• Title/Summary/Keyword: vapor phase

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A Research on the Conception Change Process of Secondary School Chemistry Major Teachers Related to the Evaporation Phenomena in the Air (대기 중의 증발 현상에 대한 중등학교 화학전공 교사들의 개념 변화 과정에 대한 연구)

  • Yang, Gee-Chang;Paik, Seoung-Hey
    • Journal of the Korean Chemical Society
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    • v.52 no.1
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    • pp.84-95
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    • 2008
  • In this study, preconceptions held by chemistry major secondary school science teachers were searched in relation to explanations of water evaporation phenomena with phase equilibrium diagrams. 25 chemistry major science teachers were selected to complete questionnaires developed in this study and 6 among of them were selected to participate in follow-up interviews. Among these, 10 participants were selected for an evaluation of the change of their preconceptions through lessons developed in this study. From the results, it was found that many teachers believed that the phase equilibrium diagram could not explain water evaporation phenomena. They also thought that there was no relation between vapor pressure and the vertical axis of the phase equilibrium diagram. However, after the lessons in earth science, they recognized that the vapor pressure curve of the phase equilibrium diagram could be explained by adopting a saturated vapor curve. Because they had known the process of application the conceptions of saturated situation, nonsaturated situation, process of equilibrium movement in saturated vapor curve. They could understand natural phenomena such as evaporation with the phase equilibrium diagram through a change in their conceptions as guided from science lessons integrating earth science and chemistry.

A Study on the Characteristics of Refrigeration System Installed with Precooler, and Liquid-Vapor Separator after Expansion Device (과냉각기와 팽창장치 후 액기분리기를 적용한 냉동시스템 성능특성 연구)

  • Yun, Sang-Kook
    • Journal of Advanced Marine Engineering and Technology
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    • v.35 no.1
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    • pp.40-45
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    • 2011
  • The purpose of research is to understand the characteristics of refrigeration system having a liquid-vapor phase separator after expansion device and precooling heat exchanger. After expansion process of typical refrigerant of freezer, R134a, the cold vapor of the expanded refrigerant mixture is separated in the liquid-vapor separator and introduced in the precooling heat exchanger to enable the liquid refrigerant to be subcooled. The analysis results showed that the increasing rate of refrigeration capacity and COP can be 8.6% and 1.4%, each. The cause of these performance improvements is due to the difference of the slope of saturated vapor and saturated liquid lines in Mollier diagram of refrigerant.

Thermodynamic Analysis of the Extraction Process and the Cold Energy Utilization of LNG (LNG추출과정과 냉열이용의 열역학적 해석)

  • Lee, G.S.;Chang, Y.S.;Ro, S.T.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.7 no.1
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    • pp.120-131
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    • 1995
  • Thermodynamic analysis of extraction process from the constant pressure LNG(Liquefied Natural Gas) vessel was performed in this study. LNG was assumed as a binary mixture of 90% methane and 10% ethane by mole fraction. The thermodynamic properties such as temperature, composition, specific volume and the amount of cold energy were predicted during extraction process. Pressure as a parameter ranges from 101.3kPa to 2000kPa. The result shows the peculiar phenomena for the LNG as a mixture. Both vapor and liquid extraction processes were investigated by a computer model. The property changes are negligible in the liquid extraction process. For the vapor extraction process, the temperature in the vessel increases rapidly and the extracted composition of methane decreases rapidly near the end of extracting process. Specific volume of vapor has the maximum and that of liquid has the minimum during the process. When pressure is increased, specific volume of vapor decreases and that of liquid increases. It was found that specific volume of vapor phase had a major effect on the heat absorption at constant pressure during vapor extraction process. If the pressure of the vessel increases, the total cold energy which can be utilized from LNG decreased.

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Decomposition of Trchloroethylene/Air Mixture by Electron Beam Irradiation in a Flow Reactor (전자빔을 이용한 흐름반응기에서의 Trichloroethylene/Air 분해)

  • ;;;Tatiana Stuchinskaya
    • Journal of Korean Society for Atmospheric Environment
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    • v.17 no.1
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    • pp.97-104
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    • 2001
  • Decomposition of trichloroethlyene(TCE) in electron beam irradiation was examined on order to obtain information on the treatment of VOC in air. Air containing vaporized TCE has been studied in a flow reactor with different reaction environments, at various initial TCE concentration and in the presence and absence of water vapor. Maximum decomposition was observed in oxygen reaction environment and the degree of decomposition was about 99% at 20kGy for 2,000ppm initial TCE. The concentration of TCE exponentially decreased with dose in air and pure oxygen. The effect of water vapor on TCE decomposition efficiency was examined. The decomposition rate of TCE in the presence of water vapor (5,600 ppm) was approximately 10% higher than that in the absence of water vapor. Dichloroacetic acid, dichloroacethyl chloride and dichloroethyl ester acid were identified as primary products of this reaction adn were decomposed and oxidized to yield CO and $CO_2$. Perchloroethylene, hexachloroethane, chloroform and carbon tetrachloride were also observed as highly chlorinat-ed by products.

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The Method of Consequence Analysis of the Unconfined Vapor Cloud Explosion Accident by the Continuous Release of Gas-Liquid Flow for the Small and Medium Size Enterprises(SMS) (기-액흐름 연속누출에 의한 개방공간 증기운 폭발사고를 중심으로 중.소규모 사업장을 위한 사고 영향평가 방법)

  • 장서일;이헌창;조지훈;김태옥
    • Journal of the Korean Society of Safety
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    • v.18 no.1
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    • pp.64-70
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    • 2003
  • For the unconfined vapor cloud explosion(UVCE) accident by the continuous release of gas-liquid flow of various saturated liquids in a vessel at ground level, overpressures were estimated by TNT equivalency model with two estimation methods, such as UVCE I model based on a constant release time and UVCEII model based on a real travel time of vapor by dispersion and analyzed with various release conditions. As a simulation result the simple, easy, and correct method of evaluation of consequences of the UVCE accident was proposed by using consequences of UVCE I model and correlation equations for differences of overpressures between UVCE models, so that this evaluation method could be used easily in the small and medium size enterprises without using the dispersion model.

Effect of Carrier Gas on the Microstructure and Magnetic Properties of Co Nanoparticles Synthesized by Chemical Vapor Condensation (화학기상응축공정(Chemical Vapor Condensation)으로 제조된 Co 나노분말의 미세구조 및 자기적 성질에 미치는 운송기체의 영향)

  • ;X. L. Dong
    • Journal of Powder Materials
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    • v.11 no.1
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    • pp.16-21
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    • 2004
  • The nano-sized Co particles were successfully synthesized by chemical vapor condensation (CVC) process using the precursor of cobalt carbonyl ($Co_2(CO)_8$). The influence of carrier gases on the microstructure and magnetic properties of nanoparticles was investigated by means of XRD, TEM, XPS and VSM. The Co nano-particles with different phases and shapes were synthesized with a change of carrier gas : long string morphologies with coexistence of fcc and hcp structure in Ar carrier gas condition; finer Co core in a mass of cobalt oxide with only fcc structure in He; rod type cobalt oxide phase in Ar+6vol%$O_2$. The saturation magnetization and coercivity was lower in Co nanoparticles synthesized in He carrier gas, due to their finer size.

A study on the enhancement of refractive index in Ti:LiTaO$_{3}$ optical waveguides by Zn-vapor diffusion (Zn-Vapor확산에 의한 Ti:LiTaO$_{3}$ 광도파로의 굴절률 증가에 관한 연구)

  • 정홍식;정영식
    • Electrical & Electronic Materials
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    • v.9 no.3
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    • pp.298-303
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    • 1996
  • A double diffusion technique is developed to enhance the effective mode index of optical waveguides in $LiTaO_3$. It consists of Zn diffusion from the vapor phase at relatively low temperatures (750->$800^{\circ}C$), into waveguides initially produced by Ti indiffusion at higher temperature (1150->$1200^{\circ}C$). Both X- and Z-cut substrates are investigated. A model that combines profiles of both diffusion is formulated to calculate the expected effective index values for planar waveguides. Good agreement is found between experimental results and model predictions which assume that the initial Ti profile is not affected by the lower temperature Zn diffusion. Effective index enhancements as high as 0.005 and 0.003 are obtained by this method for the fundamental extraordinary and ordinary modes, respectively.

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Numerical Analysis on the Die Pad/Epoxy Molding Compound(EMC) Interface Delamination in Plastic Packages under Thermal and Vapor Pressure Loadings

  • Jin Yu
    • Journal of the Microelectronics and Packaging Society
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    • v.5 no.2
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    • pp.37-48
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    • 1998
  • The popcorn cracking phenomena in plastic IC packages during reflow soldering are investigated by considering the heat transfer and moisture diffusion through the epoxy molding compound(EMC) along with the mechanics of interface delamination. Heat transfer and moisture diffusion through EMC under die pad are analyzed by finite difference method (FDM)during the pre-conditioning and subsequent reflow soldiering pro-cess and the amounts of moisture mass and vapor pressure at delaminated die pad/ EMC interface are calculated as a function of the reflow soldering time. The energy release rate stress intensity factor and phase angle were obtained under various loading conditions which are thermal crack face vapor pressure and mixed loadings. It was shown that thermal loading was the main driving force for the crack propagation for small crack lengths but vapor pressure loading played more significant role as crack grew.