• 한국농공학회:학술대회논문집
• /
• 한국농공학회 2000년도 학술발표회 발표논문집
• /
• pp.333-339
• /
• 2000

This study was performed to investigate the performance of heat recovery device attached to exhaust gas funnel connected to combustion chamber of greenhouse heating system. The experiment heat recovery system is mainly consisted of LPG combustion chamber and two heat recovery units; unit-A is attached directly to the exhaust gas funnel, and unit-B is connected with unit-A. Heat recovery performance was evaluated by estimating total energy amount by using enthalpy difference between two measurement points together with mass flow rate of gas and/or air passing through each heat recovery unit depending on 5 different flow rates controlled by voltage meter. The results of this experimental study, such as heat exchange behavior of supply air pipes and exhaust air passages crossing the pipes, pressure drop between inlet and outlet, heat recovery performance of exchange unit, etc., will be used as fundamental data for designing optimum heat recovery device to be used for fuel saving purpose by reducing heat loss amounts mostly wasted outside of greenhouse through funnels.

• Elastomers and Composites
• /
• 제51권1호
• /
• pp.63-67
• /
• 2016

Poly(ethylene-co-vinyl acetate) (EVA) was pyrolyzed to eliminate acetic acid of VA unit using off-line pyrolysis, and the deacetylated EVA was analyzed infrared spectroscopy (IR) and pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS). EVA film for deacetylation was prepared by solution casting on aluminum foil and it was pyrolyzed at low temperature of $300^{\circ}C$ in the off-line pyrolysis apparatus. After deacetylation, carbon-carbon double bond (C=C) was formed by 1,2-elimination of the VA unit in the EVA backbone. Most of C=C bonds were trans-1,4-unit and 1,2-unit was also observed. Presence of the 1,2-unit in deacetylated EVA indicates that terminal or branch VA units exist in the raw EVA. Py-GC/MS chromatogram of deacetylated EVA displayed much smaller acetic acid and much more abundant other pyrolysis products than that of raw EVA, which means that the pyrolysis efficiency and separation condition were improved.

• 대한기계학회논문집B
• /
• 제39권10호
• /
• pp.817-824
• /
• 2015

본 논문은 수직 오리피스 노즐의 유동 및 물질전달 특성에 대한 실험적 연구를 목적으로 한다. 구동유체 및 부유체의 유량, 용존산소 농도 그리고 소비 전력을 측정하였으며, 고속 카메라를 이용한 직접 촬영 기법으로 수직 혼합유동의 가시화 이미지를 획득하였다. 측정자료를 이용하여 질량비, 총괄 산소전달 계수 그리고 물질전달 성능계수를 도출하였다. 구동압력이 증가하면 질량비는 약간 감소하는 반면에, 산소전달 계수와 소비전력은 증가하였다. 구동압력이 증가하고 질량비가 작아지면, 기포의 미세화가 촉진되고 확산도가 증대되기 때문에 산소 전달율이 증가하였다.

• 해양환경안전학회:학술대회논문집
• /
• 해양환경안전학회 2005년도 추계학술대회지
• /
• pp.165-170
• /
• 2005

본 연구는 탱크로리용 디스크식 유회수기 개발을 위한 기초 연구로 기존 유회수기 디스크와 기름의 흡착이 가능하다고 판단되는 몇 가지 재료의 디스크에 대한 유회수 차이를 실험을 통해 비교한 것이다. 실험 결과를 요약하면 다음과 같다. 모든 디스크에서 경유보다는 벙커 A유의 회수량이 높았으며, 경유에서는 디스크 소재별 유회수량이 모든 디스크에서 거의 차이가 없는 반면, 벙커 A유에서는 디스크 소재에 따라 회수 성능이 큰 차이를 보였다. 또한, 디스크 구동 시간대별 회수량은 경유의 경우, 모든 디스크 소재에서 초기 시간대부터 단위 구동 시간당 기름의 회수량 차이가 거의 없는 것으로 나타난 반면, 벙커 A유는 모든 소재에서 구동 초기시간에서 회수량이 직선적으로 증가하고 시간이 경과할수록 증가량이 완만한 경향을 보여 단위 구동 시간당 기름의 회수량이 시간에 따라 차이를 보이는 것으로 나타나 유류의 점도가 디스크 회수 성능에 영향을 미치는 것을 알 수 있었다. 또한, 벙커 A유를 대상으로 전체 회수량에서 순수 유회수량과 함수량을 비교했을 때 창문용 알미늄 소재의 디스크는 다른 재질의 디스크에 비해 기름의 회수량은 차이가 없으면서 상대적으로 물의 회수량은 매우 적게 나타나는 것으로 조사되어 함수량을 고려한 유회수 효율을 고려했을 때 가장 이상적인 결과를 보여주고 있어, 본 연구에서 목적하는 탱크로리 유회수기 디스크 소재로서 가장 유리하다는 것을 알 수 있었다.

• 대한기계학회:학술대회논문집
• /
• 대한기계학회 2004년도 춘계학술대회
• /
• pp.1715-1719
• /
• 2004

An in-house supersonic ejector was designed to ensure low pressure and high speed scavenging of resonating cavity of chemical lasers. For given primary flow condition, 100g/s secondary mass flow rate was observed at the design pressure. Performance validation of a supersonic ejector system along with an investigation of effects of supersonic diffuser was conducted. Placement of diffuser at the secondary inlet further reduced diffuser upstream pressure to 1/4-1/5 relieving the local to the primary supply unit. In order to increase the secondary flow, we put two ejectors capable of removing 50g/s each of secondary flows together to deal with higher mass flow. Test of the parallel unit demonstrated the secondary flow rate was proportional to the numbers of individual units that were brought together. Additionally, flow calculations with a commercial code were carried out in every case of experiment and compared with results.

• Elastomers and Composites
• /
• 제57권4호
• /
• pp.188-196
• /
• 2022

Styrene-butadiene rubber(SBR) is a copolymer of styrene and butadiene. It is composed of 1,2-unit, 1,4-unit, and styrene, and its properties are dependent on its microstructure. In general, rubber composites contain a single rubber or a blended rubber. Similarly, SBR is used by mixing with natural rubber(NR) and butadiene rubber(BR). The composition of a rubber article affects its physical and chemical properties. Herein, an analytical method for determining the microstructure of SBR using via pyrolysis is introduced. Pyrolysis-gas chromatography/mass spectrometry is widely used to analyze the microstructure of polymeric materials. The microstructure of SBR can be determined by analyzing the principal pyrolysis products formed from SBR, such as 4-vinylcyclohexene, styrene, 2-phenylpropene, 3-phenylcyclopentene, and 4-phenylcyclohexene. An analytical method for determining the composition of SBR/NR, SBR/BR, and SBR/NR/BR blends via pyrolysis is introduced. The composition of blended rubber can be determined by analyzing the principal pyrolysis products formed from each rubber component.

• Advances in nano research
• /
• 제8권3호
• /
• pp.229-244
• /
• 2020

In this paper, modified Kelvin's model has been used to analyze the orthotropic vibration frequencies of single walled carbon nanotubes with clamped-clamped and clamped-free boundary conditions. For this system the governing equation is developed with wave propagation approach. Armchair, zigzag and chiral structures are considered for the vibrational analysis to investigate the effect of different modes, in-plane rigidity and mass density per unit lateral area. Throughout the computations, on decreasing the length-to-diameter ratios, the frequencies of said structure increases. In addition, by increasing three different value of in-plane rigidity resulting frequencies also increase and frequencies decrease on increasing mass density per unit lateral area. The results generated using computer software MATLAB to furnish the evidence regarding applicability of present model and also verified by available published literature.

• Mass Spectrometry Letters
• /
• 제10권4호
• /
• pp.112-116
• /
• 2019

In this study, a chloroform consumer chemical product (CCP) reference material (RM) is successfully developed, with potential to be used in the proficiency testing of hazardous compounds in CCPs for analysis and testing agencies. Validation experiments are rigorously conducted to evaluate whether the RM meets the requirements set by the ISO 13528 and ISO Guide 35, using a reliable GC/MS method for the analysis of chloroform. The obtained calibration plot linearity, limit of detection (LOD), and limit of quantitation (LOQ) are excellent. The developed RM meets the homogeneity and stability requirements; the between-unit (s_bb) and within-unit (s_wb) standard deviations are less than 2.5%, and the stability is found to be guaranteed for 50 days.

• 한국분무공학회지
• /
• 제5권3호
• /
• pp.9-16
• /
• 2000

In a SI engine, three-way catalyst converter has the best efficiency when A/F ratio is near the stoichiometry. The feedback control using oxygen sensors in the commercial engine has limits caused by the system delays. So it is necessary to control fuel quantity in accordance with intake air amount in order to reduce exhaust emission and improve the specific fuel consumption. Precise A/F ratio control requires measurement of air amount with respect to the cylinder and injection fuel according to the air amount In this paper, we applied nonlinear fuel injection model and developed the algorithm of A/F ratio control. This algorithm includes the methods of measurement of transient air mass flowing into each cylinder, of calculation of injection pulse width for measured air mass, and the method of feedback and engine control by using lambda sensor. Also we developed control program for IBM-PC by using C++ Builder, and tested it in the commercial engine.

• Bulletin of the Korean Chemical Society
• /
• 제26권5호
• /
• pp.763-768
• /
• 2005

An improved tandem time-of-flight (TOF) mass spectrometer for the photodissociation (PD) study of ions generated by matrix-assisted laser desorption ionization (MALDI), MALDI-TOF-PD-TOF, has been designed and constructed. Recording a full spectrum with better than unit mass resolution even in low mass range has been achieved without reflectron voltage stepping which was needed in the previous version. Other aspects of the improvement, such as those in the data system which now allow 10-100 times faster spectral acquisition than with the previous instrument, are described. Rationale for the ideas which have led to the improvements is presented also.