• Title/Summary/Keyword: vapor phase effects

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Similarity analysis of a forced uniform flow impinging on a rotating disk in a vapor deposition process (증착공정에서의 회전원판 정체점유동에 대한 상사해석)

  • Song, Chang-Geol;Hwang, Jeong-Ho
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.21 no.3
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    • pp.371-379
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    • 1997
  • A theoretical study for a forced uniform flow impinging on a rotating disk, typically involved in Chemical Vapor Deposition(CVD) and Vapor-phase Axial Deposition(VAD) processes, has been carried out. A set of exact solutions for flow and temperature fields are developed by employing a similarity variable obtained from force balance on a control volume near the disk. The solutions depend on the rotating speed of the disk, .omega., and the forced flow speed toward the disk, a. For constant forced flow speed, the overall boundary layer thickness decreases when the rotating speed increases. Approximately 5%, 15%, and 30% decreases of the thickness are obtained for .omega./a = 2, 5, and 10, respectively, compared to the case of .omega./a = 0 (axisymmetric stagnation point flow). For constant rotating disk speed the boundary layer thickness immediately decreases as the forced flow speed increases, compared to the case of .omega./a .rarw. .inf. (induced flow near a rotating disk). Effects of .omega. and a on heat transfer coefficient are studied and explained with the boundary layer characteristics.

Numerical Study of Land/Channel Flow-Field Optimization in Polymer Electrolyte Fuel Cells (PEFCs) (II) - The Effects of Land/Channel Flow-Field on Temperature and Liquid Saturation Distributions - (고분자전해질형연료전지의 가스 채널 최적화를 위한 수치적 연구 (II) - 가스 채널 치수가 온도와 액체포화 분포에 미치는 영향성 -)

  • Ju, Hyun-Chul;Nam, Jin-Moo
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.33 no.9
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    • pp.688-698
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    • 2009
  • Using the multi-dimensional, multi-phase, nonisothermal Polymer Electrolyte Fuel Cell (PEFC) model presented in Part I, the effects of land/channel flow-field on temperature and liquid saturation distributions inside PEFCs are investigated in Part II. The focus is placed on exploring the coupled water transport and heat transfer phenomena within the nonisothermal and two-phase zone existing in the diffusion media (DM) of PEFCs. Numerical simulations are performed varying the land and channel widths and simulation results reveal that the water profile and temperature rise inside PEFCs are considerably altered by changing the land and channel widths, which indicates that oxygen supply and heat removal from the channel to the land regions and liquid water removal from the land toward the gas channels are key factors in determining the water and temperature distributions inside PEFCs. In addition, the adverse liquid saturation gradient along the thru-plane direction is predicted near the land regions by the numerical model, which is due to the vapor-phase diffusion driven by the temperature gradient in the nonisothermal two-phase DM where water evaporates at the hotter catalyst layer, diffuses as a vapor form and then condenses on the cooler land region. Therefore, the vapor phase diffusion exacerbates DM flooding near the land region, while it alleviates DM flooding near the gas channel.

Comparison of GPS Antenna Calibration Models and Their Effects in Determination of Precipitable Water Vapors

  • Park, Kwan-Dong;Won, Ji-Hye;Ha, Ji-Hyun
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • v.2
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    • pp.41-45
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    • 2006
  • To get accurate positions of GPS antennas, one should apply phase center variations (PCV) corrections in the data processing. Until recently, relative calibrations, originally proposed by National Geodetic Survey of United States, were the international standard. However, in late 2006, International GNSS Service will switch to absolute calibration methods. In this study, we compared the position differences caused by different PCV models, and their effects on the calculations of Precipitable Water Vapor (PWV) in the atmosphere. Data from ${\sim}40$ permanent GPS stations in Korea were processed and we found that the vertical position differences reach up to 5 cm, depending on the model selected. Also the PWV values varied quite significantly: the maximum bias in the computed PWV values was ${\sim}4$ mm.

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Effects of impurity (N2) on thermo-solutal convection during the physical vapor transport processes of mercurous chloride

  • Kim, Geug-Tae;Kim, Young-Joo
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.20 no.3
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    • pp.117-124
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    • 2010
  • For Ar=5, Pr=1.18, Le=0.15, Pe=2.89, Cv=1.06, $P_B$=20 Torr, the effects of impurity $(N_2)$ on thermally and solutally buoyancy-driven convection ($Gr_t=3.46{\times}10^4$ and $Gr_s=6.02{\times}10^5$, respectively) are theoretically investigated for further understanding and insight into an essence of thermo-solutal convection occurring in the vapor phase during the physical vapor transport. For $10K{\leq}{\Delta}T{\leq}50K$, the crystal growth rates are intimately related and linearly proportional to a temperature difference between the source and crystal region which is a driving force for thermally buoyancy-driven convection. Moreover, both the dimensionless Peclet number (Pe) and dimensional maximum velocity magnitudes are directly and linearly proportional to ${\Delta}T$. The growth rate is second order-exponentially decayed for $2{\leq}Ar{\leq}5$. This is related to a finding that the effects of side walls tend to stabilize the thermo-solutal convection in the growth reactor. Finally, the growth rate is found to be first order exponentially decayed for $10{\leq}P_B{\leq}200$ Torr.

Application of thermodynamics to chemical vapor deposition

  • Latifa Gueroudji;Hwang, Nong-Moon
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1998.09a
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    • pp.1-20
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    • 1998
  • Processing of thin films by chemical vapor deposition (CVD) is accompanied by chemical reactions, in which the rigorous kinetic analysis is difficult to achieve. In these conditions, thermodynamic calculation leads to better understanding of the CVD process and helps to optimise the experimental parameters to obtain a desired product. A CVD phase diagram has been used as guide lines for the process. By determining the effect of each process variable on the driving force for deposition, the thermodynamic limit for the substrate temperature that diamond can deposit is calculated in the C-H system by assuming that the limit is defined by the CVD diamond phase diagram. The addition of iso-supersaturation ratio lines to the CVD phase diagram in the Si-Cl-H system provides additional information about the effects of CVD process variables.

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Control of Crystal Phase and Agglomeration of Iron Oxide Nanoparticles in Gas Phase Synthesis

  • Lee, Chang-Woo;Lee, Jai-Sung
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.424-425
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    • 2006
  • The effects of reaction temperature and precursor concentration on the microstructure and magnetic properties of ${\gamma}-Fe_2O_3$ nanoparticles synthesized as final products of iron acetylacetonate in chemical vapor condensation (CVC) were investigated. Pure ${\gamma}-Fe_2O_3$ phase was obtained at temperature above $900^{\circ}C$ and crystallite size of ${\gamma}-Fe_2O_3$ nanoparticles decreased with lowering precursor concentration. Also, the coercivity decreases with decreasing crystallite size of nanopowder. The lowest coercivity was 7.8 Oe, which was obtained from the ${\gamma}-Fe_2O_3$ nanopowder sample synthesized at precursor concentration of 0.3M. Then, the crystallite size of ${\gamma}-Fe_2O_3$ nanoparticles was 8.8 nm.

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Integral Analysis of the Effects of Non-absorbable gases on the Heat Mass Transfer of Laminar Falling Film

  • Kim, Byong-Joo
    • International Journal of Air-Conditioning and Refrigeration
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    • v.6
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    • pp.56-66
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    • 1998
  • The absorption process of water vapor in a liquid film is an important process in LiBr-Water absorption system. The composition of the gas phase, in which a non-absorbable gas is combined with the absorbate, influences the transport characteristics. In the present work, the absorption processes of water vapor into aqueous solutions of lithium bromide in the presence of non-absorbable gas are investigated. The continuity, momentum, energy and diffusion equations for the solution film and gas are formulated in integral forms and solved numerically. It is found that the mass transfer resistance in gas phase increases with the concentration of non-absorbable gas. However the primary resistance to mass transfer is in the liquid phase. As the concentration of non-absorbable gas in the absorbate increases, the interfacial temperature and concentration of absorbate in solution decrease, which results in the reduction of absorption rate. The reduction of mass transfer rate is found to be significant for the addition of a small amount of non-absorbable gas to the pure vapor, especially at the outlet of tube where the non-absorbable gas accumulates. At higher non-absorbable gas concentration, the decrease of absorption rate seems to be linear to the concentration of non-absorbable gas.

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Experiments on the GPR Reposnse of the Organic Hydrocarbons (유류오염물질의 GPR 반응에 대한 모델 실험 연구)

  • 김창렬
    • Economic and Environmental Geology
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    • v.37 no.2
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    • pp.185-193
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    • 2004
  • A physical model experiment was conducted using a sand and gravel-filled tank model, to investigate the influence on the GPR response of LNAPL vapor phase effects in the unsaturated zone and of residual phase of LNAPL trapped in the saturated zone. Background measurements of GPR were made with only water in the tank using a fluctuating water table model. Gasoline was, then, injected into the bottom of the model tank to simulate a subsurface discharge from a leaking pipe or tank at depth, obtaining GPR data with rising and lowering of water table. Results from the experiment show the GPR sensitivity to the changes in the moisture content in the vadose zone and its effectiveness for monitoring minor fluctuation of the water table. The results also demonstrate a potential of GPR for monitoring possible vapor phase effects of volatile hydrocarbons in the vadose zone as a function of time, and for detecting the effects of residual phase of hydrocarbons in the water saturated system. In addition, the results provide the basis for a strategy that has the potential to successfully detect and delineate residual LNAPL contamination in the water-saturated system at field sites where the conditions are similar to those simulated in the physcial models described herein.

Estimation of Thermal Conductivity at Liquid and Vapor Interface by Molecular Dynamics Simulation (분자동역학을 이용한 액상과 기상계면에서의 열전도율 예측)

  • Koo, Jin-Oh;Choi, Young-Ki;Lee, Joon-Sik;Park, Seung-Ho
    • Proceedings of the KSME Conference
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    • 2004.04a
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    • pp.1558-1563
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    • 2004
  • This work applies the nonequilibrium molecular dynamics simulation method to study a Lennard-Jones liquid thin film suspended in the vapor and calculates the thermal conductivity by linear response function. As a preliminary test, the thermal conductivity of pure argon fluid are calculated by nonequilibrium molecular dynamics simulation. It is found that the thermal conductivity decrease with decreasing the density. When both argon liquid and vapor phase are present, the effects of the system temperature on the thermal conductivity are investigated. It can be seen that the thermal conductivity of liquid-vapor interface is constant with increasing the temperature

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Experimental investigation of two-phase flow and wall heat transfer during reflood of single rod heater (단일 가열봉의 재관수 시 2상유동 및 벽면 열전달에 관한 실험적 연구)

  • Park, Youngjae;Kim, Hyungdae
    • Journal of the Korean Society of Visualization
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    • v.18 no.3
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    • pp.23-34
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    • 2020
  • Two-phase flow and heat transfer characteristics during the reflood phase of a single heated rod in the KHU reflood experimental facility were examined. Two-phase flow behavior during the reflooding experiment was carefully visualized along with transient temperature measurement at a point inside the heated rod. By numerically solving one-dimensional inverse heat conduction equation using the measured temperature data, time-resolved wall heat flux and temperature histories at the interface of the heated rod and coolant were obtained. Once water coolant was injected into the test section from the bottom to reflood the heated rod of >700℃, vast vapor bubbles and droplets were generated near the reflood front and dispersed flow film boiling consisted of continuous vapor flow and tiny liquid droplets appeared in the upper part. Following the dispersed flow film boiling, inverted annular/slug/churn flow film boiling regimes were sequentially observed and the wall temperature gradually decreased. When so-called minimum film boiling temperature reached, the stable vapor film between the heated rod and coolant was suddenly collapsed, resulting in the quenching transition from film boiling into nucleate boiling. The moving speed of the quench front measured in the present study showed a good agreement with prediction by a correlation in literature. The obtained results revealed that typical two-phase flow and heat transfer behaviors during the reflood phase of overheated fuel rods in light water nuclear reactors are well reproduced in the KHU facility. Thus, the verified reflood experimental facility can be used to explore the effects of other affecting parameters, such as CRUD, on the reflood heat transfer behaviors in practical nuclear reactors.