• Journal of the Korea Institute of Military Science and Technology
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• v.18 no.4
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• pp.387-394
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• 2015

We have recently developed a cost-effective and pouch-type chemical vapor sampler which consists of a selectively permeable high density polyethylene(HDPE) membrane, aluminum/nylon barrier film, and adsorbents. Since the sampler mimics the actual adsorption process that occurs when the skin is exposed to chemical vapors, it can be applied to man-in-simulant test(MIST) to determine the protective capability of individual protective ensembles for chemical warfare agents. In this study, we describe the manufacturing process of samplers and results for performance testing on MIST. Methyl salicylate(MeS) is used to simulate chemical agent vapor and the vapor sampler was used to monitor chemical concentration of MeS inside the protective suit system while worn. Values of protection factors(PF) were also analyzed to provide an indication of the protection level of the suit system evaluate by MIST. The results obtained by home-made samplers(ADD samplers) and commercially avaliable ones(Natick samplers) showed no significant differences.

• Journal of the Korea Institute of Military Science and Technology
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• v.17 no.1
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• pp.129-134
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• 2014

We have developed a cost-effective and facile method to manufacture a pouch-type chemical vapor sampler. Originally, the sampler was developed by U. S. Army Natick Soldier Research, Development, and Engineering Center(NSRDEC) to determine the protective capability of individual protective ensembles or Man-in-Simulant Test (MIST). They used a selectively permeable high density polyethylene(HDPE) as front membrane and aluminum/ Nylon barrier film as an impermeable back sheet in order to mimic the actual adsorption process that occurs when the skin is exposed to chemical weapons. However, it costs over twenty dollars per sampler and the minimum of quantity is 2500 per order. In addition, it is inconvenient to employ a variety of adsorbents into the sampler, which could prevent MIST researchers to do various tests for development of MIST methodologies. Here, we report the simple method to manufacture the sampler in a laboratory scale. All the materials we used are easily obtainable and inexpensive. In addition, all the procedures we perform are generally known. We used methyl salicylate(MeS) vapor to be adsorbed into the sampler and employed several different adsorbents to evaluate the performance of samplers. The results obtained by home-made samplers and commercially avaliable one showed no significant differences. Also, MeS vapor was selectively adsorbed into the sampler depending on adsorbents. We conclude that home-made samplers are capable of collecting any kind of chemical vapor for a variety of purposes.

• Vacuum Magazine
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• v.5 no.1
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• pp.9-12
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• 2018

Electronic nose has been developed for detection of various hazardous molecules, especially vapor organic compounds (VOCs), by adsorption and desorption phenomenon. However, although conventional electronic noses have provided many advantages such as simple detection and high sensitivity, they still need advanced technologies for selective specificity in real samples. In this review, we provide bionanoelectronic noses with natural receptors for selective odorant detection. This review includes from fabrication of natural receptors and conducting nanomaterials to bioelectronic noses. We also discussed their perspective applications for the future at the conclusion.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1997.11a
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• pp.484-488
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• 1997

BSCCO thin film is fabricated cia both processes of co-deposition and layer-by-layer deposition at an ultralow growth rate using ion beam sputtering method. The adsorption of Bi atom and the appearance of Bi-2212 phase shows large differance between both processes. It is found that the resident time of Bi vapor species on the surface of the substrate strongly dominates the film composition and the formation of the structure.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1992.05a
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• pp.144-146
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• 1992

Surface acoustic wave(SAW) oscillator offers many attractive features for application to vapor sensors. The perturbation of SAW velocity by the hexafluoropropence plasma polymer thin film has been studied for relative humidity sensing. adsorption of moisture produces rapid aid changes in the properties of the film, resulting in a change in the velocity of surface acoustic waves and, hence, in the frequency of one SAW oscillator. The device used in our experiments have 55 MHZ SAW oscillator fabricated on a LiNbO substrate.

• Journal of the Korean institute of surface engineering
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• v.33 no.4
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• pp.261-265
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• 2000

Geometrically and chemically well defined Pt/alumina model catalysts have been prepared. To this end, we fabricated electrochemically alumina supports in which pores of constant size, length and shape were regularly distributed over a wide area of the surface. Platinum particles were dispersed on the pore surfaces via organometallic chemical vapor deposition technique using (trimethyl) methylcyclopentadienylplatinum (IV) as a precursor. The chemical composition of the alumina plane surfaces was examined by Auger electron spectroscopy and the adsorption characteristics of the platinum particles were studied by thermal desorption spectroscopy. A variety of industrial catalytic problems are now open for further investigation utilizing the Pt/alumina model catalysts.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.33 no.6
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• pp.255-260
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• 2023

As demanding the detection of explosive molecules, it is required to develop rapidly and precisely responsive sensors with ultra-high sensitivity. Since two-dimensional semiconductors have an atomically thin body nature where mobile carriers accumulate, the abrupt modulation carrier in the thin body channel can be expected. To investigate the effectiveness of WSe₂ semiconductor materials as a detection material for TNT (Trinitrotoluene) explosives, WSe₂ was synthesized using thermal chemical vapor deposition, and afterward, WSe₂ FETs (Field Effect Transistors) were fabricated using standard photo-lithograph processes. Raman Spectrum and FT-IR (Fourier-transform infrared) spectroscopy reveal that the adsorption of TNT molecules induces the structural transition of WSe₂ crystalline. The electrical properties before and after adsorption of TNT molecules on the WSe₂ surface were compared; as -50 V was applied as the back gate bias, 0.02 μA was recorded in the bare state, and the drain current increased to 0.41 μA with a dropping 0.6% (w/v) TNT while maintaining the p-type behavior. Afterward, the electrical characteristics were additionally evaluated by comparing the carrier mobility, hysteresis, and on/off ratio. Consequently, the present report provides the milestone for developing ultra-sensitive sensors with rapid response and high precision.

• Journal of the Korean Wood Science and Technology
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• v.43 no.3
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• pp.334-343
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• 2015

This study was carried out to evaluate quantitatively some properties (density, equilibrium moisture content, shrinkage, water vapor adsorption, water absorptivity, compressive strength, bending strength, hardness and decay resistance) of Larix kaempferi lumber which was heat-treated by hot air and has been used commercially in Korea. Equilibrium moisture content of the heat-treated wood was decreased with increase of hydrophobicity. Dimensional stability of the wood was improved with decrease of shrinkage, water vapor adsorption and free water absorptivity. Also, with the thermo-chemical changes of wood component and lower equilibrium moisture content, decay resistance and compressive strength of heat-treated wood were increased. But, bending strength and hardness of wood were decreased.

• KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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• v.12 no.2
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• pp.87-90
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• 2006

Thermal and gas adsorption properties were measured for Korean earthenware (onggi) as a step to elucidate its role as food preserving container. Thermal conductivity and diffusivity decreased with increase in porosity while heat capacity depended on the raw soil component rather than porosity. Thermal barrier of the earthenware was generally similar to that of glass. The onggi material could sorb or adsorb a limited amount of water vapor, $CO_2$ and ethylene gases (0.0005 g/g, $17{\mu}g/g$, $2.6{\mu}g/g$, respectively). Thermal and gas adsorption properties of onggi seem to provide unique application area for use as food container and packaging.

• Proceedings of the Korean Vacuum Society Conference
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• 2016.02a
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• pp.378.2-378.2
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• 2016

Biosensors currently suffer from severe non-specific adsorption of proteins, which causes false positive errors in detection through overestimation of the affinity value. Overcoming this technical issue motivates our research. Polyethylene glycol (PEG) is well known for its ability to reduce the adsorption of biomolecules; hence, it is widely used in various areas of medicine and other biological fields. Likewise, amine functionalized surfaces are widely used for biochemical analysis, drug delivery, medical diagnostics and high throughput screening such as biochips. As a result, many coating techniques have been introduced, one of which is plasma polymerization - a powerful coating method due to its uniformity, homogeneity, mechanical and chemical stability, and excellent adhesion to any substrate. In our previous works, we successfully fabricated plasmapolymerized PEG (PP-PEG) films [1] and amine functionalized films [2] using the plasma enhanced chemical vapor deposition (PECVD) technique. In this research, an amine functionalized PP-PEG film was fabricated by using the plasma co-polymerization technique with PEG 200 and ethylenediamine (EDA) as co-precursors. A biocompatible amine functionalized film was surface characterized by X-ray photoelectron spectroscopy (XPS) and Fourier-transform infrared spectroscopy (FT-IR). The density of the surface amine functional groups was carried out by quantitative analysis using UV-visible spectroscopy. We found through surface plasmon resonance (SPR) analysis that non-specific protein adsorption was drastically reduced on amine functionalized PP-PEG films. Our functionalized PP-PEG films show considerable potential for biotechnological applications such as biosensors.