• Proceedings of the Korean Society of Machine Tool Engineers Conference
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• 2003.10a
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• pp.406-411
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• 2003

It is clearly demonstrated that deeper cups could be formed by single and double stretch-drawings from smaller circular blanks due to such wall-thinning action than in the usual deep-drawing of larger blanks. From this fact, it is emphasized that the deep-drawability of a sheet metal Is not evaluated simply by the conventional L.D.R (limiting drawing ratio), but the depth of the drawn cup should also be taken into account. Many experimental data about various metals and thicknesses given in this paper offer a valuable information in this process for more general use which recommends to replace the conventional deep-drawing process by the stretch-drawing process both for single and double operations. In the single stretch-drawing, it is also confirmed that a deeper cup can be produced by raising the blank-holding force at later stage of operation.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 1996.04a
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• pp.689-693
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• 1996

This paper was performed on the automatic selection of cutting condition on multispindle machine. the several mathematical relationships were formulated for simulataneous selection of machining parameters and tool changing scheme. In this research we used two step generative approach; step 1 is mathematical modeling for the selection of optimal cutting conditions and the other is GMDH-TYPE modeling to find prediction equation of system performance. thus in this paper, mathematical machining models combined with a heuristic GMDH-TYPE modeling to estimate the system performance, these models are developed computer programs for practical application and it was shown that the proposed approach has a good potential and offers a valuable tools to performance evaluation for metal cutting system.

• Bulletin of the Korean Chemical Society
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• v.28 no.9
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• pp.1553-1561
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• 2007

The new type of heterometallic chiral polymer salen complexes have been synthesized and it has been found that group 13 metal salts (AlCl3, GaCl3 and InCl3) combined to cobalt salen unit played the crucial role in the asymmetric kinetic resolution of racemic epoxides. Polymeric salen catalysts showed very high reactivity and enantioselectivity for the asymmetric ring opening of terminal epoxide with diverse nucleophiles. They provide the enantiopure useful chiral intermediates such as chiral terminal epoxides and α -aryloxy alcohols in one-step process. An efficient methodology for providing very high enantioselectivity can be achieved in the synthesis of valuable chiral building blocks via our catalytic system by combination of various asymmetric ring opening reactions.

• Resources Recycling
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• v.27 no.4
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• pp.65-69
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• 2018

In solvent extraction, extraction isotherm represents the relation between the equilibrium concentration of metal in the aqueous and organic phase. McCabe-Thiele diagram on which extraction isotherm and operating line are constructed provides valuable information on the mass transfer operation. When the equilibrium constant of a solvent extraction reaction is known, the calculation method to obtain extraction isotherm was introduced. Kresmer equation by which the number of extraction stages can be calculated when the distribution coefficient is constant was introduced.

• Journal of Electrochemical Science and Technology
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• v.15 no.1
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• pp.32-50
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• 2024

Diabetes mellitus is one of the common chronic diseases, seriously threating to human health. The continuous monitoring of blood glucose concentration can effectively prevent diabetic diseases. The sensing performance of glucose non-enzymatic sensors is mainly determined by working electrode materials. Metal-organic frameworks (MOFs) are recognized as promising candidate for glucose sensor application, due to its large surface areas, ordered porous structure and nearly infinite designability. In this review, the sensing performance, research progress and future challenge of non-enzymatic glucose sensors based on MOF-based materials in recent years are presented. We hope that this review would provide valuable technology guidance for high performance non-enzymatic glucose sensors based on MOFs.

• Journal of Environmental Science International
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• v.26 no.6
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• pp.797-802
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• 2017

This study aimed to remove organic matter and heavy metals that could affect the recycling of soils contaminated by heavy metals, by means of electrolysis, carried out simultaneously with the leaching of the soil. To ensure better experimental equipment, a soil electrolysis apparatus, equipped with spiral paddles, was used to agitate the heavy-metal-contaminated soil effectively. The heavy-metal-contaminated soil was electrolyzed by varying the voltage to 5 V(Condition 1), 15 V(Condition 2), and 20 V(Condition 3), under the optimal operating conditions of the electrolysis apparatus, as determined through previous studies. The results showed that the pH of the electrolyte solution and the heavy-metal-contaminated soil, after electrolysis, tended to decrease with an increase in voltage. The highest removal efficiencies of TOC and $COD_{Cr}$ were 18.8% and 29.1%, 38.8% and 4.2%, and 33.3% and 50.0%, under conditions 1, 2 and 3, respectively. Heavy metals such as Cd and As were not detected in this experiment. The removal efficiencies of Cu, Pb and Cr were 4.7%, 8.3% and 2.1%, respectively, under Condition 1, while they were 42.9%, 15.2% and 22.1%, respectively, under Condition 2, and 4.7%, 23.0%, and 24.9%, respectively, under Condition 3. These results suggest that varying the voltage with the soil electrolysis apparatus for removing contaminants for the recycling of heavy-metal-contaminated soil allows the selective removal of contaminants. Therefore, the results of this study can be valuable as basic data for future studies on soil remediation.

• Journal of Mechanical Science and Technology
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• v.16 no.12
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• pp.1687-1692
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• 2002

The problem analyzed here is a sheet metal forming process which requires a drawbead. The drawbead provides the sheet metal enough tension to be deformed plastically along the punch face and consequently, ensures a proper shape of final products by fixing the sheet to the die. Therefore, the optimum design of drawbead is indispensable in obtaining the desired formability. A static-explicit finite element analysis is carried out to provide a perspective tool for designing the drawbead. The finite element formulation is constructed from static equilibrium equation and takes into account the boundary condition that involves a proper contact condition. The deformation behavior of sheet material is formulated by the elastic-plastic constitutive equation. The finite element formulation has been solved based on an existing method that is called the static-explicit method. The main features of the static-explicit method are first that there is no convergence problem. Second, the problem of contact and friction is easily solved by application of very small time interval. During the analysis of drawbead processes, the strain distribution and the drawing force on drawbead can be analyzed. And the effects of bead shape and number of beads on sheet forming processes were investigated. The results of the static explicit analysis of drawbead processes show no convergence problem and comparatively accurate results even though severe high geometric and contact-friction nonlinearity. Moreover, the computational results of a static-explicit finite element analysis can supply very valuable information for designing the drawbead process in which the defects of final sheet product can be removed.

• Journal of Mechanical Science and Technology
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• v.19 no.spc1
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• pp.437-443
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• 2005

Controlling the friction between wheel and rail is direct and very effective measures to improve the curving performances of railway trucks, because the curving performances depend much on friction characteristics. Authors have proposed a method, 'friction control', which utilizes friction modifier ($KELTRACK^{TM}$ HPF) with onboard spraying system. With the method, not only friction coefficient, but also friction characteristics can be controlled as expected. In this study, MBD simulation is very valuable tool to foresee the effect of the control in advance of experiment with real car. And the creep characteristics of wheel/rail contact with the friction modifier takes very important role in the simulation. In this paper, authors propose a theoretical model of wheel/rail contact condition considering the creep characteristics of friction modifier, which is derived the application of principle tribological theories.

• Journal of Sensor Science and Technology
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• v.32 no.3
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• pp.147-153
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• 2023

Metal-organic frameworks (MOFs) of cobalt gallate were synthesized and deposited on gold electrodes using self-assembly monolayers (SAMs) and hydrothermal processing. These MOF films exhibit strong adsorption capabilities for gaseous particulates, and the use of SAMs allows the synthesis and deposition processes to be completed in a single step. When cobalt gallate is mixed with SAMs, a coordination bond is formed between the cobalt ion and the carboxylate or hydroxyl groups of the SAMs, particularly under hydrothermal conditions. Additionally, the quartz crystal microbalance (QCM) gas sensor accurately measures the number of particulates adsorbed on the MOF films in real-time. Thus, the QCM gas sensor is a valuable tool for quantitatively measuring gases, such as SO₂, NO₂, and CO₂. Furthermore, the QCM MOF film gas sensor was more effective for gas adsorption than the MOF particles alone and allowed the accurate modeling of gas adsorption. Moreover, the QCM MOF films accurately detect the adsorption-desorption mechanisms of SO₂ and NO₂, which exist as gaseous particulate matter, at specific gas concentrations.

• Journal of Soil and Groundwater Environment
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• v.29 no.2
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• pp.1-10
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• 2024

With industrial development, the inevitable increase in both organic and inorganic waste necessitates the exploration of waste treatment and utilization methods. This study focuses on co-pyrolyzing lignin and red mud to generate metalbiochar, aiming to demonstrate their potential as effective adsorbents for water pollutant removal. Thermogravimetric analysis revealed mass loss of lignin below 660℃, with additional mass loss occurring (>660℃) due to the phase change of metals (i.e., Fe) in red mud. Characterization of the metal-biochar indicated porous structure embedded with zero-valent iron/magnetite and specific functional groups. The adsorption experiments with 2,4-dichlorophenol and Cd(II) revealed the removal efficiency of the two pollutants reached its maximum at the initial pH of 2.8. These findings suggest that copyrolysis of lignin and red mud can transform waste into valuable materials, serving as effective adsorbents for diverse water pollutants.