• Title/Summary/Keyword: vaporization rate

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Decomposition of PVC and Ion exchange resin in supercritical water

  • Lee, Sang-Hwan;Yasuyo, Hosgujawa;Kim, Jung-Sung;Park, Yoon-Yul;Hiroshi, Tomiyasu
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2005.05a
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    • pp.267-271
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    • 2005
  • This experiment was carried out at 450"C, which is relatively lower than the temperature for supercritical water oxidation (600-650$^{\circ}C$). In this experiment, the decomposition rates of various incombustible organic substances were very high. In addition, it was confirmed that hetero atoms existed in organic compounds and chlorine was neutralized by sodium(salt formation).However, to raise the decomposition rate, relatively large amount of sodium nitrate(3-4 times the equivalent weight) was required. When complete oxidation is intended as in the case with PCB, the amount of oxidizer and decomposition cost is important. But when vaporization reduction is required as in the case with nuclear wastes, the amount of radioactive wastes increases instead. But as can be seen in the result of XRD measurement, unreacted sodium nitrate remained unchanged. If oxidation reaction of organic substance simply depends on collision frequency, unreacted sodium nitrate can be recovered and reused, then oxidation equivalent weight would be sufficient. In the gas generated, toxic gas was not found. As the supercritical water medium has high reactivity, it is difficult to generate relatively low energy level SO$_{X}$, and NO$_{X}$.

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A Pilot Study of Skin Resurfacing Using the 2,790-nm Erbium:YSGG Laser System

  • Rhie, Jong Won;Shim, Jeong Su;Choi, Won Seok
    • Archives of Plastic Surgery
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    • v.42 no.1
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    • pp.52-58
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    • 2015
  • Background The erbium:yttrium scandium gallium garnet (Er:YSGG) laser differs from other laser techniques by having a faster and higher cure rate. Since the Er:YSGG laser causes an appropriate proportion of ablation and coagulation, it has advantages over the conventional carbon dioxide ($CO_2$) laser and the erbium-doped yttrium aluminum garnet (Er:YAG) laser, including heating tendencies and explosive vaporization. This research was conducted to explore the effects and safety of the Er:YSGG laser. Methods Twenty patients participated in the pilot study of a resurfacing system using a 2,790-nm Er:YSGG laser. All patients received facial treatment by the 2,790-nm Er:YSGG laser system (Cutera) twice with a 4-week interval. Wrinkle reduction, reduction in pigment inhomogeneity, and improvement in tone and texture were measured. Results Study subjects included 15 women and five men. Re-epithelization occurred in all subjects 3 to 4 days after treatment, and wrinkle reduction, reduction in pigment inhomogeneity, and improvement in tone and texture within 6 months of treatment. Conclusions The 2,790-nm YSGG laser technique had fewer complications and was effective in the improvement of scars, pores, wrinkles, and skin tone and color with one or two treatments. We expect this method to be effective for people with acne scars, pore scars, deep wrinkles, and uneven skin texture and color.

Flame and Combustion Characteristics of D.I. HCCI Diesel Engine using a Visualization Engine (가시화 엔진을 이용한 직분식 예혼합 압축착화 디젤엔진의 화염 및 연소특성)

  • 권오영;류재덕;이기형;이창식
    • Transactions of the Korean Society of Automotive Engineers
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    • v.10 no.6
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    • pp.100-107
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    • 2002
  • Combustion characteristics of diesel engine depends on mixture formation process during Ignition delay and premixed flame region. Fuel and air mixture formation has a great influence on the exhaust emission. Therefore, the present study focused on the combustion mechanism of Homogeneous Charge Compression Ignition (HCCI) engine. This study was carried out to investigate the combustion characteristics of direct injection type HCCI engine using a visualization engine. To investigate the combustion characteristics, we measured cylinder pressure and calculated heat release rate. In addition, we investigated the flame development process by using visualization engine system. From the experimental result of HCCI engine, we observed that cool flame was always appeared in HCCI combustion and magnitude of cool flame was proportional to magnitude of hot flame. And we also found that fuel injection timing is more effective to increase lean homogeneous combustion performance than intake air temperature. Since increasing the intake air temperature improved fuel vaporization before the fuel atomizes, we concluded that increasing the temperature has disadvantage fur homogeneous premixed combustion.

Fracture and Hygrothermal Effects in Composite Materials (복합재의 파괴와 hygrothermal 효과에 관한 연구)

  • Kook-Chan Ahn;Nam-Kyung Kim
    • Journal of the Korean Society of Safety
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    • v.11 no.4
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    • pp.143-150
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    • 1996
  • This is an explicit-Implicit, finite element analysis for linear as well as nonlinear hygrothermal stress problems. Additional features, such as moisture diffusion equation, crack element and virtual crack extension(VCE ) method for evaluating J-integral are implemented in this program. The Linear Elastic Fracture Mechanics(LEFM) Theory is employed to estimate the crack driving force under the transient condition for and existing crack. Pores in materials are assumed to be saturated with moisture in the liquid form at the room temperature, which may vaporize as the temperature increases. The vaporization effects on the crack driving force are also studied. The Ideal gas equation is employed to estimate the thermodynamic pressure due to vaporization at each time step after solving basic nodal values. A set of field equations governing the time dependent response of porous media are derived from balance laws based on the mixture theory Darcy's law Is assumed for the fluid flow through the porous media. Perzyna's viscoplastic model incorporating the Von-Mises yield criterion are implemented. The Green-Naghdi stress rate is used for the invariant of stress tensor under superposed rigid body motion. Isotropic elements are used for the spatial discretization and an iterative scheme based on the full newton-Raphson method is used for solving the nonlinear governing equations.

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Char Oxidation Characteristics of High Ash Coal in Drop Tube Furnace (고회분탄의 촤 산화 반응 특성 연구)

  • An, Ke-Ju;Lee, Byoung-Hwa;Kim, Sang-In;Kim, Man-Cheol;Kim, Seung-Mo;Jeon, Chung-Hwan
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.37 no.4
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    • pp.405-413
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    • 2013
  • The char oxidation characteristics of high ash coal were experimentally investigated at several temperatures (from 900 to $1300^{\circ}C$) for 4 types of coals (Gunvor, Glencore, Noble, and ECM) under atmospheric pressure in a drop tube furnace (DTF). The char reaction rate was calculated from the exhaust gas concentrations (CO and $CO_2$) using FT-IR, and the particle temperature was measured using the two-color method. In addition, the activation energy and pre-exponential factor for high ash coal char were calculated based on the Arrhenius equation. The results show that as the ash content increases, the particle temperature and area reactivity decreases. This is because in high ash coal, the large heat capacity of the ash, ash vaporization, and relatively low fixed carbon content of ash suppress combustibility during char oxidation. As a result, the higher ash content of coal leads to high activation energy.

A Study on the Combustion Characteristic in Hybrid Rocket Motor using PE/$LN_2O$ (PE/$LN_2O$ 하이브리드 로켓 모터의 연소특성에 관한 연구)

  • Kim, Gi-Hun;Lee, Jung-Pyo;Kim, Soo-Jong;Cho, Jung-Tae;Kim, Hak-Chul;Woo, Kyoung-Jin;Sung, Hong-Gye;Moon, Hee-Jang;Kim, Jin-Kon
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2009.05a
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    • pp.233-236
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    • 2009
  • In this study, the characteristic of the hybrid rocket motor with $LN_2O$(Liquid Nitrous oxide) was investigated experimentally. HDPE(High Density PolyEthlene) was used as fuel with different sized single port. When used $LN_2O$, combustion efficiency is lower than using $GN_2O$(Gas Nitrous oxide), because of completeness of vaporization of droplet and mixing. And regression rate was changed by different oxidizer phase. This behavior was considered that flame temperature and combustion of solid fuel front/end surface.

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Enhancement of Desulfurization System Efficiency in 1,000 MW Coal-Fired Power Plants (1,000 MW 석탄화력발전소 대기환경오염물질 제거효율 향상을 위한 탈황설비 성능개선)

  • Lee, Young-Su;Moon, Seung-Jae
    • Plant Journal
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    • v.17 no.2
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    • pp.32-41
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    • 2021
  • Recently, air environmental issues such as fine dust have rapidly emerged as national issues, and intensive environmental regulations are being applied to coal-fired power plants. This study introduces the case of improving the performance of desulfurization facilities for removing sulfur oxides and dust, which are the main air pollutant emitters of coal-fired power plants, and conducted four case studies to improve the performance of 1,000 MW power plants currently in operation and carried out construction. Liquid ratio was increased by remodeling the absorption tower of desulfurization facilities, and vaporization reaction was promoted by increasing the flow rate of oxidized air. In addition, the gas heater leakage rate was improved to improve the efficiency of final desulfurization facilities. It is expected that performance improvement work considering harmony with existing facilities will satisfy the regulations(25ppm of sulfur oxides, 5mg/Sm3) that will be applied from 2023, and can be referred to other thermal power plants for review and application.

Revisiting Horton Index Using a Conceptual Soil Water Balance Model (개념적인 토양수분수지 모형을 이용한 Horton 지수의 재논의)

  • Choi, Daegyu;Kim, Sangdan
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.30 no.5B
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    • pp.471-477
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    • 2010
  • In this study, the variability of the Horton index which is ratio of vaporization and wetting water is investigated using a conceptual soil water balance model. From the proposed model, the steady-state soil water probabilistic density function is derived through meteorological and watershed characteristics and then the sensitivity of Horton index to the precipitation occurrence rate and the mean of wet day precipitation is examined. As a result, the inter-annual variability of the Horton index is lower than that of precipitation and they showed the strong negative correlation. It is also shown that although precipitation is not varied, the Horton index can be varied due to the fluctuation of the precipitation occurrence rate and the mean of wet day precipitation. In addition, it is presented that there is a non-linear relationship which has a critical point switching proportional or inverse relationship between the Horton index and two main characteristics of precipitation process.

An Experimental Study on Spray Characteristics of Directly Injected Bio-Ethanol-Gasoline Blended Fuel By Varying Fuel Temperature (직접분사식 바이오 에탄올-가솔린 혼합연료의 연료온도에 따른 분무 특성에 관한 실험적 연구)

  • Lee, Seangwook;Park, Giyoung;Kim, Jongmin;Park, Bongkyu
    • Transactions of the Korean hydrogen and new energy society
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    • v.25 no.6
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    • pp.636-642
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    • 2014
  • As environment problem became a worldwide issue, countries are tightening regulations regarding greenhouse gas reduction and improvement of air pollution problems. With these circumstances, one of the renewable energies produced from biomass is getting attention. Bio-ethanol, which is applicable to SI engine, showed a positive effect on the PFI (Port Fuel Injection) type. However, Ethanol has a problem in homogeneous mixture formation because it has high latent heat of vaporization characteristics and in the GDI (Gasoline Direct Injection) type, mixture formation is required quickly after fuel injection. Particularly, South Korea is one of the countries with great temperature variation among seasons. With this reason, South Korea supply fuel additive for smooth engine operation during winter. Therefore, experimental study and investigation about application possibility of blending fuel is necessary. This paper demonstrates the spray characteristics by using the CVC direct injection and setting the bio-ethanol blending fuel temperature close to the temperature during each seasons: -7, 25, $35^{\circ}C$. The diameter and the width of the CVC are 86mm and 39mm. High-pressure fuel supply system was used for target injection pressure. High-speed camera was used for spray visualization. The experiment was conducted by setting the injection pressure and ambient pressure according to each temperature of bio-ethanol blending fuel as a parameter. The result of spray visualization experiment demonstrates that as the temperature of the fuel is lower, the atomization quality is lower, and this increase spray penetration and make mixture formation difficult. Injection strategy according to fuel temperature and bio-ethanol blending rate is needed for improving characteristics.

Numerical Investigation on Soot Primary Particle Size Using Time Resolved Laser Induced Incandescence (TIRE-LII) (시분해 레이저 유도 백열법을 이용한 매연 입자 크기에 관한 수치적 연구)

  • Lee, Jong-Ho;Kim, Jeong-Yong;Jeong, Dong-Soo;Chang, Young-June;Jeon, Chung-Hwan
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.29 no.9 s.240
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    • pp.1022-1031
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    • 2005
  • Temporal behavior of the laser induced incandescence (LII) signal is often used for soot particle sizing, which is possible because the cooling behavior of a laser heated particle is dependent on the particle size. In present study, LII signals of soot particles are modeled using two non-linear coupled differential equations deduced from the energy- and mass-balance of the process. The objective of this study is to obtain an appropriate calibration curve for determining primary particle size by comparing the gated signal ratio and double-exponential curve fitting methods. Not only the effects of laser fluence and gas temperature on the cooling behavior but also heat transfer mechanisms of heated soot particle have been investigated. The second-order exponential curve fitting showed better agreements with the LII signals than the gated signal ratio method which was based on the lust-order exponential curve fit. And the temporal decay rate of the LII signal and primary particle size showed nearly linear relationship, which was little dependent on the laser fluence. And it also could be reconfirmed that vaporization was dominant process of heat loss during first loons after laser pulse, then heat conduction played most important role while thermal radiation had little influence all the time.