• Title/Summary/Keyword: vinyl

Search Result 2,424, Processing Time 0.027 seconds

Formaldehyde Free Cross-linking Agents Based on Maleic Anhydride Copolymers

  • Yoon, Kee-Jong;Woo, Jong-Hyung;Seo, Young-Sam
    • Fibers and Polymers
    • /
    • v.4 no.4
    • /
    • pp.182-187
    • /
    • 2003
  • Low molecular weight copolymers of maleic anhydride and vinyl acetate were prepared to develop formaldehyde free cross-linking agents. Since lower molecular weight is favorable for efficient penetration of the finishing agent into the cotton fibers in the padding process, the concentration of the initiator, chain transfer agent and the monomer ratios were varied to obtain copolymers of low molecular weights. The prepared polymers were characterized by GPC, $^1{H-NMR}$, FTIR, DSC and TGA. Copolymers of molecular weights of 2 000 to 10 000 were obtained and it was found that the most efficient method of controlling the molecular weight was by varying the monomer ratios. Poly(maleic anhydride-co-vinyl acetate) did not dissolve in water, but the maleic anhydride residue hydrolyzed within a few minutes to form poly(maleic acid-co-vinyl acetate) and dissolved in water. However, the maleic acid units undergo dehydration to form anhydride groups on heating above ${160}^{\circ}C$ to some extent even in the absence of catalysts. The possibility of using the copolymers as durable press finishing agent for cotton fabric was investigated. Lower molecular weight poly(maleic anhydride-co-vinyl acetate) copolymers were more efficient in introducing crease resistance, which appears to be due to the more efficient penetration of the cross-linking agent into cotton fabrics. The wrinkle recovery angles of cotton fabrics treated with poly(maleic anhydride-co-vinyl acetate) copolymers were slightly lower than those treated with DMDHEU and were higher when higher curing temperatures or higher concentrations of copolymer were used, and when catalyst, $NaH_2$$PO_2$, was added. The strength retention of the poly(maleic anhydride-co-vinyl acetate) treated cotton fabrics was excellent.

Pressure Sensitive Adhesive Properties of Blends of Acrylic Quarternary Copolymer with Vinyl Chloride-Vinyl Propionate Copolymers (아크릴계 4원 공중합체와 염화비닐-비닐프로피오네이트 공중합체와의 블렌드의 점착물성)

  • Oh, Dae-Hee;Seo, Kwan-Ho
    • Elastomers and Composites
    • /
    • v.34 no.4
    • /
    • pp.360-365
    • /
    • 1999
  • In this study, the blends of acrylic quaternary polymer (PEBEV) which was co- polymerized from 2-ethylhexyl acrylate (2-EHA), n-butyl acrylate (BA) and ethyl acrylate (EA), vinyl acetate (VAc), and poly(vinyl chloride-co-vinyl propionate) (PVCVP) were prepared by solution blending. Pressure sensitive adhesive (PSA) properties of PEBEV/PVCVP blends were compared with those of PEBEV/poly(vinyl chloride-co-vinyl acetate) (PVCVAc) blends. Compatibility of PEBEV/PVCVP was better than that of PEBEV/PVCVAc. Tackiness of both blend systems were similar, but holding power began to decrease at 15wt% or higher PVCVAc contents in PEBEV/PVCVAc blends. On the other hands, holding power of PEBEV/PVCVP increased as the contents of PVCVP increased. Failure modes of the blends were adhesive failure except 5wt% of PVCVP was blended.

  • PDF

Automated Vinyl Green House Identification Method Using Spatial Pattern in High Spatial Resolution Imagery (공간패턴을 이용한 자동 비닐하우스 추출방법)

  • Lee, Jong-Yeol;Kim, Byoung-Sun
    • Korean Journal of Remote Sensing
    • /
    • v.24 no.2
    • /
    • pp.117-124
    • /
    • 2008
  • This paper introduces a novel approach for automated mapping of a map feature that is vinyl green house in high spatial resolution imagery Some map features have their unique spatial patterns. These patterns are normally detected in high spatial resolution remotely sensed data by human recognition system. When spatial patterns can be applied to map feature identification, it will improve image classification accuracy and will be contributed a lot to feature identification. In this study, an automated feature identification approach using spatial aucorrelation is developed, specifically for the vinyl green house that has distinctive spatial pattern in its array. The algorithm aimed to develop the method without any human intervention such as digitizing. The method can investigate the characteristics of repeated spatial pattern of vinyl green house. The repeated spatial pattern comes from the orderly array of vinyl green house. For this, object-based approaches are essential because the pattern is recognized when the shapes that are consists of the groups of pixels are involved. The experimental result shows very effective vinyl house extraction. The targeted three vinyl green houses were exactly identified in the IKONOS image for a part of Jeju area.

Improvement of Cultural Practices for a New Aromatic Tabacco ST 375-4 II. Effects of Vinyl Pot Size and Number of Plants per Pot on the Seedling Growth (향끽미종 잎담배 ST375-4의 신재배법 연구 제2보 Vinyl pot 크기의 pot당 육묘주수가 이식묘의 생육특성에 미치는 영향)

  • Jeong, K.T.;Ban, Y.S.;Yu, I.S.
    • KOREAN JOURNAL OF CROP SCIENCE
    • /
    • v.26 no.4
    • /
    • pp.350-356
    • /
    • 1981
  • An experiment was carried out to investigate the effect of the vinyl pot size and number of plants per pot on the seedling growth. Dry weight per plant, coefficient of variance and dry weight/fresh weight ratio increased as pot size increased, but competitive index, unit productivity and top/root ratio decreased. Dry , weight per plant decreased with increase in number of plants per pot, but coefficient of variability, competitive index and unit productivity increased. Dry weight per plant of the check plot (1 seedling/3.5cm $\times$ 3.5cm pot) showed little difference between 3 plants/4cm x 4cm pot and 5 plants/5cm x 5cm pot. Temporary transplanting of five plants per 5cm $\times$ 5cm pot saved seedbed area and seedbed materials by 60.9% and labor of transplanting by 36.3% as compared with check plot.

  • PDF

The Association between Vinyl House Work and Low Back Pain among Some Rural Residents (일부 농촌지역주민의 비닐하우스 작업여부와 요통과의 관련성)

  • Kim, Kwi-Nam;Ryu, So-Yeon;Park, Jong;Lee, Jun-Haeng;Kim, Ki-Soon
    • Journal of agricultural medicine and community health
    • /
    • v.24 no.1
    • /
    • pp.145-159
    • /
    • 1999
  • To find the association, between vinyl house work and the prevalence of low back pain, a questionnaire survey was made toward 215 vinyl house farmers and 228 general farmers without vinyl house who are cared by Jungjung Community health Practioners at Soobuk Myun, Damyang-gun, Chollanamdo. 1. Vinyl house farmers were significantly younger in age, higher in educational status higher survival rate of spouse, higher economic state and less cared by medical aid than general farmers. 2. Vinyl house farmers showed shorter career for agricultural work, used modern farming instrument more frequently and worked with sitting position. 3. During unbusy season in general agriculture, vinyl house farmers consumed significantly more time in agricultural work and general activity, but no significant difference of time of the above activity among busy season. 4. During the last spring season when most vinyl house work was performed, vinyl house farmers showed significantly higher prevalence of low back pain than general farmers, but no significant difference of prevalence among the two groups for the last one week. 5. By the simple analysis statistical significant related variables with low back pain was found to be sex(p<0.001), educational status(p<0.05), work posture(p<0.001) and use of modern agricultural machine(p<0.05). 6. By the multiple logistic regression the odds ratio for low back pain among vinyl house farmers were 2.08(95% confidence interval 1.31-3.00) compared to general farmers, the odds ratio among female was 2.35(95% confidence interval 1.24-4.47) to male, the odds ratio among illiterate persons were 2.60(95% confidence interval 1.24-4.47) to high school graduate, and the odds ration among primary school graduate was 2.19(95% confidence interval 1.04-4.47) to high school graduate. In conclusion because vinyl house farmers showed significantly higher rates of low back pain compared to farmers without vinyl house, continuous study to find the true cause of low back pain among vinyl-house farmers and active effort to prevent low back pain are necessary.

  • PDF

Growth and Seed Quality as Affected by Growing Condition in Sesame (참깨 재배조건에 따른 생육과 품질)

  • 김동관;국용인;천상욱;강명화;이주철;김명석;박규철
    • KOREAN JOURNAL OF CROP SCIENCE
    • /
    • v.47 no.6
    • /
    • pp.443-447
    • /
    • 2002
  • This study was carried out to determine the differences in the growth, grain yield, and seed quality of sesame plant according to seeding date between P,E. vinyl-house and outdoor cultures. Reproductive growth period in vinyl-house culture was shorter than in outdoor culture. Stem length and capsule setting length of sesame were much longer in vinyl-house culture than in outdoor culture. Also, number of capsules per plant and 1,000 grain weight in vinyl-house culture were higher, specially the grain yield was approximately 57% more than in outdoor culture. In vinyl house culture, sesame plants sown on June 8 had longer capsule setting length, more capsules per plant, higher 1,000 grain weight, and higher percent ripened grain at the upper part of the capsule settings than those sown in May 9. They also had higher 1,000 grain weight at the middle and lower part of the capsule settings compared to May 9 seeding. However, no difference in grain yield of in seeding dates was observed. In outdoor culture, sesame plants, which was sown on May 9, had more effective branch number and capsule number and plant compared to those sown on June 8. Though sesame plants sown on May 9 had lower percent ripened grain at the upper and middle part of the capsule settings and lower 1,000 grain weight, the seed yield was similar to those sown on June 8. No difference in chromaticity value $L^*$ of sesame seeds between two culture conditions was observed. The $a^*$ value was higher in vinyl-house culture than outdoor culture while $b^*$ value was higher in outdoor culture. Sesaminol triglucoside content of sesame seeds was higher in vinyl-house culture than in outdoor culture. On the other hand, the content of sesamin and sesamolin from sesame seeds in vinyl-house culture were lower than in outdoor culture.