• 한국재료학회:학술대회논문집
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• 한국재료학회 2003년도 춘계학술발표강연 및 논문개요집
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• pp.137-137
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• 2003

Conducting PPy/PVA composite and pure PPy gas sensors were prepared by in-situ vaporstate polymerization method in a vaporization chamber under N2 condition, by exposing the pre-coated electrode with PVA/FeC13 to distilled pyrrole monomer. The various electrical sensing behaviors of both types of sensors were systematically investigated by a flow measuring system including mass flow controller (MFC) and bubbling bottle. The FT-Raman spectroscopy of vapor state polymerized PPy was identical to that of chemically polymerized PPy, confirming the same chemical structure. Both types of sensors had positive sensitivity when exposed to methanol gas. The sensitivity varied linearly with gas concentration in the range of 50ppm to 1059ppm. The detection limit of PPy/PVA sensor was believed to be as low as 10ppm. The sensitivity of PPy/PVA composite sensor was higher than that of pure PPy sensor. Both the response time and recovery time of PPy/PVA composite sensors were longer than those of pure PPy sensors. The thickness of the sensing film affected the sensitivity this way that the sensor having thinner film had higher sensitivity, indicating that the resistance of polymer film involved in the sensing behavior was bulk resistance rather than surface resistance. The reproducibility of PPy/PVA composite sensor was excellent during eight on-off cycles by switching between N2 and 3000ppm methanol gas. The sensitivity of PPy/PVA composite sensor was only maintained for two weeks, while the sensitivity of pure PPy sensor was maintained over two months.

• 대한기계학회논문집A
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• 제34권10호
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• pp.1507-1512
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• 2010

본 연구에서는 조선용 6mm 아연코팅강판의 $CO_2$ 레이저 겹치기 용접시 발생하는 유기 플라즈마를 마이크로폰과 포토다이오드로 측정하였다. 이때 겹치기 갭간극에 따른 용접조건을 RMS한 신호와 비교 분석하였다. 이를 통해 아연증발량이 증가함에 따라 RMS값도 증가하였으며, 겹침부의 조건에 따라 결함 발생시 RMS의 급격한 변화도 확인할 수 있었다. 또한 용접조건에 따른 Raw signal의 FFT값을 구한 후, 이때 구해진 주파수값을 밴드폭으로 설정하여 Raw signal을 필터링한 뒤의 RMS값을 용접비드와 대응하여 필터링하지 않은 RMS와의 차이점도 비교 분석하였다. 이를 통해 기존의 방법들보다 신뢰성 높은 In-process 모니터링이 가능함을 확인하였다.

• 자원환경지질
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• 제17권4호
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• pp.299-314
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• 1984

The Yeongdo Island in Busan City is a remnant of the latest Cretaceous volcano, and consists geologically of andesites, rhyolite tuff, pelitic and psammitic hornfelses, lapilli rhyodacite tuff of the Yucheon Group, felsite and felsite porphyry of the Bulgugsa intrusives, and Holocene sediments in ascending order. The hornfelses are bound to the Taejongdae Formation. The stratigraphic position of the Formation is determined definitely into the Yucheon Group, thus the geologic age is approximately the same with the volcanic rocks of the Group. The sediments had been thermally metamorphosed to make pelitic and psammitic hornfelses of the albite epidote hornfels facies by the effects of active hydrothermal circulation, vaporization, and hybridization of andesitic solution, or of basification of acidic intrusives. Thus, on occasion, those hornfelses are not used to be distinguished from the andesitic rocks in the southeastern part of the Korean peninsula. The paleocurrent direction determined from several cross-beddings of the Taejongdae Formation is suggested to be from southwest to northeast. Orbicular rocks occur in hornfelsed rhyolite tuff, pelitic- and psammitic-hornfelses, and felsite porphyry at a lot of outcrops in the area of southwestern shoreline of the Yeongdo Island. Orbicules in rhyolite tuff and hornfels in the island might have originated from diffusion processes of metasomatic metamorphism carried out by hydrothermal solution rised from the intrusive adamellite which may be emplaced deeply under the Yeongdo volcanics. Those orbicules are due to metasomatic, secondary, and epigenetic origin. Proto-, multi-shelled, and multi-cored orbicules are described in the orbicular tuff. But multi-cored orbicules are not found in the orbicular fornfels. 250 tuff-orbicules numbered sporadically are in $20,000m^2$ area of the locality of orbicular tuff. About 60 hornfels-orbicules occurred sporadically are in $1,700m^2$ area of the locality of orbicular hornfels in the Taejongdae Formation. Orbicules in felsite porphyry might have originated by diffusion reaction between xenoliths and a quiescent zone in felsite porphyry magma. Those are of igneous, primary, and syngenetic origin.

• 에너지공학
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• 제20권2호
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• pp.77-83
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• 2011

니켈 아연전지(Ni-Zn)를 산업용 전지로 이용하려면, 음극성능 향상이 필요하다. 기존의 니켈 아연전지(Ni-Zn)는 짧은 수명, 심한 가스발생 및 빠른 전해액 증발이 산업용 전지 상용화의 최대 문제점이었다. 본 연구에서 도전 촉진제, 첨가제 및 바인더를 변경하여, 8셀의 거동을 고찰하였다. 바인더 및 흡착 촉진제($Ca(OH)_2$, $Bi_2O_3$)의 종류를 변경한 결과, 기존보다 가스발생은 감소하면서, 균일하고 단단한 전극을 제조할 수 있었다. 또한 전해액에 EG-EP#12(비중 1.26) 보충함으로써 전지 내 전해액의 비중이 일정하게 유지되어, 전지의 수명이 기존보다 200~300%의 획기적인 성능 향상을 보였다.

• 수산해양기술연구
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• 제53권1호
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• pp.89-97
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• 2017

Butanol has an ability to improve the ignition quality due to its lower latent heat of vaporization; it has an advantage to reduce a volume of a fuel tank because its energy density is higher than that of ethanol. Also, butanol-diesel oil blending quality is good because butanol has an effect to prevent the phase-separation between two fuels. Even if the blended oil contains water, it can reduce the corrosion of the fuel line. Thus, it is possible to use butanol-diesel oil blended fuel in diesel engine without modification, and it may reduce the environment pollution due to NOx and particulate and the consumption of diesel oil. Therefore, some studies are being advanced whether butanol is adequate as an alternative fuel for diesel engines, and the results of the combustion and exhaust gas emission characteristics are being presented. Though the injection and spray characteristics of butanol are more important in diesel combustion, the has not yet dealt with the matter. In this study, the influence in which differences of physical properties between butanol and diesel oil may affect the injection and spray characteristics such as injection rate, penetration, spray cone angle, spray velocity and process of spray development were examined by using CRDI system, injection rate measuring device and spray visualization system. The results exhibited that the injection and macroscopic spray characteristics of two fuels were nearly the same.

• The Korean Journal of Pain
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• 제14권2호
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• pp.234-238
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• 2001

Percutaneous laser discectomy has potential advantages over conservative therapy and classical open surgery as a minimally invasive procedure, although clinical experiences are limited. We experienced a patient treated with herniated lumbar discs using Nd：YAG laser. A 55-year-old woman complained of severe back pain with sciatica on L4/5 and L5/S1 dermatome for several months. The MRI finding showed bulging discs at L4/5 and L5/S1. Epidural, transsacral and root block treatments were attempted without effect. Under fluoroscopic guidance, a 14 G biopsy needle was inserted into the L4/5 and L5/S1 disc spaces to the margin of the nucleus pulposus. Laser irradiation for vaporization of tissue was performed at 20 W/second to 1200 J. A laser fiber ($600{\mu}m$) was advanced 1 cm from the tip of the needle. At the end of the procedure, the patient began to feel relief of pain (VAS changed from 9 to 4) and was discharged the same day after staying 2 hours in the recovery room. Antibiotics were administered for prevention of discitis. She had no complaints of pain until the 1-month follow up visit. Percutaneous laser discetomy technique has the disadvantages of expensive equipment, high temperature and amount of vaporing disc tissue is empirical. However, this technique, as one of the therapeutic modalities for disc herniation, provides faster relief from acute attack than conservative management techniques in carefully selected patients with sciatica due to disc prolapse.

• Korean Chemical Engineering Research
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• 제58권3호
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• pp.390-395
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• 2020

몇몇 포화를 갖는 공정에서 경제적인 운전점이 포화시작점에 있게 된다. 고전적인 피드백 제어기는 포화시작점에서 동특성이 급박하게 바뀌고 포화가 된 상태에서는 피드백을 위한 정보가 없기 때문에 사용할 수가 없다. 포화점과 동특성이 알려져 있고 바뀌지 않을 때는 모델예측제어 같은 최적화를 기반으로 하는 방법들이 어려움 없이 이 제어 문제를 처리할 수 있다. 그렇지 않으면, 이 포화점과 등특성을 추적하는 적응 방법이 첨가되어야 한다. 여기서는, 이 제어 문제를 해결할 수 있는 매우 간단한 방법들로서, 최근의 slope seeking method와 relay feedback method에 기반한 두가지 제어 방법을 제안한다. 포화현상을 갖는 이차 액위제어 공정에 적용한 모사를 통하여 그 성능을 검사하였다. 모사결과는 제안하는 본 제어 방법들이 포화시작점을 5% 이내로 찾고 유지하는 것을 보여주고 있다.

• Journal of Welding and Joining
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• 제24권2호
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• pp.71-78
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• 2006

It has been reported that good quality weld beads are not easily obtained during the $CO_2$ CW laser welding of primer coated plate. However, by introducing a small gap clearance in the lap position, the zinc vapor can escape through it and sound weld beads can be acquired. Therefore, this study examines for keyhole behavior by observing the laser-induced plasma and investigates the relation between keyhole behavior and formation of weld defect. Laser-induced plasma has accompanied with the vaporizing pressure of zinc ejecting from keyhole to surface of primer coated plate. This dynamic behavior of plasma was very unstable and this instability was closely related to the unstable motion of keyhole during laser welding. As a result of observing the composition of porosity, much of Zn element was found from inner surface of porosity. But Zn was not found from the dimple structure fractured at the weld metal. By analyzing of vaporizing element in laser welding, a component ratio of Zn was decreased by introducing a small gap clearance. Therefore we can prove that the major cause of porosity is the vaporization of primer in lap position. Mechanism of porosity-formation is that the primer vaporized from the lap position accelerates dynamic behavior of the key hole and the bubble separated from the key hole is trapped in the solidification boundary and romaines as porosity.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2009년도 춘계학술대회 논문집
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• pp.233-236
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• 2009

산화제는 $LN_2O$, 고체연료는 HDPE(High Density PolyEthlene)를 사용하여 산화제의 상 및 연료포트 직경에 따른 하이브리드 로켓 모터의 연소특성을 비교 분석하였다. 불완전한 액적의 기화와 연료와 산화제의 혼합으로 인해 산화제로 $GN_2O$ 보다 $LN_2O$를 적용했을 때, 연소효율이 낮게 나타났다. O/F비에 따른 화염온도변화 및 끝 단면적에서의 연소반응으로 인해 $LN_2O$와 $GN_2O$를 사용하였을 경우 고체연료의 초기 포트 직경에 따른 후퇴율의 경향이 달리 나타났다.

• 한국결정성장학회지
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• 제18권2호
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• pp.81-86
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• 2008

열증착법(thermal evaporation method)에 의해 ZnO 나노선을 합성하였다. 나노선 합성조건에 따른 구조적 특성을 분석하여 그 합성 메카니즘을 확인하였다. ZnO 나노선 합성 시 기화 온도가 고온일수록 성장속도가 빠르고 $CO/CO_2$ 분압이 역전되는 1000$^{\circ}C$ 이상에서는 그 형태가 크게 변화하고, 성장온도 700$^{\circ}C$ 이상에서 Au 촉매가 그 기능을 하고 있음을 확인하였다. 성장된 ZnO 나노선은 380 nm에서의 blue emission을 나타냄을 확인하였다.