• Title/Summary/Keyword: uniform CA

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A Study on Bloating of Porous Foam by Pressure Infiltration with H2O2 (과산화수소의 가압침투에 의한 다공성 발포체에 관한 연구)

  • Kim, Gui-Shik;Jeong, Ji-Hyun
    • Journal of Power System Engineering
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    • v.20 no.5
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    • pp.86-91
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    • 2016
  • This paper is concerned chiefly with the method of porous foam manufacture using basalt stone powder sludge. The hydrogen peroxide($H_2O_2$) of bloating agent has lots of problems to manufacture porous lightweight aggregate due to fast reaction rate with cement or calcium hydroxide($Ca(OH)_2$). The $H_2O_2$ injecting method using nozzle for manufacturing porous lightweight aggregate is proposed, in this study. This method is to inject $H_2O_2$ at the pressure of 10 MPa on upper side of slurry mixing materials such as stone powder sludge and quick-lime(CaO) by injector. The specimen was dried in furnace at $100^{\circ}C$ for 1 hour and cured at ambient temperature for 30 days. We analyzed the characteristics including specific gravity and water absorption. The experiments were found that the porous foam has low specific gravity, high water absorption and uniform distribution of porous more than manufactured foam by general bloating methods.

Fabrication and Sensing Properties of Pt-electrode/NASICON Solid Electrolyte/ Carbonate(Na2CO3-K2CO3-CaCO3system ) Electrode for CO2gas sensor (CO2용 Pt전극/NASICON고체전해질/Carbonate (Na2CO3-K2CO3-CaCO3 계) 전극의 가스 센서제작 및 특성)

  • Choi, Jin-Sam;Bae, Jae-Cheol;Bang, Yeong-Il;Lee, Deok-Dong;Huh, Jeung-Su
    • Korean Journal of Materials Research
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    • v.12 no.4
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    • pp.269-273
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    • 2002
  • The NASICON solid electrolyte films, $Na_{1+x}Zr_2Si_xP_{3-x}O_{12}$(1.5< x < 2.3), was prepared from ceramic slurry by modified doctor-blade process. The NASICON solid electrolyte and fabricated sensors, Pt-electrode/NASICON/Carbonate$(Na_2CO_3-K_2CO_3CaCO_3\; system)$ electrode, were investigated to measure phase, microstructure and e.m.f variation for sensing $CO_2$ concentration. The uniform grain size of $2-4{\mu}m$ and major phase of sodium zirconium silicon phosphate phase, $Na_{1+x}Zr_2Si_xP_{3-x}O_{12}$was identified with X-ray diffraction patterns and scanning electron microscopy, respectively. The Nernst's slope of 84 mV/decade for $CO_2$ concentration from 500 to 8000 ppm was obtained at operating temperature of $400^{\circ}C$.

Complementary Beamforming Method Increasing Throughput in ECMA UWB AAS Systems (ECMA UWB AAS 시스템의 전송률 향상을 위한 보완 빔 방법)

  • Kim, Seok-Hyeon;Ji, Young-Gun;Lee, Hong-Won;Chung, Jae-Hak
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.32 no.8A
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    • pp.827-835
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    • 2007
  • In this paper, the extension method of data transmission range as adapting AAS(Adaptive Antenna Systems) in ECMA(European Computer Manufacturers Association) standard MB-OFDM(MultiBand-Orthogonal Frequency Division Multiplexing) UWB systems is proposed, and the complementary beamforming method which can solve hidden beam problem when we adapt AAS in CSMA/CA(Carrier Sense Multiple Access with Collision Avoidance) systems is proposed. To design the complementary beamforming, Gram-Schmidt orthogonalization is utilized, whose beam pattern exhibits perfect nulling at the main beam angles and provides uniform power for detection of channel utilization out of main beam. The proposed method can be utilized with any arbitrary beamforming when we make main beamforming. Through computer simulation, it can be shown that proposed AAS and complementary beamforming increase data transmission range from 2m to 3.95m in 480Mbps data transmission system and increase throughput about 20% as compared with general UWB AAS systems.

The Spreading Characteristics of the (Polymer/18-Crown-6) Composite Solution for Water Cast-Membranes ((Polymer/18-Crown-6)복합박막 제조용액의 수면전개 특성)

  • 남석태;최호상;최성부;김병식
    • Membrane Journal
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    • v.6 no.4
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    • pp.265-272
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    • 1996
  • The (polymer/carrier) composite membranes for separating the metallic ion have been prepared by the water cast-method. The morphology of these membranes was affected by the physical properties of the spreading solution. The surface tension of the (polymer/18-crown-6) composite solution was decreased with increasing the concentration of 18-crown-6 compound and the surface tension of polymer solution decreased the following order PVC>PS>CA. The viscosity of CA solution decreased with increasing the contents of the 18-crown-6 compound, but PVC and PS solutions showed no significance changes according as the concentration of 18-crown-6 compound. In the composite solutions, the spreading ability was improved by' the cyclic 18-crown-6 molecules which acted as an electric buffer and diminished the intermolecular force between the polymer chains. The (polymer/18-crown-6) composite membrane was more uniform than that of the mono polymer membrane on the coagulation state of polymer, and the top and bottom sides of membrane showed also the more smooth structure according as the concentration increment of 18-crown-6 molecule.

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Hydrothermal Coating of Hydroxyapatite on ZrO2 Ceramics

  • Ha, Jung-Soo
    • Journal of the Korean Ceramic Society
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    • v.43 no.8 s.291
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    • pp.463-468
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    • 2006
  • Hydrothermal deposition of hydroxyapatite coatings on two types of $ZrO_2$ substrates (3 mol% $Y_2O_3$-doped and 13 mol% $CeO_2$-doped tetragonal $ZrO_2s$) was studied using aqueous solutions of $Ca(NO_3)_2\;4H_2O$ and $(NH_4)_2HPO_4$ containing EDTA (ethylene diamine tetra acetic acid) disodium salt as a chelating agent for $Ca^{2+}$ ions. For the precipitation of the coatings, the $EDTA-Ca^{2+}$ chelates were decomposed by oxidation with $H_2O_2$ at $90^{\circ}C$. The deposition behavior, morphology, and orientation of the coatings were investigated while varying the solution pH using scanning electron microscopy and X-ray diffractometry. For the two sub-strates, sparse deposition of the coating was obtained at pH 5.5, whereas a uniform deposition was obtained at pH 7.1, 9.8, and 11.4 with a denser microstructure for the higher pH. The coating consisted of thin needle-like or plate-like crystals ($1-2{\mu}m$ length or diameter) at pH 7.1, but fine rod-like crystals ($1-2{\mu}m$ length, $0.1{\mu}m$ diameter) at pH 9.8 and 11.4. The coatings were $1-3{\mu}m$ thick and showed a preferred orientation of the hydroxyapatite crystals with their c axis (i.e., the elongated direction) perpendicular to the substrate surface especially for pH 9.8 and 11.4.

Grain Growth Behavior of Heat Treated Mg-0.6wt.%Zn-0.6wt.%Ca Alloy Sheet Manufactured via Twin Roll Casting and Hot Rolling (트윈롤 주조 후 열간압연된 Mg-0.6wt.%Zn-0.6wt.%Ca 합금 판재의 열처리에 따른 결정립 성장 거동)

  • Lee, Hee Jae;Park, No Jin
    • Journal of the Korean Society for Heat Treatment
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    • v.35 no.2
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    • pp.74-81
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    • 2022
  • This study aims to mitigate the microstructural heterogeneity arising from the manufacture of magnesium alloy plates using the twin roll casting (TRC) process. Homogenization was introduced through hot rolling and heat treatment, followed by confirmation of observed changes in the microstructure. Following the TRC process, the hot rolled 2mm plate exhibited a dendritic cast structure tilted in the roll rotation direction, while central segregation were developed. This nonuniform structure and central segregation disappeared upon heat treatment, followed by recrystallization to form uniform and fine grains. Abnormal grain growth (AGG) was observed over the course of heat treatment; grains exhibiting AGG occupied up to 75% of the total area after having held the sample at 400℃ for 64 h. The formation of coarse grains was also observed during heat treatment at 340℃ over a relatively long duration, though the maximum grain size was significantly smaller than that corresponding to the heat treatment at 400℃. AGG in the 400℃ heat treatment occurred because of movement of the grain boundary, which had been fixed prior as a result of the grain boundary fixing effect of the precipitation phase. The re-dissolution of the Ca2Mg5Zn5 precipitated phase over the long duration of the high-temperature annealing process caused the surrounding grains to disappear and regrow.

Influence of Feeding Processed Cottonseed Meal on Meat and Wool Production of Lambs

  • Nagalakshmi, D.;Sastry, V.R.B.;Rao, V. Kesava
    • Asian-Australasian Journal of Animal Sciences
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    • v.15 no.1
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    • pp.26-33
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    • 2002
  • In order to assess the effect of feeding raw or processed cotton (Gossypium) seed meal (CSM) on meat and wool production, 30 male crossbred lambs (3-4 months) of uniform body weight were assigned equally to five dietary treatments in a completely randomised design. The CSM was processed by three different methods i.e., cooking the meal at $100^{\circ}C$ for 45 minutes, treatment with 1% calcium hydroxide ($Ca(OH)_2$) for 24 h and iron treatment in the ratio of 1 part free gossypol (FG) to 0.3 parts of iron for 30 minutes. The lambs were fed isonitrogenous and isocaloric concentrate mixtures, containing 30% deoiled peanut meal (reference diet) and 40% of either raw, cooked, $Ca(OH)_2$ or iron treated CSM for 180 days. The raw and variously processed CSM replaced about 50% nitrogen of reference concentrate mixture. The concentrate mixtures were fed to meet 80% of the protein requirements (NRC, 1985) along with ad libitum chopped maize (Zea mays) hay. The slaughter weight, empty body weight and carcass weight was higher ($p{\leq}0.01$) in lambs fed cooked CSM incorporated diets, compared to diets containing deoiled peanut meal (DPNM). These parameters were not influenced by feeding diets containing either raw, $Ca(OH)_2$ or iron treated CSM in comparison DPNM diets. The carcass length, loin eye area and edible and inedible portion of carcass and the meat: bone ratio in whole carcass were also not affected by feeding CSM based diets. Among various primal cuts, the yield of legs was lower ($p{\leq}0.05$) from raw CSM fed lambs in comparison to DPNM fed lambs. The fat content in the Longissimus dorsi muscle was reduced ($p{\leq}0.05$) in lambs fed processed CSM based diets compared to those fed DPNM diet. Replacing DPNM with either raw or processed CSM based diets did not influence the sensory attributes and overall acceptability of meat. The wool yield was higher ($p{\leq}0.05$) in iron treated CSM fed lambs. The fibre length and fibre diameter were comparable among lambs on various dietary regimes. Among lambs fed variously processed CSM diets, the feed cost per kg of edible meat production was lower ($p{\leq}0.05$) on $Ca(OH)_2$ treated CSM, followed by cooked CSM diet and then on raw CSM based diets compared to DPNM diet. The CSM after 1% $Ca(OH)_2$ treatment or cooking for 45 minutes appears to be a satisfactory protein supplement in lamb diets for meat and wool production to replace at least 50% nitrogen of scarce and costly peanut meal.

Comparison of Anticariogenic Effect after Applying Fluoride Varnish on Sound and Artificial Caries Enamel (정상법랑질과 인공우식법랑질에 불소바니쉬 도포 후 항우식 효과 비교)

  • Jeong, Moon-Jin;Lim, Ji-Hyang;Min, Ji-Hye;Jeong, Soon-Jeong;Son, Jung-Hui;Lim, Do-Seon
    • Journal of dental hygiene science
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    • v.13 no.4
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    • pp.461-470
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    • 2013
  • In order to examine the anticariogenic effect after fluoride varnish was applied to sound enamel and artificial caries enamel, anterior teeth of healthy cattle were used and divided into four groups such as group 1 (sound enamel), group 2 (application of fluoride varnish to sound enamel), group 3 (artificial caries enamel) and group 4 (application of fluoride varnish to artificial caries enamel). Remineralization on the surface of enamel and changes of crystalline structure after demineralization were observed by using a field emission scanning electron microscope (FE-SEM). Quantitative analysis of Ca and P was measured by using the energy dispersive X-ray spectrophotometer (EDS). The following conclusions were obtained: 1)Surface pattern of enamel was the roughest in group 3 due to the defects caused by porosity and microcracks. Group 4, group 1 and group 2 were followed in order; 2) It was found that pattern of crystalline structures in a group of application of fluoride varnish and a group of no application showed bigger change in artificial caries enamel than that in sound enamel. In other words, groups 4 and 1 showed a similar pattern; 3) The contents of Ca and P were higher in groups of application of fluoride varnish (group 2 and group 4) than in groups of no application of fluoride varnish (group 1 and group 3). Taken results of this study together, in the case of application of fluoride varnish, crystalline structure was changed by remineralization even in the sound enamel. In particular, porous structures showed a smooth and uniform pattern due to the recalcification in the artificial caries enamel. In addition, according to results of EDS analysis, the contents of Ca and P were increased and it had great anticariogenic effects which inhibit decalcification of sound enamel and artificial caries enamel.

Metallurgical Study of Iron Artifacts from Guryong-ri Site in Ungcheon, Boryeong

  • Choi, Eun Young;Cho, Nam Chul
    • Journal of Conservation Science
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    • v.38 no.4
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    • pp.289-300
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    • 2022
  • In the 6th and 7th centuries, 5 iron artifacts excavated form the Baekje Stone Tomb in Guryong-ri site, Ungcheon, Boryeong, were studied. The sample were metal microscopic observation, SEM-EDS analysis and Raman micro-spectroscopy analysis were conducted to understand the metallurgical characteristics. The microstructure observation showed the presence of ferrite and pearlite throughout, and differences in carbon content existed depending on the direction. Non-metallic inclusions were in the form of long lines, and most of them were wüstite, fayalite. It is indicated that the artifacts were forge welded using hypoeutectoid steel, with signs of carburizing and decarburizing processes. Some crystals with high P2O5, TiO2, CaO content were identified as sarcopside, ulvöspinel, and perovskite, respectively, through Raman spectroscopy. A comparison of the results with previous studies on the sites of Bujang-ri site in Seosan and Bongseon-ri site in Seocheon, which are adjacent sites in the coastal area, revealed that, while heat treatment technology was available, the artifacts were not heat-treated considering the purpose for use for these artifacts. The chemical composition of the non-metallic inclusions P2O5, TiO2, CaO were plotted in proportions to SiO2 and compared with adjacent sites. Considering that the P2O5/SiO2 ratio was widely distributed, the refining technology was not uniform. In addition, the TiO2/SiO2 ratio was found to be higher than that of other sites, meaning that a titanium-containing ore was used to manufacture the artifacts, unlike in surrounding sites, but it is not detected in all artifacts, so it may have been affected by various factors such as furnace walls in addition to raw materials. Although slag formers were used, considering the CaO/SiO2 ratio and the (Al2O3/SiO2)/(CaO/SiO2) ratio, which appear to be similar to the surrounding sites, but it is possible that CaO containing raw ore was used because it is also affected by the components of raw ore. As a result of the study, it is highly likely that ore different from that of the surrounding sites was used for production, but a more comprehensive comparative study with the surrounding sites is needed in the future.

Cultivation of Oyster Mushroom[Pleurotus ostreatus (Jacq. ex Fr.) Kummer] at Medium with Ca(OH)2 Treatment (수산화칼슘[Ca(OH)2] 처리 배지를 이용한 느타리버섯의 재배)

  • Baek, Seung-Hwa;Lee, Yeong-Il;Yoo, Ki-Yong;Han, Seong-Soo
    • Korean Journal of Environmental Agriculture
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    • v.27 no.4
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    • pp.303-313
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    • 2008
  • This research is aimed to investigate the cultivation method of oyster mushroom[Pleurotus ostreatus (Jacq. ex Fr.) Kummer] at the non-sterilized medium with $Ca(OH)_2$ treatment. Therefore, experiments were carried out to develop non-sterilization method of medium by addition of $Ca(OH)_2$ for omission of heat sterilization progress of medium. General components, minerals and amino acid in Jiri wild type No. 1 (Pleurotus ostreatus) and production cost were analyzed. For the purpose of omission of heat sterilization progress, treatment ratio of $Ca(OH)_2$ (purity 95%) was 5%(w/w) of dry medium. Initial pH of this medium was 11 and then the pH was changed by 9 after the uniform mixing of the medium for half an hour. The various germs occurred 50% and 100% at pH 8 and pH 7 of the non-sterilized medium, respectively. Production of oyster mushroom increased by $2,030\;ton\;ha^{-1}$ when the main raw material used corn pith instead of waste cotton. The time required of mycelium culture was 30 days when hypha was cultured at the non-sterilized medium, and pinhead occurred when 2 or 3 days was passed after the time required of mycelium culture. Occurrence of pinhead was most rapid at the condition of $22{\sim}26^{\circ}C$, 65% humidity and pH $6.5{\sim}7.0$ and required of $22{\sim}28$ days at $70{\sim}80\;mm$ thickness of non-sterilized medium. Ca content in 1st harvest oyster mushroom was higher than that in 2nd harvest one, and its difference was $30.3\;mg\;kg^{-1}$. Amino acid content by stipe thickness of oyster mushroom was ranged from 411.2 to $343.9\;mg\;kg^{-1}$ both in a pileus and a stipe of 1st harvest mushroom, and from 402.4 to $498.2\;mg\;kg^{-1}$ and from 442.6 to $470.4\;mg\;kg^{-1}$ in those of 2nd harvest one, respectively. The results of the present study suggest that the non-sterilization medium by addition of $Ca(OH)_2$ is usable with the cultivation of oyster mushroom.