzed with thermo-graphic images. As the ratio of the CFRP lamination was increased, in which the energy absorbance is dispersed by the fibers, it was more likely for the brittle failure mode to occur. In the cases of Type 3 through Type 5, in which the role of the EVA sheet is more prominent because it absorbs the impact energy rather than dispersing it, a clear form of puncture failure mode was observed. Based on the above results, it was found that all the observation values decreased as the EVA lamination increased compared with the CFRP lamination. The EVA lamination was thus found to have a very important role in reducing the impact. However, the strain and temperature were inversely propositional.

EVA 수지 이용 연료유 생성을 위한 열분해 반응에서 실리카-알루미나 계열 무기물의 영향 (The Effects of Silica-Alumina Type Inorganic Compounds on the Pyrolysis Reaction of EVA to Produce Fuel-Oil)

  • 박영철;최주홍;오세희
    • 한국수소및신에너지학회논문집
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    • 제22권5호
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    • pp.706-713
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    • 2011
  • The effects of silica-alumina type catalysts addition on the thermal decomposition of ethylene vinyl acetate (EVA) resin have been studied in a thermal analyzer (TGA, DSC) and a small batch reactor. The silica-alumina type compounds tested were kaolinite, bentonite, perlite, activated clay and clay. As the results of TGA experiments, pyrolysis starting temperature for EVA resin had the 1st pyrolysis temperature range of 300~$400^{\circ}C$ and the 2nd pyrolysis temperature range of 425~$525^{\circ}C$. The silica-alumina type catalysts did not affect the pyrolysis rate in EVA pyrolysis reaction. In the DSC experiments, addition of kaolinite and bentonite catalysts reduced the heat of fusion and heat of 2nd pyrolysis reaction. In the batch system experiments, the mixing of silica-alumina type catalysts enhanced the yield of fuel oil, and affected to the distribution of carbon numbers. In the silica-alumina type inorganic material used in this experiments, bentonite was the most effective from the pyrolysis heat, yields, and the characteristics of fuel oil.

Percutaneous Absorption and Model Membrane Variations of Melatonin in Aqueous-based Propylene Glycol and 2-Hydroxypropyl-$\beta$-cyclodextrin Vehicles

  • Lee, Beom-Jin;Cui, Jing-Hao;Keith A. Parrott;James W.Ayres;Robert L.Sack
    • Archives of Pharmacal Research
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    • 제21권5호
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    • pp.503-507
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    • 1998
  • Percutaneous absorption and model membrane variations of melationin (MT) in aqueous-based propylene glycol and $2-hydroxypropyl-{\beta}-cyclodextrin $vehicles were investigatted. the excised hairless mouse skin (HMS) and two synthetic ethylene vinyl acetate (EVA) and microporous polyethylene (MPE) were selected as a model membrane. the solubility of MT was determined by phase equilibrium study. the vertical $Franz{\circledR}$ type cell was used for diffusion study. The concentration of MT was determined using reverse phse HPLC system. The MT solubility was the highest in a mixture of PG and $2-HP{\beta}CD$. The percutaneous absorption of MT through excised HMS increased as the solubility increased. However, the permeability coefficient decreased and then slightly increased in mixture of PG and $2-HP{\beta}CD$. On the other hand, both flux and permeability coefficient through EVA membrane decreased as the solubility increased. No MT was detected over 12 h after starting diffusion through MPE membrane. The flux of MT was dependent on the type of membrane selected. Flux of MT was greatest in excised HMS followed by EBA and MPE membrane. Flux of MT through EVA membrane was 5-20 times lower when compared to excised HMS. Interestingly, volumes of donor phase when MPE membrane was used, significantly increased during the study period. the HMS might be applicable to expect plasma concentration of MT in human subjects based on flux and pharmacokinetic parameters as studied previously. the current studies may be applied to deliver MT transdermally using aqueous-based vehicles and to fabricate MT dosage forms.

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전면 유리와 EVA의 광 반사에 의한 PV모듈의 광전류 손실 예측 시뮬레이션 (A Simulation of Photocurrent Loss by Reflectance of the Front Glass and EVA in the Photovoltaic Module)

  • 이상훈;송희은;강기환;안형근;한득영
    • 전기학회논문지
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    • 제62권1호
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    • pp.76-82
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    • 2013
  • The solar cell is a device to convert light energy into electric, which supplies power to the external load when exposed to the incident light. The photocurrent and voltage occurred in the device are significant factors to decide the output power of solar cells. The crystalline silicon solar cell module has photocurrent loss due to light reflections on the glass and EVA(Ethylene Vinyl Acetate). These photocurrent loss would be a hinderance for high-efficiency solar cell module. In this paper, the quantitative analysis for the photocurrent losses in the 300-1200 wavelength region was performed. The simulation method with MATLAB was used to analyze the reflection on a front glass and EVA layer. To investigate the intensity of light that reached solar cells in PV(Photovoltaic) module, the reflectance and transmittance of PV modules was calculated using the Fresnel equations. The simulated photocurrent in each wavelength was compared with the output of real solar cells and the manufactured PV module to evaluate the reliability of simulation. As a result of the simulation, We proved that the optical loss largely occurred in wavelengths between 300 and 400 nm.

EVA와 PET 혼합(混合) 폐플라스틱의 재질분리(材質分離)를 위한 마찰하전형(摩擦荷電形) 정전선별(靜電選別) 기술개발(技術開發) (Development of Triboelectrostatic Separation Technique for Material Separation of EVA & PET Mixture Plastic Wastes)

  • 전호석;박철현;백상호;김병곤;김형석
    • 자원리싸이클링
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    • 제18권1호
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    • pp.13-21
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    • 2009
  • 본 연구에서는 마찰하전형정전선별법을 적용하여 EVA(ethylene vinyl acetate)와 PET(polyethylene terephthalate) 혼합 폐플라스틱의 재활용을 위한 재질분리 연구를 수행하였다. 하전물질 선정을 위한 하전특성 연구결과, PP(polypropylene)재질이 EV4와 PET 폐플라스틱의 재질분리에 가장 효과적인 하전물질로 확인되어, PP재질의 pipe-type 하전장치를 개발하였다. 본 연구에서 개발된 하전장치를 이용한 재질분리 실험결과, 최적 실험조건에서 PET의 품위와 회수율이 각각 98.7%와 89.7%인 결과를 얻었다.

한지벽지 제조에 관한 연구(II) - 한지벽지 제조 및 특성 - (A Studies on Wallpaper Making Using Hanji(II) - Making and Properties of Hanji Wallpaper -)

  • 윤승락;조현진;박상범;김재경;김사익;김효주;이문희
    • Journal of the Korean Wood Science and Technology
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    • 제25권4호
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    • pp.17-21
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    • 1997
  • This study was carried out to develop the manufacturing technique of Korean paper(Hanji) and find out new uses of machine-made Hanji produced on a a large scale by paper machine. Six kinds of Hanji were made and laminated with backpaper by acryl-based or vinyl acetate ethylene-based adhesive. Six kinds of wallpapers were made such as WH 1, WH 2-1, WH 2-2, WH 3-1, WH 3-2 and WH 4. Physical properties and quality test on the wallpapers were examined. Physical strength of the wallpapers was better than each strength of the Hanji and backpaper. It might be a roll of adhesive. And so, Production cost of the Hanji could be brought down if the Hanji was made thin to get strength not enough to cut during lamination of two papers(Hanji and backpaper). Hanji wallpapers of WH 3-1 and WH 4 are lower than a standard in sunlight resistance and WH 1 is in properties of opacity. WH 2-1, WH 2-2 and WH 3-2 were better than Korean standard in some quality tests. WH 2-2 and WH 3-2 were superior to other wallpapers as a whole. About, twenty kinds of wallpapers with surface treatment, are now being produced on the basis of these two types of wallpapers.

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Insect Repellency and Crop Productivity of Essential Oil Films

  • KIM, Jin Gu;KANG, Seok Gyu;MOSTAFIZ, Md Munir;LEE, Jeong Min;LEE, Kyeong-Yeoll;HWANG, Tae Kyung;LIM, Jin Taeg;KIM, Soo Yeon;LEE, Won Hee
    • Journal of the Korean Wood Science and Technology
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    • 제48권1호
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    • pp.95-106
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    • 2020
  • The purpose of this study was to determine the effects of coniferous essential oils (EOs) blended films on insect repellence and crop productivity. Low-density polyethylene (LDPE) film is widely used, especially in agriculture and for food packaging. Ethylene vinyl acetate was blended with LDPE to reduce volatilization of EOs. An EO from Japanese cypress (Chamaecyparis obtusa) was incorporated into the blend film to conduct field research on antimicrobial and insect repellent properties. Among the various concentrations of EO, the highest concentration (2.5%) showed the highest efficiency in terms of pesticidal activity. The ability to inhibit microbial growth can be explained by the lipophilic properties of the EO component, and many studies have already demonstrated this. Agricultural films containing all types of EO have been tested on various crops such as chili, cucumber, Korean melon and have been able to verify their effectiveness in avoiding pests and increasing yields. From these results, it was found that it is reasonable to use a modified film such as a composite film containing an EO for agriculture. Thus, the modified film containing EO has undoubtedly shown impressive potential for reducing the use of pesticides in a variety of ways, not only for agricultural mulching film but also for food and agricultural product packaging. This product is an environmentally friendly chemical and is safe for agricultural and industrial and food packaging applications, among others. In particular, the use of agricultural films significantly reduces the use of pesticides, suggesting that farmers can increase their incomes by reducing working hours and costs, and increasing production.

사용 후 태양광 실리콘 모듈의 리싸이클링 (Recycling of End-of-Life Photovoltaic Silicon Modules)

  • 김준수;조재영;이재경;박아름;박진혁;윤현목;전연수
    • 자원리싸이클링
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    • 제28권5호
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    • pp.19-29
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    • 2019
  • 최근에 들어 태양광 발전의 시설용량이 급격히 증가되고 기 설치된 태양광 패널의 수명이 다하여 폐기될 모듈의 양이 점점 많아짐에 따라, 이에 대한 처리가 환경문제 해결뿐만 아니라 유가물질의 회수차원에서도 크나큰 관심을 받고 있다. 사용 후 태양광 모듈의 처리 공정은 대부분 알루미늄 프레임의 해체, 강화유리의 분리 회수, 실리콘 웨이퍼에 부착된 에틸렌 비닐 아세테이트(EVA)의 제거 및 태양광 셀 중에 함유된 유가금속의 회수 등으로 구성되어 있다. 전술한 태양광 폐모듈의 리싸이클링 기술들을 치밀하게 검토한 다음, 물질 선별기술을 포함한 효과적인 처리 기술을 제시하였다. 그리고 리싸이클링 산업의 활성화를 위해서 필수적인 생산자 책임제도의 시행을 비롯한 종합적인 의견을 제안하였다.