• 한국산업보건학회지
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• 제3권1호
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• pp.91-98
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• 1993

This study was carried out to investigate characteristic of vinyl chloride emissioned from poly vinyl chloride extrusion process and to evaluate the efficiency of local exhaust ventilation system. Before local ventilation facility was constructed in poly vinyl chloride extrusion process, the average worker exposure to vinyl chloride was 3.15 ppm, which exceeded Threshold Limit Value of American Conference of Gorvernmental Industrial Hygienists (ACGIH-TLV), 1 ppm. lt is possible that vinyl chloride residues in the poly vinyl chloride resin was released or degased due to extrusion heat. The larger the width of vinyl tube become, the higher worker exposure to vinyl chloride was. It is estimated that vinyl chloride from vinyl chloride resin increased as amount of poly vinyl chloride resin extruded in the extrusion process increased. Canopy hood was an appropriate type for poly vinyl chloride resin extrusion process. This local exhaust ventilation has fan static pressure of 7.65 inch wg($190mmH_2O$, total volumetric flowlate of 4,796 CFM ($135.8m^3$/min) and fan power requirement of 12 hp (8.952 Kw). After this local exhaust ventilation was constructed there, the average concentration of worker exposure to vinyl chloride was reduced to be 0.46 ppm, which was below the Threshold Limit Value, 1 ppm. Also, the removal efficiency rate of vinyl chloride attained by local exhaust ventilation was 85.3%. It was a statistically significant (p<0.01).

• 한국안전학회지
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• 제34권5호
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• pp.72-77
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• 2019

Vinyl house consists of main rafter, lateral member, clamps and polyethylene film. Many vinyl houses are used to grow fruits, flowers and vegetables in the countryside. Due to climate change, vinyl houses are often destroyed by strong winds or typhoons in summer. Many farmers suffer great economic damage from the collapse of vinyl houses. So it is very important to build a safe vinyl house and find a method to withstand this heavy wind load. In this study, a structural analysis was performed on four types of vinyl houses(10-single-4, 10-single-6, 10-single-7, 10-single-10). In addition, axial force and flexural moment are obtained from the structural analysis of four types of vinyl house. For these four types of vinyl house, structural safety was reviewed by obtaining the combined stress ratio by the strength design method. This structural review showed that the specifications for the vinyl house proposed in the design are not safe. Especially, the result of structural analysis for four types of vinyl house showed that the vinyl house structure constructed as a standard was a very dangerous structure. Therefore, it is necessary to devise diverse methods in order to make vinyl houses structurally safe for heavy wind load in the future. Also a variety of manual development is needed to prevent the collapse of vinyl houses at heavy wind load.

• 한국안전학회지
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• 제34권2호
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• pp.34-39
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• 2019

Vinyl house consists of main rafter, lateral member, clamps and polyethylene film. Many vinyl houses are used in the countryside to grow vegetables. These vinyl houses have occasionally been collapsed due to heavy snowfall in winter. Many farmers get a lot of economical damages, if vinyl houses are collapsed. So it is most important to built a safe vinyl house that can withstand heavy snowfall. In this study, a structural analysis was performed on three types of vinyl houses(07-single-01, 10-single-04, 12-single-01). In addition, the structural analysis of the three types of vinyl houses provided axial forces, flexural moment, and combined stress. For these three types of vinyl houses, structural safety was reviewed by obtaining the combined stress ratio by the strength design method. This structural review showed that the specifications for the vinyl house proposed in the design are not safe. Especially, the result of increasing the design snow load by 15 percent and 30 percent showed that the vinyl house structure constructed as a standard for vinyl house was a more dangerous structure. Therefore, it is necessary to revise regulations such as increasing the thickness of rafters or widening the gap in order to make vinyl houses structurally safe for heavy snowfall in the future, and to devise diverse methods to make vinyl houses that are structurally safe.

• Macromolecular Research
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• 제11권3호
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• pp.202-205
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• 2003

The reactive precursors, vinyl ethers, and epoxy-silicones, were synthesized. The vinyl ether monomers were prepared from primary alcohol and ethyl vinyl ether with mercury (II) acetate. The epoxy-functionalized silicones have been achieved by the controlled, rhodium-catalyzed, chemoselective hydrosilation of vinyl ether with siloxanes or silane. It was shown that the hydrosilation proceeds exclusively at the vinyl ether group of alkenyl vinyl ether without participation at the alkenyl group. The photoinduced cationic polymerization of these monomers was studied and found to be all highly reactive.

• 공업화학
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• 제10권1호
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• pp.85-92
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• 1999

고정층 촉매 반응기를 이용하여 ${\gamma}$-알루미나에 담지한 크롬산화물 촉매상에서 vinyl chloride의 완전산화잔응을 $240{\sim}300^{\circ}C$의 온도와 600~3,500 ppm의 농도범위에서 조사하였다. 반응은 vinyl chloride의 농도에 대하여 비선형적으로 변하였으며, 산소의 농도에 대하여는 0차 거동을 보였다. 또한 반응 생성물인 $H_2O$와 HCl를 반응물에 첨가하였을 때 vinyl chloride의 전환율에 영향이 거의 없었다. Vinyl chloride의 산화반응에 대한 몇 가지 반응모델을 가정하고 실험결과와 상관시켜 가장 잘 일치하는 모델을 도출하였다. 속도식의 해석결과 vinyl chloride의 산화반응은 산소로 피복된 촉매표면에 vinyl chloride가 흡착한 후 산화분해되며, vinyl chloride가 촉매표면에 흡착하여 반응을 방해한다는 가정하에서 도출된 반응속도 모델이 실험결과를 가장 잘 표현하였다. 실험치와 예측치간의 표준편차 백분율은 약 5.2% 정도였으며 활성화에너지는 18.9 kcal/mol으로 계산되었다.

• 한국응용과학기술학회지
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• 제13권2호
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• pp.77-84
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• 1996

Poly(vinyl acetate)와 poly(vinyl acetate-co-2-ethylhexyl acrylate)를 여러 조건에서 semicontinuous emulsion 중합으로 합성하였다. Overall conversion, emulsion 입자크기, pH, 점도 등을 합성한 두 emulsion polymer에 대해 측정하였다. Vinyl acetate monomer에 2-ethylhexyl acrylate를 도입함으로서 emulsion 입도, 점도, 중합 속도, 유리 전이 속도가 감소함을 확인하였다.

• 한국섬유공학회:학술대회논문집
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• 한국섬유공학회 1998년도 봄 학술발표회 논문집
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• pp.130-134
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• 1998

The physical properties of poly(vinyl alcohol) (PVA) are highly dependent on the degree of syndiotacticity, which is determined primarily by the choice of the vinyl ester monomer precursor. Efforts to produce more syndiotactic PVAs, as well to increase the molecular weight, have centered on the polymerization of vinyl trifluoroacetate,$^1$ vinyl trichloroacetate,$^2$ and vinyl pivalate (VPi).(omitted)

• Korean Chemical Engineering Research
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• 제49권1호
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• pp.56-61
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• 2011

Methyl vinyl ether, propyl vinyl ether, isopropyl vinyl ether, butyl vinyl ether 그리고 isobutyl vinyl ether 등의 alkyl vinyl ether는 화학 및 의약산업에서 용매와 합성중간체로 널리 사용된다. 최근 들어 alkyl vinyl ether는 고분자 전해질막 연료 전지에 대한 원료와 셀룰로오스의 염색가공에 선호되나, 공정 및 운전변수의 최적화를 위한 alkyl vinyl ether계의 혼합물성은 극히 일부가 보고되고 있고, propyl vinyl ether(PVE)에 대한 상평형과 물성 데이터는 거의 알려진 바가 없다. 따라서 본 연구는 {PVE + ethanol + benzene} 삼성분계 333.15 K에서 기액평형을 headspace gas chromatography (HSGC)을 이용하여 측정하였고 Wilson, NRTL 및 UNIQUAC 식에 상관시켰다. 또한 삼성분계를 구성하는 혼합물성으로써 {PVE + ethanol}, {ethanol + benzene} 그리고 {PVE + benzene}계에 대한 과잉부피($V^E$) 및 굴절율 편차(${\Delta}R$)를 303.15 K에서 측정하였다. 측정된 이성분계 혼합물성은 Redlich-Kister 다항식을 이용하여 매개변수를 상관시켰으며, 이를 이용하여 Radojkovi 식으로 삼성분계 혼합물성을 예측하였다.

• Macromolecular Research
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• 제10권6호
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• pp.339-344
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• 2002

Poly(vinyl alcohol-b-styrene) (poly(VA-b-St)) diblock copolymer containing high syndiotactic poly (vinyl alcohol) (PVA) was synthesized by the saponification of poly(vinyl pivalate-b-styrene) (poly(VPi-b-St)). For the block copolymer, poly(vinyl pivalate) (PVPi) with trichloromethyl end group was obtained via telomerization of vinyl pivalate with carbon tetrachloride as a telogen and 2,2-azobisisobutyronitrile (AIBN) as an initiator. Then resulting poly(vinyl pivalate) with trichloromethyl end group was used as an effient macroinitiator for the synthesis of poly(VPi-b-St) using atom transfer radical polymerization (ATRP) in the presence of CuCl/2,2'-bipyridine at 130 $^{\circ}C$. The poly(vinyl pivalate) macroinitiator, poly(VPi-b-St), poly(VA-b-St) were characterized by GPC, FT-IR and $^1$H-NMR. And the analysis showed that integrity of the block copolymer was maintained during saponification reaction.

• 한국잠사곤충학회지
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• 제16권2호
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• pp.141-146
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• 1974

실내 vinyl house내에서 간이 공동사육을 위한 치잠기 특수사육의 가능성 여부를 구명하고자 실내 vinyl house육과 보습방건지육, 보통육을 비교시험을 한 결과는 다음과 같다. 1. 실내 vinyl house육은 보통육 및 방건지육에 비하여 온습도를 합리적으로 조절할 수 있었으며 모든 작업도 편리하였다. 2. 경과일시수는 실내 vinyl house육구와 보습방건지육에는 같았고 보통육구는 실험구에 비하여 춘잠치잠기에 5시간 추잠 치잠기에 6시간 길었다. 3. 감잠비율에 있어서는 춘추 공히 실내vinyl house육구와 보습방건지육구간에는 큰 차이는 없었지만 실내 vinyl house육구에서 감잠수가 약간 적었고 보통육구에서 높은 경향이었다. 4. 각견비율은 춘추 공히 유의성은 없었지만 특수육의 경우 상견비율이 높았고 보통육의 경우 중하견비율이 높은 경향이었다. 5. 대4령 기잠 1만두 수견량은 춘추잠기 공히 실내 vinyl house육구가 높은 경향이었다. 6. 견층비율은 춘추 공히 유의성은 없었지만 보통육구에 비하여 방건지육구와 실내 vinyl house 육구가 높은 경향이었다. 7. 상기의 시험결과를 종합 검사하면 실내 vinyl house육구는 대조구에 비하여 1일 3회 급상으로도 좋은 성적을 얻었으므로 간이 공동사육을 위한 치잠기특수사육장으로서 적합하다고 사료된다.