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Effect of Seed Coating Layer on the Microstructure of NaA Zeolite Separation Layer Grown on ${\alpha}$-alumina Support (종결정 코팅층이 다공성 ${\alpha}$-알루미나 지지체 표면에 성장되는 NaA 제올라이트 분리층의 미세구조에 미치는 영향)

  • Kim, Min-Ji;Sharma, Pankaj;Han, Moon-Hee;Cho, Churl-Hee
    • Membrane Journal
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    • v.24 no.5
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    • pp.375-385
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    • 2014
  • NaA zeolite/${\alpha}$-alumina composite membranes were hydrothermally synthesized at $100^{\circ}C$ for 24 hr by using nanosize seed of 100 nm in diameter and an ${\alpha}$-alumina support of $0.1{\mu}m$ in pore diameter, and then effect of seed coating layer on the microstructure of NaA zeolite separation layer was systematically investigated. In cases when nanosize seed was coated with a monolayer, increment in seed coverage induced small grained and thick NaA zeolite separation layer. On the other hand, in case when nanosize seed was coated with a multilayer, much small grained and thick separation layer was formed. It was clear that an uniform monolayer seed coating is required to grow hydrothermally a thin and defect-free NaA zeolite separation layer. In the present study, it was clearly announced that seed coating layer is a key factor to determine the microstructure of NaA zeolite layer, secondary grown on a porous support.

Fabrication of SiCp/Al Alloy Composites by In-situ Vacuum Hot Press Process (In-situ Vacuum Hot Press 공정을 이용한 SiCp/Al 복합재료의 제조)

  • Choe, Se-Won;Hong, Seong-Gil;Kim, Yeong-Man;Jang, Si-Yeong;Gang, Chang-Seok
    • Korean Journal of Materials Research
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    • v.11 no.7
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    • pp.590-598
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    • 2001
  • SiCp/pure Al and SiCp/2024Al MMCs were fabricated by in-situ VHP process designed specially just in this study which is composed of the vacuum hot press at range from R.T. to $500^{\circ}C$ and the continuous extrusion without canning process at $520^{\circ}C$. It was investigated the effect of SiC particle size, volume fraction and extrusion ratio on the tensile properties and micro structure in auf composites. In case of the 10:1 extrusion ratio, but SiCp/pure Al and SiCp/2024Al composites were shown a sound appearance and a good micro structure without crack of SiCp as well as uniform distribution of SiCp. However, in case of the 16:1 extrusion ratio, the number of cracked SiC particles more than increased in a higher volume fraction composite and 2024Al matrix composite compared with pure Al matrix one. The tensile strength of the composites reinforced smaller SiCp was higher than that of the bigger SiCp reinforced in same volume fraction and extrusion ratio.

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Separation of Aluminum and Iron from Platinum Mixture using Synthetic Extraction Resins (합성(合成) 추출(抽出) 수지(樹脂)를 이용(利用)한 백금용액(白金溶液)으로부터 알루미늄과 철(鐵)의 분리(分離))

  • Lim, Gwang-Il;Han, Dong-Hyuk;Hwang, In-Sung;Han, Choon;Lee, Jin-Young;Kim, Joon-Soo;Park, Hyung-Kyu
    • Resources Recycling
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    • v.20 no.3
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    • pp.68-76
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    • 2011
  • For the separation of aluminum and iron from platinum mixtures, extraction resins were synthesized and separation efficiencies were compared with those by commercial one, $P_{204}$. During synthesis, the suspension polymerization method was adopted with D2EHPA as an extractant. Also, benzoyl peroxide as a starter was divided into 3parts and injected for the uniform size and dispersion of resin particles. Comparison tests resulted in 100% separation of Fe and Pt for both synthetic and $P_{204}$ resins. In case of Al and Pt, synthetic and $P_{204}$ resin gave extraction efficiencies of 99.9% and 98.9%, respectively. Difference in extractant contents of synthetic resin(61.8%) and $P_{204}$(60%) was considered to give differences in separation efficiencies of aluminum and iron elements. For both resins, separation efficiencies of Al and Fe increased up to $55^{\circ}C$. According to FT-IR analyses of both resins, specific peaks of D2EHPA and crosslinked polystyrene were identified at the wavenumber of $1000cm^{-1}$ and $2900cm^{-1}$ respectively.

Effect of the A-site Deficieny of ABO3 type (La0.75Sr0.25)1-xFeO3-δ Used as Cathode Materials for SOFC on the Electrode Properties (고체산화물 연료전지의 공기극용 ABO3구조의 (La0.75Sr0.25)1-xFeO3-δ의 A-site변화에 따른 전극 특성 연구)

  • Park, Ju-Hyun;Lee, Seung-Bok;So, Hui-Jeong;Lim, Tak-Hyoung;Yoon, Soon-Gil;Shin, Dong-Ryul;Song, Rak-Hyun
    • Journal of the Korean Electrochemical Society
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    • v.11 no.2
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    • pp.89-94
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    • 2008
  • We synthesized and investigated $(La_{0.75}Sr_{0.25})_{1-x}FeO_{3-\delta}$ perovskite oxides having different stoichiomety (x = 0, 0.02, 0.04, 0.06, 0.08) as cathode materials. SEM images and XRD patterns reveal that the synthesized powder has uniform size distribution and high degree of crystallinity. The electrochemical performances of the synthesized powders were investigated by AC impedance spectroscopy. Both the electric conductivity and the electrochemical performance showed the highest properties at the stoichiometry x = 0.02. Finally, we concluded that the variation of A-site deficiency results in the variation of the amount of oxygen vacancy and micro structure, which leads to the variation of electric conductivity and polarization resistance.

Study on the Cases and Features of Chair Design Inducing the Participation of Users - Focused on the cases of chair design from 1966 up to now - (사용자 참여를 유도하는 의자디자인의 사례와 특성에 관한 연구 - 1966년부터 현재까지 디자인된 의자디자인의 사례를 중심으로 -)

  • Kim, Jin-Woo
    • Korean Institute of Interior Design Journal
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    • v.16 no.2 s.61
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    • pp.262-269
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    • 2007
  • The blur phenomenon obscuring the boundary between the field of designers and that of users may be the key paradigm in the 21st century. However, we observed a number of chair design cases that could be considered as the results of blur pheonomenon in the furniture design field from mid 1960s. The backgrounds include the repulsion against the uniform functionalism, deliberation on the life in the future and the development of plastic materials and their processing methods. Under such backgrounds, the designers pursued the new and futuristic furniture design. In that process, what is about the "freedom" that the consumers as well as the designers should have in using the furniture was the important concept. This concept enabled the creation of chair design inducing the participation of consumers. They created various kinds of shapes, functions and structures that the consumers became interested in as if they had fun with toy blocks by mainly using the new material "plastic". In a formative aspect, the entire shape is classified into the organic shape and geometric shape. The unit types are divided into two kinds; type that the unit of simple shape is repeated only with size difference and irregular combination type of the units comprised of more than two shapes. In the functional aspect, some cases showed the transformation and expansion of the function more variously. Other cases changed the function of chairs to tables, cabinets, or objects. In the structural aspect, on the basis of the method assembling each unit, one method is to assemble using the hardware and the other is to assemble only with intrinsic units of chair. The chair design created by the blur phenomenon between the designers and the users as described above causes the blur phenomenon between the furniture and the space where the furniture is installed. Accordingly, it is expanding the furniture design sphere including the case that the furniture is not selected as the rifle article depending on the characteristics of interior space but it becomes the element leading the characteristics of space. This study aims to estimate the change of interior space and the furniture that my cause the blur phenomenon by examining the cases above appropriate for the paradigm of the 21st century. Furthermore, this study will enable the discussion oil the directions of future furniture design based on its results.

A Study on the Current Nutritin Labeling Practices for the Processed Foods Retailed in the Supermarket in Korea (시판 포장가공 식품의 영양표시 현황에 관한 조사연구)

  • 장순옥
    • Journal of Nutrition and Health
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    • v.30 no.1
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    • pp.100-108
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    • 1997
  • Our current food hygiene law mandates nutrition label (NL) for the special nutrition foods, health support foods, instant foods, and foods with certain nutrient emphasized note, only. Currently more processed foods are bearing nutrition labels though the format is quite inconsistant. This study examined the status on current nutrition labeling practices for the processed foods that are retailed in the supermarket. The obtained information was assessed in the aspects of numerical data presentation on nutrients content, descriptive terms, health claim, and the format. The results are summarized as follows. 1) Foods with NL are limited to the food category specified by current hygiene law while voluntary nutition labeling is few. 2) Descriptive terms such as free, low, and sufficient are not substantiated with quantitative data. The efficacy of microelements which has not been clalified yet are overemphasized but major nutrients are ignored. 3) The regulations for the descriptive terms are set on the base of the nutrient content per 100g or 100ml under current nutrition labeling act. It would mislead consumers thus the definition for these descriptor be better set on the unit of the amount of food customary eaten at one time. For this the standard serving size should be set officially. 4) Quantitative nutrition information given on food products is difficult to compare because of the lack in formality. The title of NL, load and kinds of nutritents, order of nutrients listed, the unit of expression, RDA comparision, and reference RDA are inconsistant among the foods similar in dietary property. Uniform format is needed to give NL the credibility and usefulness. Proividing nutrition information to the consumers with NL is a worldwide practice though its efficacy has been controversial. Under newly legistered health promotion law in Korean nutrition education is esxpected to take part in to improve national nutrition condition and NL would education is expected to take part in to improve national nutrition condition and NL would be a potent tool for public nutritions education. It appears to be the time to mandate NL to all the processed foods in the market. The result of present study would initiate further consumer experiments related to NL. Various interest groups such as food and nutrition professions, public health organizations, government regulatory agencies, food producers and marketers, and consumer groups need to particepate and communicate for the legislation of NL and the development of NL format.

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The Study of Compaction Characteristics of Cataclasite Fill Material using Large and Standard Compaction Tests (대형다짐시험 및 표준다짐시험을 이용한 파쇄암 성토재의 다짐특성 연구)

  • Jeoung, Jae-Hyeung;Ryu, Sang-Hun;Choi, Dong-Yub;Park, Kwang-Sik;Hwang, Sung-Pil
    • The Journal of Engineering Geology
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    • v.26 no.4
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    • pp.439-445
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    • 2016
  • The new airports apply the systematic runway foundation construction to build the high quality runways in order to take the leading position to win future aerial demands and stay ahead of competitors. This study is intended to supplement the weakness of existing standard compaction test to minimize residual settlement of lower weak foundation during operation of passenger berthage. The fill material was sampled from 4 construction sites using the fill material with diameter of 100mm or less, and the standard compacting test (KS F 2312), large circular mold compacting test, and water-replacement field density test (ASTM D 5030) were conducted. The regression analysis of correlation of the field density test and the standard indoor compaction test showed the unreliable value at P-value of 0.05, and the regression analysis of the field density test and the large indoor compaction test showed the high correlation with R value of 0.8878. It is judged that the construction of overall uniform quality can be assured as the site condition is truly reflected only if the compacting test method is selected in consideration of maximum size of fill material when evaluating the maximum dry density used in design and construction.

Effects of Catalysts and Blowing Agents on the Physical Properties and Cell Morphology of Polyurethane Foams (폴리우레탄 폼의 물성과 Cell Morphology에 대한 촉매와 발포제의 영향)

  • Kwon, Hyun;Lee, Su Heon;Kim, Sang Bum;Bang, Moon-Soo;Kim, Youn Cheol
    • Applied Chemistry for Engineering
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    • v.16 no.3
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    • pp.379-384
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    • 2005
  • Polyurethane foams (PUFs) were prepared from polymeric 4,4'-diphenylmethane diisocyanate (PMDI), seven polyols with different functionalities and OH values, silicone surfactant, two catalysts, and three blowing agents. Chlorofluorocarbon (CFC-11), hydrochlorofluorocarbon (HCFC-141b) and hydrofluorocarbon (HFC-365mfc) were used as blowing agents. The effect of gelling and blowing catalysts on basic properties and cell structure of PUF with HCFC-141b was investigated. The cell size of the PUF decreased with an increase in the amount of catalyst from 0 to 2 pph (parts per hundred polyol). In the case of gelling type catalyst, the compressive strength increased from 11.9 to $12.66kg_f/cm^2$ with an increase in the amount catalyst from 0 to 2 pph but the density did not change significantly. The gelling time, density, and compressive strength of the PUF with three different blowing agents were measured. There was no detectable change in their properties. However, the cell structure of PUF with HCFC-141b was not uniform as in the other systems.

Effect of Additives on Preparation of Porous Alumina Membrane by Anodic Oxidation in Sulfuric Acid (황산전해조에서 양극산화에 의한 다공성 알루미나 막의 제조시 첨가제의 영향)

  • Lee, Chang-Woo;Lee, Yoong;Kang, Hyun-Seop;Chang, Yoon-Ho;Hong, Young Ho;Hahm, Yeong-Min
    • Applied Chemistry for Engineering
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    • v.9 no.7
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    • pp.1030-1035
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    • 1998
  • The porous alumina membrane was prepared from aluminum metal(99.8%) by anodic oxidation using DC power supply of constant current mode in an aqueous solution of sulfuric acid. To prevent the chemical dissolution of alumina membrane, $Al_2(SO_4)_3$, $AlPO_4$ and $Al(NO_3)_3$ which could be considered to supply $Al^{3+}$ ions were added to electrolyte solution at a reaction temperature of $20^{\circ}C$ and cumulative charge of $150C/cm^2$. Effects of these additives on the formation of porous alumina membrane were evaluated under various electrolyte concentration(5~20 wt%) and current densities($10{\sim}50mA/cm^2$). The membrane surfaces which were prepared in electrolyte solution with all the additives except $Al_2(SO_4)_3$ were damaged. However, when $Al_2(SO_4)_3$ was added to the $H_2SO_4$ solution, an uniform surface of porous alumina was obtained. Also, it was shown that the pore size of membrane was nearly independent on the quantity of $Al_2(SO_4)_3$ added at same electrolyte concentration and current density.

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Growth Inhibition and Ultra-Structural Changes of Saccharomyces cerevisiae by Paraquat (Saccharomyces cerevisiae에 대(對)한 제초제(除草劑) Paraquat의 증식(增殖)저해 작용(作用) 및 효모균체(酵母菌體)의 미세구조(微細構造)의 변화(變化))

  • Park, Young-Sill;Kim, Mi-Lim;Choi, Kyoung-Ho
    • Applied Biological Chemistry
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    • v.29 no.4
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    • pp.359-365
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    • 1986
  • Exponentially growing cells of S. cerevisiae were cultivated in the concomitant presence of $2{\times}10^{-3}\;M$ paraquat for 12 hours. Cellular growth became slower as the time passed and then, it was completely inhibited after 6 hours of cultivation. More than 70 percent of the yeast cells were killed with in 12 hours of paraquat treatment. It was observed that size of the yeast cell varied from $4.5{\times}5.5{\um}m$ to $2.5{\times}3.5{\um}m$ in diameter, while that of control was uniform. The number of budding cells became rare, Cell wall of the paraquat treated cell was thinner$(0.15{\mu}m)$ than that of control cell$(0.20{\mu}m)$. Outer part of the cell wall had higher density than inner part. Membrane structures such as plasma membrane and mitochondria was decomposed during the paraquat treatment for 12 hours.

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