• Title/Summary/Keyword: two-metal system

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Distribution of Trace Metals in Sediments of Mokpo Coastal Area after a Strong Rainfall

  • Kim Do Hee;Sin Yong Sik
    • Fisheries and Aquatic Sciences
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    • v.5 no.4
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    • pp.302-307
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    • 2002
  • The characteristics of trace metals were investigated in the sediments of the Mokpo coastal area, southwestern coast of Korea. Surface sediments were collected in September 3, 2002 after a strong rain event. The sampling sites were categorized into the inner and outer harbour based on salinity distribution and difference of trace metal concentration was evidence between these two zones. The enrichment factor (E' F) of Zn and Cr were high at the mouth of Mokpo Harbour and $E \cdot F$ of Cu was high at the east-south of Dali Island. One hundred percent of Mn and Pb samples and $40\%$ of Zn samples had E' F higher than 1 suggesting that they are accumulated in the entire outer of Mokpo Harbour. Trace metals appeared to be accumulated in the inner harbour by input of sediments in the discharged freshwater from Young-San River during strong rainfall whereas they were influenced by natural sedimentation and human activities in part.

Development of Continuous Flow Microwave Digestion Procedures for Analysis of Trace Metal in Water Using Ion Chromatography

  • Youn Doo Kim;Gae Ho Lee;Hyung Seung Kim;Dong Soo Kim;Kwang Kyu Park
    • Bulletin of the Korean Chemical Society
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    • v.15 no.9
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    • pp.786-791
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    • 1994
  • A simple and rapid sample pretreatment process necessary for determination of metal oxides in water was proposed. Samples were injected into the continuous-flow tube installed inside the microwave oven and the treated samples were cooled before entered to the Ion Chromatography (IC) or Inductively Coupled Plasma (ICP). By coupling this microwave digestion system with IC or ICP, a fully automatic analytical procedures may be easily established. In this study, two different types of digestion methods were considered; the open tubing method (OTM) and the restraint tubing method (RTM). The RTM was proved to be 3 times faster in digestion period and 10 times higher in detection range than the OTM. Validation of proposed sample digestion system was carried out by using an ICP. The results showed that both of continuous-flow methods, the OTM and the RTM were comparable in accuracies with the conventional batch-type vessel digestion method.

A Studyon Microwave Ampilifer using GaAs MESFET (GaAs MESFET를 이용한 초고주파 증폭기에 관한 연구)

  • 박한규
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.13 no.5
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    • pp.1-8
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    • 1976
  • Microwave GaAs Metal Semiconductor Field effect Transistors (MESFET) with the gate-length of two micrometers are investigated. The scattering parameters of the transistors have been measured from 1GHz to 2GHz by Hp8545 Automatic network analyzer. From the measured data, an equivalent circuit is established which consists of an ntrinsic and. extrinsic transistor elements. In this paper, GaAb MESFET Amplifier is used in conjunction with conventional microstrip techniques to match into a 50 ohms high input/output impedances system. We found that Power gain is less than 8dB and VSWR is less than 1.5 in L-Band.

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Two-Chip Integrated Humidity Sensor Using Thin Polyimide Films (폴리이미드 박막을 이용한 투 칩 집적화 습도 센서)

  • 민남기;김수원;홍석인
    • Journal of the Korean Institute of Telematics and Electronics D
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    • v.35D no.9
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    • pp.77-86
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    • 1998
  • A two-chip humidity sensor system has been developed which consists of a capacitive sense element die and a CMOS interface chip. The sense element was fabricated using thin polyimide films on (100) silicon substrate and showed excellent linearity(0.72%FS), low hysteresis (<3%) and low temperature coefficient(-0.0285 ~-0.0542pF/K) over a wide range of relative humidity and temperature. The capacitance-relative humidity characteristic exhibited a drift of 2~3% after 9 weeks of exposure to 4$0^{\circ}C$/90%RH. The signal-conditioning circuitry was fabricated using an 1.2- ${\mu}{\textrm}{m}$, one poly double metal CMOS process. The measured output voltage of the sensor system was directly proportional to relative humidity and showed good agreement with theory.

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Rh-doped carbon nanotubes as a superior media for the adsorption of O2 and O3 molecules: a density functional theory study

  • Cui, Hao;Zhang, Xiaoxing;Yao, Qiang;Miao, Yulong;Tang, Ju
    • Carbon letters
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    • v.28
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    • pp.55-59
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    • 2018
  • Transition-metal-embedded carbon nanotubes (CNTs) have been accepted as a novel type of sensing material due to the combined advantage of the transition metal, which possesses good catalytic behavior for gas interaction, and CNTs, with large effective surface areas that present good adsorption ability towards gas molecules. In this work, we simulate the adsorption of $O_2$ and $O_3$ onto Rh-doped CNT in an effort to understand the adsorbing behavior of such a surface. Results indicate that the proposed material presents good adsorbing ability and capacities for these two gases, especially $O_3$ molecules, as a result of the relatively large conductivity changes. The frontier molecular orbital theory reveals that the conductivity of Rh-CNT would undergo a decrease after the adsorption of two such oxidizing gases due to the lower electron activity and density of this media. Our calculations are meaningful as they can supply experimentalists with potential sensing material prospects with which to exploit chemical sensors.

A Numerical Study on the Heat Transfer Characteristics of a Metal Hydride Reactor with Embedded Heat Pipes (내부에 히트파이프를 삽입한 메탈 하이드라이드 반응기의 열전달 특성에 대한 수치해석 연구)

  • Park, Young-Hark;Boo, Joon-Hong
    • Proceedings of the KSME Conference
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    • 2008.11b
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    • pp.2346-2351
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    • 2008
  • This study deals with heat pipes inserted into the metal hydride(MH) reactor to increase the effective thermal conductivity of the system and thus to enhance the thermal control characteristics. A numerical analysis was conducted to predict the effect of inserted heat pipes on the heat transfer characteristics of MH, which inherently has extremely low thermal conductivity. The numerical model was a cylindrical container of O.D. 76.3 mm and length 1 m, which is partially filled with about 60% of MH material. The heat pipe was made of copper-water combination, which is suitable for operation temperature range between $10^{\circ}C$ and $80^{\circ}C$. Both inner -and outer- heat pipes were considered in the model. Less than two hours of transient time is of concern when decreasing or increasing the temperature for absorption and discharge of hydrogen gas. FLUENT, a commercial software, was employed to predict the transient as well as steady-state temperature distribution of the MH reactor system. The numerical results were compared and analyzed from the view point of temperature uniformity and transient time up to the specified maximum or minimum temperatures.

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Heavy Metal Detection and Removal in Artificial Wastewater Using Two-Component System Based Recombinant Bacteria (Two-component System 기반 재조합균을 이용한 인공폐수에서의 중금속 인지 및 제거)

  • Ravikumar, Sambandam;Hong, Soon-Ho;Yoo, Ik-Keun
    • Korean Journal of Microbiology
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    • v.48 no.3
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    • pp.187-191
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    • 2012
  • Two-component system (TCS)-based bacterial zinc and copper biosensors, in which green fluorescent protein (GFP) is expressed under the control of zraP and cusC promoter in ZraS/R and CusS/R TCS, were evaluated in artificial wastewater. Bacterial biosensors developed in this study efficiently expressed GFP by the recognition of $Zn^{2+}$ and $Cu^{2+}$ in artificial wastewater. Secondly, TCS-based zinc and copper removing bacteria with the peptide displayed on cell surface were examined in artificial wastewater. Zinc and copper removing bacteria expressed the peptide as a fusion protein such as OmpC-ZBP (zinc binding peptide) and OmpC-CBP (copper binding peptide) on the cell surface when sensing exogenous $Zn^{2+}$ and $Cu^{2+}$ through ZraS/R and CusS/R TCS. The recombinant cell expressing metal-adsorbing peptide could efficiently remove copper and zinc (15 and 18 mg/g dry cell weight, respectively) in artificial wastewater. Therefore, it was demonstrated that the TCS-based recombinant cell for the recognition or removal of heavy metal functions well in artificial wastewater environment.

Archaeological geophysics: 3D imaging of the Muweilah archaeological site, United Arab Emirates

  • Evangelista Ryz;Wedepohl Eric
    • Geophysics and Geophysical Exploration
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    • v.7 no.1
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    • pp.93-98
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    • 2004
  • The sand-covered Muweilah archaeological site in the United Arab Emirates (UAE) is a unique Iron Age site, and has been subject to intensive investigations. However, excavations are time consuming and may require twenty years to complete. Thus geophysical surveys were undertaken with the objective of characterising the site more expeditiously. This paper presents preliminary results of these surveys. Ground penetrating radar (GPR) was tested as a primary imaging tool, with an ancillary shallow time domain EM (MetalMapper) system. Dense 3D GPR datasets were migrated to produce horizontal (plan view) depth slices at 10 cm intervals, which is conceptually similar to the archaeologists' excavation methodology. The objective was to map all features associated with anthropogenic activity. This required delineating extensive linear and planar features, which could represent infrastructure. The correlation between these and isolated point reflectors, which could indicate anthropogenic activity, was then assessed. Finally, MetalMapper images were used to discriminate between metallic and non-metallic scatterers. The moderately resistive sand cover allowed GPR depth penetration of up to 5 m with a 500 MHz system. GPR successfully mapped floor levels, walls, and isolated anthropogenic activity, but crumbling walls were difficult to track in some cases. From this study, two possible courtyard areas were recognised. The MetalMapper was less successful because of its limited depth penetration of 50 cm. Despite this, the system was still useful in detecting modem-day ferruginous waste and bronze artefacts. The results (subject to ongoing ground-truthing) indicated that GPR was optimal for sites like Muweilah, which are buried under a few metres of sand. The 3D survey methodology proved essential to achieve line-to-line correlation for tracking walls. In performing the surveys, a significant improvement in data quality ensued when survey areas were flattened and de-vegetated. Although MetalMapper surveys were not as useful, they certainly indicated the value of including other geophysical data to constrain interpretation of complex GPR features.

Stabilization of Two Mine Drainage Treated Sludges for the As and Heavy Metal Contaminated Soils (오염토양 특성별 광산배수처리슬러지의 비소 및 중금속 안정화)

  • Tak, Hyunji;Jeon, Soyoung;Lee, Minhee
    • Journal of Soil and Groundwater Environment
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    • v.27 no.4
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    • pp.10-21
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    • 2022
  • In the South Korea, 47% of abandoned mines are suffering from the mining hazards such as the mine drainage (MD), the mine tailings and the waste rocks. Among them the mine drainage which has a low pH and the high concentration of heavy metals can directly contaminate rivers or soil and cause serious damages to human health. The natural/artificial treatment facilities by using neutralizers and coagulants for the mine drainage have been operated in domestic and most of heavy metals in mind drainage are precipitated and removed in the form of metal hydroxide, alumino-silicate or carbonate, generating a large amount of mine drainage treated sludge ('MDS' hereafter) by-product. The MDS has a large surface area and many functional groups, showing high efficiency on the fixation of heavy metals. The purpose of this study is to develop a ingenious heavy metal stabilizer that can effectively stabilize arsenic (As) and heavy metals in soil by recycling the MDS (two types of MDS: the acid mine drainage treated sludge (MMDS) and the coal mine drainage treated sludge (CMDS)). Various analyses, toxicity evaluations, and leaching reduction batch experiments were performed to identify the characteristics of MDS as the stabilizer for soils contaminated with As and heavy metals. As a result of batch experiments, the Pb stabilization efficiency of both of MDSs for soil A was higher than 90% and their Zn stabilization efficiencies were higher than 70%. In the case of soil B and C, which were contaminated with As, their As stabilization efficiencies were higher than 80%. Experimental results suggested that both of MDSs could be successfully applied for the As and heavy metal contaminated soil as the soil stabilizer, because of their low unit price and high stabilization efficiency for As and hevry metals.

Development of a System Analysis Code, SSC-K, for Inherent Safety Evaluation of The Korea Advanced Liquid Metal Reactor

  • Kwon, Young-Min;Lee, Yong-Bum;Chang, Won-Pyo;Dohee Hahn;Kim, Kyung-Doo
    • Nuclear Engineering and Technology
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    • v.33 no.2
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    • pp.209-224
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    • 2001
  • The SSC-K system analysis code is under development at the Korea Atomic Energy Research Institute (KAERI) as a part of the KALIMER project. The SSC-K code is being used as the principal tool for analyzing a variety of off-normal conditions or accidents of the preliminary KALIMER design. The SSC-K code features a multiple-channel core representation coupled with a point kinetics model with reactivity feedback. It provides a detailed, one-dimensional thermal-hydraulic simulation of the primary and secondary sodium coolant circuits, as well as the balance-of-plant steam/water circuit. Recently a two-dimensional hot pool model was incorporated into SSC-K for analysis of thermal stratification phenomena in the hot pool. In addition, SSC-K contains detailed models for the passive decay heat removal system and a generalized plant control system. The SSC-K code has also been applied to the computational engine for an interactive simulation of the KALIMER plant. This paper presents an overview of the recent activities concerned with SSC-K code model development This paper focuses on both descriptions of the newly adopted thermal hydraulic and neutronic models, and applications to KALIMER analyses for typical anticipated transients without scram.

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