• Title/Summary/Keyword: vapor phase

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STUDY OF CATALYSIS FOR MAKING ALCOHOL FROM ACROLEIN AND ISOPROPYL ALCOHO

  • Nagase, Yoshinori
    • Journal of the Korean institute of surface engineering
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    • v.29 no.6
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    • pp.640-643
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    • 1996
  • The vapor phase hydrogen trancefer reaction between acrolein and isopropyl alcohol has been investigated over $Ag_2O$-Cao catalyst. A high selectivity of allyl alcohol was obtained at 88.7% with conversion of 75.4%.

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Degradation of TPHs, TCE, PCE, and BTEX Compounds for NAPLs Contaminated Marine Sediments Using In-Situ Air Sparging Combined with Vapor Extraction (증기추출법과 결합된 공기주입법을 이용한 비수용성액체 해양퇴적물의 TPHs, TCE, PCE 및 BTEX 정화)

  • Lee, Jun-Ho;Han, Sun-Hyang;Park, Kap-Song
    • Economic and Environmental Geology
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    • v.46 no.5
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    • pp.425-444
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    • 2013
  • This study was carried out in order to determine the remediation of total petroleum hydrocarbons (TPHs), trichloroethylene (TCE), perchloroethylene (PCE), benzene, toluene, ethylbenzene and xylenes (BTEX) compounds for non-aqueous phase liquids (NAPLs) using in-situ air sparging (IAS) / vapor extraction (VE) with the marine sediments of Mandol, Hajeon, Sangam and Busan, South Korea. Surface sediment of Mandol area had sand characteristics (average particle size, 1.789 ${\Phi}$), and sandy silt characteristics (average particle size, 5.503 ${\Phi}$), respectively. Sangam surface sediment had silt characteristics (average particle size, 5.835 ${\Phi}$). Sediment characteristics before experiment in the Busan area showed clay characteristics (average particle size, 8.528 ${\Phi}$). TPHs level in the B1 column of Mandol, Hajeon, Sangam, and Busan sediments were 2,459, 6,712, 4,348, and 14,279 ppm. B2 (3 L/min) to B5 (5 L/min) columns reduced 99.5% to 100.0% of TCE and 93.2% to 100.0% of PCE. Removal rates of TCE, PCE, and BTEX are closely correlated (0.90-0.99) with particle sizes and organic carbon concentrations. However, TPHs (0.76) and benzene (0.71) showed the poorer but moderate correlations with the same parameters.

A Study on the Annealing Effect of SnO Nanostructures with High Surface Area (높은 표면적을 갖는 SnO 나노구조물의 열처리 효과에 관한 연구)

  • Kim, Jong-Il;Kim, Ki-Chul
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.9
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    • pp.536-542
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    • 2018
  • Tin dioxide, $SnO_2$, is a well-known n-type semiconductor that shows change in resistance in the presence of gas molecules, such as $H_2$, CO, and $CO_2$. Considerable research has been done on $SnO_2$ semiconductors for gas sensor applications due to their noble property. The nanomaterials exhibit a high surface to volume ratio, which means it has an advantage in the sensing of gas molecules. In this study, SnO nanoplatelets were grown densely on Si substrates using a thermal CVD process. The SnO nanostructures grown by the vapor transport method were post annealed to a $SnO_2$ phase by thermal CVD in an oxygen atmosphere at $830^{\circ}C$ and $1030^{\circ}C$. The pressure of the furnace chamber was maintained at 4.2 Torr. The crystallographic properties of the post-annealed SnO nanostructures were investigated by Raman spectroscopy and XRD. The change in morphology was confirmed by scanning electron microscopy. As a result, the SnO nanostructures were transformed to a $SnO_2$ phase by a post-annealing process.