• 한국도로학회논문집
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• 제14권5호
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• pp.85-91
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• 2012

PURPOSES: In this study, various laboratory tests were performed to investigate the suitability of wasted vinyl as a modifier of asphalt binder. METHODS: Based on the ASTM specification, variations in material properties of asphalt binder such as penetration, flash point, softening point, ductility, penetration index (PI), and performance grade (PG) with vinyl content were tested and analyzed. RESULTS: Lavoratory tests revealed that penetration and ductility of the asphalt binder increased with the vinyl content. The flash point, softening point, and PI decreased, and PG changed from 64-22 to 70-22 with increase of the vinyl content. CONCLUSIONS: Wasted vinyl modified the material properties of the asphalt binder. However, the asphalt binder with vinyl content over 6.0% was unsuitable as a pavement material.

• 농촌의학ㆍ지역보건
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• 제19권1호
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• pp.25-29
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• 1994

In order to find out the effects of vinyl house body, the author compared the physical and laboratory examinations between 96 cases of vinyl house farmers and 96 cases of land farmers who lived in 3 Gun's in Kyoungnam Province from July, 1st through September, 30, 1993. The examination included blood pressure, CBC, urinalysis, and blood chemistry. Systolic blood pressure and alkaline phosphates levels were lower in vinyl house farmers than in land farmers. But white blood cell counts were higher in vinyl house farmers and the other results were not different between two groups. It suggests that the environment of vinyl house - small, poorly ventilating, hot and humid environment - affected human body, then those facts should be considered during construction of vinyl houses.

• 공업화학
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• 제10권3호
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• pp.362-366
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• 1999

Poly(vinyl chloride) (PYC) 유도제들로부터 용매증발법을 이용하여 바이오센서용 막을 제조하고 기체 투과특성을 조사하였다. 진공하에서 용매를 증발시켜서 제조된 막보다 공기 중에서 서서히 증발시켜 제조된 막의 투과도 계수가 더 높은 것으로 나타났다. PVC 유도체 막들에 대한 $CO_2$와 $O_2$의 투과도 계수는 공급부의 압력이 증가함에 따라 감소하였다. Carboxylated poly(vinyl chloride) (CPVC) 에 대한 dioctyl phthalate (DOP)의 첨가량이 증가함에 따라 투과도 계수는 증가하였다. 예를 들면 DOP 30 wt. %를 첨가하였을 때, $CO_2$와 $O_2$의 투과도 계수는 100 psig에서 각각 2.03, 0.96 Barrer 이었으며, DOP를 첨가하지 않았을 때 보다 약 4~5배 증가하였다. Poly(vinyl chloride-co-vinyl acetate) (PVCA)를 가수분해함으로써 OH기가 도입된 poly(vinyl chloride-co-vinyl acetate-co-vinyl alcohoI) (Syn-PVCAcAl)에 DOP를 첨가하였을 때 $CO_2$의 투과도 계수에서 시판제품 PVCAcAl보다 비교적 높은 값을 나타내었으나, $O_2$의 투과도 계수에는 차이가 없었다.

• 폴리머
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• 제24권5호
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• pp.579-588
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• 2000

보호콜로이드에 따른 입체 안정제 (steric stabilizer)작용이 폴리초산비닐 (poly(vinyl acetate), PVAc) 라텍스의 안정성에 미치는 영향을 조사하였다. 보호콜로이드로서 중합도 1080, 검화도 78.4%인 반응성 poly(vinyl alcohol) mono thiol (PVALT)를 사용한 것이 중합도 1100, 검화도 81.6%인 poly(vinyl alcohol) (PVA)를 사용하는 것보다 PVAc 라텍스의 안정성이 양호하였으며, 반응성 PVALT의 첨가량이 증가할수록 PVAc 라텍스의 안정성은 향상되었다. PVAc 라텍스 입자의 표면 형태 변화는 투과전자 현미경으로 관찰하였다. 입자크기는 반응성 PVALT의 첨가량이 증가할수록 감소하였다. 결과적으로 에멀젼의 중합 시 PVA보다 반응성 PVALT를 사용하는 것이 PVAc 라텍스의 안정성이 양호함을 알 수 있었다. 이는 반응성 PVALT로 인해 PVAc 라텍스 입자계면에 PVA와의 화학 결합을 유도할 수 있는 다량의 티올 (thiol)기가 도입되어 PVAc와 반응성 PVALT간의 화학반응으로 인한 PVALT-b-PVAc 블록 공중합체가 생성됨에 기인하는 것으로 사료된다. 아울러 제타전위는 탄산나트륨의 농도가 증가할수록 감소하였다.

• 한국농공학회지
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• 제29권4호
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• pp.117-123
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• 1987

This study was conducted to develop an automatic insulation system to reduce the heat loss through the wall of greenhouses during the nighttime in winter. A double covered model vinyl house was constructed, and blowers were used to fill or remove styrene pellets automatically the inside of the double-wall of the double covered vinyl house. The effects of insulation of the double covered vinyl house insulated with the styrene pellets were analyzed by comparing with the single covered vinyl house. The results obtained from this study can be summarized as follows : 1. The optimum thickness of the double-wall of the double covered vinyl house was found to be 5 to 10 cm. 2.When the outside temperature varied in the range of -8.3 to -1.5$^{\circ}C$ during the nighttime, the inside temperature of the double covered vinyl house insulated with the styrene pellets showed 7.7 to 11.7$^{\circ}C$ and the inside temperature of the single covered vinyl house showed -5.8 to 2.3$^{\circ}C$. Therefore, the effects of insulation of the double covered vinyl house insulated with the styrene pellets were confirmed to be excellent. 3. Also, the excessive increase of the inside temperature in the vinyl house was prevented by the shading effect of the double covered vinyl house insulated with the styrene pellets during the daytime. 4. When the outside temperature varied in the range of 17.7 to 30.0$^{\circ}C$ during the daytime, it was possible to keep the inside temperature at 30${\pm}$4$^{\circ}C$ in the double covered vinyl house by operating the insulation system. 5. The transmissivity of the double covered vinyl house with the styrene pellets removed was 52.4 % on the average.

• 공업화학
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• 제10권1호
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• pp.58-66
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• 1999

알루미나에 담지한 $CrO_x$ 촉매를 이용하여 $200{\sim}400^{\circ}C$의 온도 구간에서 공기 중 vinyl chloride의 산화반응을 조사하였다. 탄소를 포함하는 주생성물은 CO 및 $CO_2$로, 온도의 증가에 따라 $CO_2$의 선택도는 증가하고 CO는 감소하였다. 이로부터 $CrO_x$ 촉매상에서 vinyl chloride는 먼저 CO로 일차산화 후 다시 $CO_2$로 완전산화됨을 알 수 있었다. 반응물에 HCl을 첨가하였을 때 vinyl chloride의 전환율은 변화가 없었으나 $CO_2$의 선택도는 감소하였는데 이는 주반응생성물인 HCl이 vinyl chloride의 $CO_2$로 완전산화를 방해함을 의미한다. 반응물에 물이 없는 조건하에서 vinyl chloride를 산화시킬 때 상당량의 $Cl_2$가 생성되었으나 물을 첨가 시 $Cl_2$는 검출되지 않았다. Vinyl chloride의 촉매산화반응에 대한 $CrO_x$ 담지촉매와 몇가지 귀금속 및 다른 전이 금속 산화물의 활성을 비교하였는데 $CrO_x$ 담지촉매의 vinyl chloride 분해활성은 1% Pt 담지촉매를 제외한 다른 촉매에 비해 높았으며, $275^{\circ}C$에서 12% $CrO_x/Al_2O_3$의 반응속도를 기준으로 각 촉매의 활성을 비교시 1% $Pt/Al_2O_3$ 보다 1.2배정도 활성이 떨어지나 다른 촉매에 비하여 각각 3배에서 8배 가량 높은 활성을 나타내었다.

• Korea-Australia Rheology Journal
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• 제17권2호
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• pp.79-85
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• 2005

Aqueous mixtures of hyaluronic acid and poly(vinyl alcohol) system and hydrogels thereof were introduced to obtain new bioartificial materials that have excellent mechanical properties, biocompatibility and enhanced rheological properties. The interactions between hyaluronic acid and poly(vinyl alcohol) and/or borax were investigated by rheological measurements. Preparation parameters of the aqueous mixtures were mixture composition, the degree of hydrolysis of poly(vinyl alcohol) and borax concentration. From the rheological behavior, it could be deduced that the key factor of the interaction between hyaluronic acid and poly(vinyl alcohol) was the hydrogen bonding between them and the effect was pronounced with borax. Enhanced viscosity was observed at the composition of $20wt\%$ of hyaluronic acid solution and $80wt\%$ of poly(vinyl alcohol) and borax solution. Rheological properties were influenced by the degree of hydrolysis of poly(vinyl alcohol) and borax concentration. As the degree of hydrolysis and borax concentration increased, rheological properties increased due to the increased hydrogen bonding and networking of hyaluronate aggregates. Physical hydrogels from hyaluronic acid and poly(vinyl alcohol) were prepared and the composition dependence of the gels was rheologically investigated as well.

• 한국도로학회논문집
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• 제15권2호
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• pp.73-81
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• 2013

PURPOSES : In this study, various laboratory tests were performed to investigate basic physical properties of the asphalt concrete which uses wasted vinyl aggregates. METHODS : The thermal conductivity, ultrasonic velocity, Marshall stability, flow, indirect tensile strength were measured according to binder content and wasted vinyl aggregate content. An experimental construction was performed to verify construct ability of the asphalt pavement using the wasted vinyl aggregates. RESULTS : The thermal conductivity and ultrasonic velocity decreased showing insulation effect by mixing more wasted vinyl aggregate, whereas stability and flow increased. The void ratio shows similar value regardless of the mixing ratio. The highest indirect tensile strength was measured at 2.5% of wasted vinyl aggregate content. The construct ability was verified by observing the process of mixing, placing, and compaction and the state of the pavement surface. CONCLUSIONS : The basic properties and construct ability of the asphalt concrete using the wasted vinyl aggregates were verified. The temperature according to pavement depth will be measured to verify the insulation effect of the wasted vinyl aggregates. In addition, amount of snowfall, snowmelt area, and ice adhesion strength will be analyzed quantitively.

• 폴리머
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• 제33권3호
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• pp.230-236
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• 2009

비닐 아세테이트/알킬메타크릴레이트계 에멀젼 공중합에서 반응온도, 개시제의 종류와 농도, 보호콜로이드인 PVA의 종류와 농도, 공단량체인 MMA, EMA의 조성비를 변화시키며 중합하였다. 제조된 공중합체인 poly(vinyl acetate-co-methyl methacrylate)(PVAc/PMMA), poly(vinyl acetate-co-ethyl methacrylate)(PVAc/PEMA)를 수분 측정기를 사용하여 100, 130, 150, 180, $200^{\circ}C$에서 등온건조 시키고, 그 건조 특성을 고찰하여 다음과 같은 결론을 얻었다. 등온법으로 얻은 중합체 고형화 과정의 활성화 에너지는 PVAc/PMMA> PVAc/PEMA> PVAc의 순으로 공단량체의 곁사슬의 탄소수 증가에 따라 감소하였다. 접착박리강도는 동일한 조성의 공중합체에서 보호콜로이드 함량에 비례하여 증가하였고, 내수 접착박리강도는 최적의 보호콜로이드 함량에서 공단량체의 종류와 함량에 따라 PVAc/PMMA>PVAc/PEMA>PVAc 순이다.

• 한국산업융합학회 논문집
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• 제26권4_2호
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• pp.599-603
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• 2023

Analyzed in the NFDS, The average number of fires in vinyl temporary buildings is more than 1,000 in annually. And the number of deaths and injuries was around 30 people in every year. According to the National Fire Agency, There are 142,386 vinyl temporary buildings for Agriculture and Fishery, of which 4,720 are residential vinyl temporary buildings in illegally. Model house is subject to regulation in fire-related law. But, even though it's the same temporary building, Vinyl temporary building is not subject to regulation. For this reason, Vinyl temporary buildings are left in the blind spot of fire safety. Therefore, In this study, We propose that amend of Act on installation and management of firefighting systems, make of temporary fire safety controller, develop and apply of alarm system that is connected to a single-alarm smoke dretector, organize and operate volunteer fire brigade of the crop group to prevent and extinguish the fire.