• Proceedings of the Korea Concrete Institute Conference
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• 2004.11a
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• pp.297-300
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• 2004

The purpose of this study reutilization of waste fine tailing as admixture for cement. We observe tailing's basic properties such as shape, physical and chemical basic features. Also, various admixtures were made of 2 Types of tailings, OPC, fly-ash and blast furnace slag. The basic properties of the cement mortars incorporation with these admixtures were examined and analyzed under a verity of experimental conditions. This work showed that the tailing separated coarse materials could be effectively utilized as replacement materials of cement without any decrease in the strength if we can control the blaine of materials like OPC, slag and fly ash.

• Proceedings of the Korea Concrete Institute Conference
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• 2005.05b
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• pp.381-384
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• 2005

The purpose of this study reutilization of waste fine tailing (FT) as admixture for cement and concrete. Various admixtures were made of Fine tailings and 2 Types of OPC, fly-ash and blast furnace slag. Cement mortars and concrete with FT are tested for fluidity and compressive strength. Also, the hydration reactivity of cement mortar with FT was examined by XRD and SEM morphology analysis. This work showed that the waste fine tailing could be effectively utilized as replacement materials of cement without any decrease in the strength if we can control the blaine of materials like cement, blast furnace slag and fly ash.

• Journal of the Korean Ceramic Society
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• v.12 no.3
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• pp.3-7
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• 1975

The usefulness of the domestic shale contained chiastolite as additive were investigated. Crude mixed minerals were separated into shale and chiastolite. Refractory body added simple component or multiple components as additives was obtained when firing at 125$0^{\circ}C$ for each body. Compressive strength, refractories, apparent sp. gr., water absorption, corrosion test by slag, hot linear expansion were measured and X-ray diffraction analysis was observed. As the result of study, refractory body contained separated minerals as additives showed slightly increasing in refractoriness, lowering in sintering effect, the excellent effect for corrosion resistance by acidic slag. With more containing separated minerals, hot linear expansion for the body can be decreased.

• Resources Recycling
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• v.19 no.4
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• pp.19-28
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• 2010

Attempts to increase the utilization of a by-products such as fly ash and blast furnace slag to partially replace the cement in concrete are gathering momentum. But most of by-products is currently dumped in landfills, thus creating a threat to the environment. Many researches on alkali-activated concrete that does not need the presence of cement as a binder have been carried out recently. However, most study deal only with alkali-activated blast furnace slag or fly ash, as for the combined use of the both, little information is reported. In this study, we investigated the influence of mixture ratio of fly ash/slag, type of alkaline activator and curing condition on the workability and compressive strength of mortar in oder to develop cementless alkali-activated concrete. In view of the results, we found out that the mixture ratio of fly ash/slag and the type of alkaline activator always results to be significant factors. But the influence of curing temperature in the strength development of mortar is lower than the contribution due to other factors. At the age of 28days, the mixture 50% fly ash and 50% slag activated with 1:1 the mass ratio of 9M NaOH and sodium silicate, develop compressive strength of about 65 MPa under $20^{\circ}C$ curing.

• Journal of the Korean Recycled Construction Resources Institute
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• v.5 no.4
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• pp.114-121
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• 2010

Portland cement production is under critical review due to high amount of CO2 gas released to the atmosphere. Attempts to increase the utilization of a by-products such as fly ash and ground granulated blast-furnace slag to partially replace the cement in concrete are gathering momentum. But most of by-products is currently dumped in landfills, thus creating a threat to the environment. Many researches on alkali-activated concrete that does not need the presence of cement as a binder have been carried out recently. However, most study deal only with alkali-activated ground granulated blast furnace slag or fly ash, as for the combined use of the both, little information is reported. In this study, we investigated the influence of mixture ratio of fly ash/ blast furnace slag tand curing condition on the flowability and compressive strength of mortar in oder to develop cementless alkali-activated concrete. In view of the results, we found out that the mixture ratio of fly ash/blast furnace slag always results to be significant factors. But the influence of curing temperature in the strength development of mortar is lower than the contribution due to other factors. At the age of 28days, the mixture 50% fly ash and 50% ground granulated blast furnace slag activated with 1:1 the mass ratio of 9M NaOH and sodium silicate, develop compressive strength of about 65 MPa under $20^{\circ}C$ curing.

• Resources Recycling
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• v.30 no.6
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• pp.53-60
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• 2021

In EAF steelmaking industries, MgO content in slag increases due to the addition of dolomite flux to protect refractory lines of furnaces and improve the desulfurization capability of slag. In addition, coal powder is injected in the molten steel bath to increase the energy efficiency of the process. In this regard, the utilization of waste MgO-C refractory material as a flux was examined because it has high amounts of MgO (>70%) and graphite carbon (>10%). A series of experiments were carried out using industrial EAF slag with added light burnt dolomite and waste MgO refractory material from a Korean steel company. The results for the addition of the two fluxes were similar in terms of slag basicity; therefore, it is expected that waste MgO-C refractory material can successfully replace dolomite flux. In addition, when the waste MgO-C refractory material was added as flux, slag foaming phenomenon was demonstrated because of the reaction between the graphite from the refractory material and iron oxides in the slag.

• Applied Chemistry for Engineering
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• v.28 no.1
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• pp.101-111
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• 2017

Mineral carbonation is a technology in which carbonates are synthesized from minerals including serpentine and olivine, and industrial wastes such as slag and cement, of which all contain calcium or magnesium when reacted with carbon dioxide. This study aims to develop the mineral carbonation technology for commercialization, which can reduce environmental burden and process cost through the reduction of carbon dioxide using steel slag and the slag reuse after calcium extraction. Calcium extraction was conducted using NH4Cl solution for air-cooled slag and convert slag, and ${\geq}98%$ purity calcium carbonate was synthesized by reaction with calcium-extracted solution and carbon dioxide. And we conducted experimentally to minimize the quantity of by-product, the slag residue after calcium extraction, which has occupied large amount of weight ratio (about 80-90%) at the point of mineral carbonation process using slag. The slag residue was used to replace silica sand in the manufacture of cement panel, and physical properties including compressive strength and flexible strength of panel using the slag residue and normal cement panel, respectively, were analyzed. The calcium concentration in extraction solution was analyzed by inductively coupled plasma optical emission spectrometer (ICP-OES). Field-emission scanning electron microscope (FE-SEM) was also used to identify the surface morphology of calcium carbonate, and XRD was used to analyze the crystallinity and the quantitative analysis of calcium carbonate. In addition, the cement panel evaluation was carried out according to KS L ISO 679, and the compressive strength and flexural strength of the panels were measured.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2022.04a
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• pp.107-108
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• 2022

This study aims to solve environmental problems by reducing complex degradation and recycling industrial waste by utilizing waste fibers and blast furnace slags, which are industrial by-products. In addition, it is intended to secure long-term durability to reduce cracks. To this end, the disadvantages of fiber-reinforced concrete are to solve the problem of lowering liquidity and ensuring curing time, and to find the optimal combination when waste fibers and blast furnace slag are used together.

• Korean Journal of Soil Science and Fertilizer
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• v.43 no.6
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• pp.864-871
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• 2010

At the current situation of continuous utilization of heavy metal contaminated upland for agricultural purpose in Korea, minimizing transport of heavy metals from soil to crops is important for securing safety of human health. The present study (in field scale) examined the efficiency of several soil amendments (dolomite, steel slag, lime, zeolite, and compost) on reduction of phytoavailable heavy metals (Cd, Cu, Pb, and Zn) in soil through comparison with no amendment treatment and clean soil cover treatment. For determination of the phytoavailability, 1 M $NH_4NO_3$ extraction and red pepper cultivation were introduced. Among the amendments, in general, dolomite and steel slag were the most effective in reduction of metal (Cd, Pb, and Zn) phytoavailability resulting in less accumulation of these metals in shoot and fruit of red pepper. However, dolomite and steel slag treatment was not as effective as clean soil cover treatment which showed the least metal accumulation in red pepper fruit. Nevertheless, with taking into account the cost, treatment of dolomite or steel slag can be competitive method because the current study showed that dolomite or steel slag treatment reduced accumulated heavy metal concentration effectively in both shoot and fruit of red pepper compared to those from control soil and the concentration in fruit was within the standard value (<0.2 mg $kg^{-1}$ for both Cd and Pb).

• Korean Journal of Soil Science and Fertilizer
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• v.16 no.4
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• pp.343-346
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• 1983

This paper was prepared to characterize a physico-chemical and mineralogical examination on blast furnace slag as a source of silicate fertilizer, which was quenched with high pressure water stream in process of iron refinery at Pohang Iron and Steel Manufacturing Inc. Quenched slag was more coarse in particle size compared to present commercial silicate fertilizer milled from air-cooled slag and mostly generated in size of 1 to 2 mm. The total chemical composition of quenched and air-cooled slags was same but mineralogical composition was quite different. The former was composed of amorphous materials resulting in more soluble silica content, however, the latter contained dominantly crystalline minerals such as akermanite, gehlenite and wollastonite which meant less soluble ones. Latent cementing property and angular surface of gain of the slag made it difficult to apply the slag directly, however, it could be used as a source of silicate fertilizer and soil ammendment.