• Title/Summary/Keyword: two-dimensional materials

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Development of Operational Technology and Integrated Measurement Information Management System for the Radioactivity Measurement Device (방사능 측정장치 운영 기술 및 측정정보 통합관리 시스템 개발)

  • Dong-Sik Jin;Kyeong-Ryeong Kim;Jae-Geun Lee
    • Journal of radiological science and technology
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    • v.47 no.3
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    • pp.183-195
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    • 2024
  • Additional functional upgrades to the large-area compton camera (LACC) measurement device that can provide characteristics evaluation information (nuclear species and radioactivity) and two-dimensional or three-dimensional distribution imaging information of radioactive materials existing in surface or internal of concrete structures are required in terms of work stability and efficiency in order to apply to actual decommissioning sites such as nuclear power plants or medical cyclotron facilities by using this measurement device. To this purpose, the technology that allows radiation workers to intuitively and visually check the distribution of radioactive materials in advance by matching the two-dimensional distribution imaging information of radioactive materials obtained through the LACC measurement device and visual imaging of the measurement zone (10 m × 5 m) was developed. In addition, the separate system that can automatically adjust the position (height) in units of the measurement area size (0.7 m × 0.3 m × 0.8 m) of the LACC measurement device was developed and the integrated management system for characteristics evaluation information and two-dimensional or three-dimensional distribution imaging information obtained per unit of measurement for radioactive materials was developed. These functional upgrades related to LACC measurement device can improve work efficiency and safety when measuring radioactivity of concrete structures and enable the establishment of appropriate decommissioning strategies using radioactivity measurement information for decommissioning nuclear power plants or medical cyclotron facilities.

Atomic Resolution Scanning Transmission Electron Microscopy of Two-Dimensional Layered Transition Metal Dichalcogenides

  • Lu, Ning;Wang, Jinguo;Oviedo, uan Pablo;Lian, Guoda;Kim, Moon Jea
    • Applied Microscopy
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    • v.45 no.4
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    • pp.225-229
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    • 2015
  • Transition metal dichalcogenides (TMDs) are a class of two-dimensional (2D) materials that have attracted growing interest because of their promising applications. The properties of TMDs strongly depend on the crystalline structure and the number and stacking sequence of layers in their crystals and thin films. Though electrical, mechanical, and magnetic studies of 2D materials are being conducted, there is an evident lack of direct atom-by-atom visualization, limiting insight on these highly exciting material systems. Herein, we present our recent studies on the characterization of 2D layered materials by means of aberration corrected scanning transmission electron microscopy (STEM), in particular via high angle annular dark field (HAADF) imaging. We have identified the atomic arrangements and defects in 2H stacked TMDs, 1T stacked TMDs, distorted 1T stacked TMDs, and vertically integrated heterojunctions of 2D TMDs crystals.

Effective Passivation of Black Phosphorus under Ambient Conditions

  • Yoon, Jongchan;Lee, Zonghoon
    • Applied Microscopy
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    • v.47 no.3
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    • pp.176-186
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    • 2017
  • Two-dimensional (2D) materials have been studied widely owing to their outstanding properties since monolayer graphene was isolated in 2004. Especially, among 2D materials, phosphorene, a single atomic layer of black phosphorus (BP), has been highlighted for its electrical properties. This material can serve as a substitute for graphene, which has been revealed as a "semi-metal", in next-generation semiconductors. However, few-layer BP is prone to degradation under ambient conditions owing to its reactivity with oxygen and water, which results in the condensation of water droplets on the surface of the BP flakes. This causes charge transfer from the phosphorus atom to oxygen, resulting in the formation of phosphoric acid (oxide) and degrades the various properties of BP. Therefore, it is necessary to find passivation methods to prevent BP flakes from being degraded under ambient conditions. This review article deals with recent studies on passivation methods for BP and their performance against oxygen and water, effects on the electrical properties of BP, and the extent to how they protect BP.

Design of Semiconducting Gas Sensors for Room-Temperature Operation

  • Song, Young Geun;Kim, Gwang Su;Ju, Byeong-Kwon;Kang, Chong-Yun
    • Journal of Sensor Science and Technology
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    • v.29 no.1
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    • pp.1-6
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    • 2020
  • Gas sensors that operate at room temperature have been extensively studied because of sensor stability, lift time, and power consumption. To design effective room-temperature gas sensors, various nanostructures, such as nanoparticles, nanotubes, nanodomes, or nanofibers, are utilized because of their large-surface-to-volume ratio and unique surface properties. In addition, two-dimensional materials, including MoS2, SnS2, WS2, and MoSe, and ultraviolet-activated methods have been studied to develop ideal room-temperature gas sensors. Herein, a brief overview of state-of-the-art research on room-temperature gas sensors and their sensing properties, including nanostructured materials, two-dimensional materials, the ultraviolet-activated method, and ionic-activated gas sensors, is provided.

Syntheses, Structures and Luminescent Properties of Two Novel M(II)-Phen-SIP Supramolecular Compounds (M = Co, Ni)

  • Zhu, Yu-Lan;Shao, Shuai;Ma, Kui-Rong;Tang, Xue-Ling;Cao, Li;Zhao, Hui-Chao
    • Bulletin of the Korean Chemical Society
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    • v.33 no.4
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    • pp.1259-1263
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    • 2012
  • Two metal compounds, $[Co(phen)_2(H_2O)_2]{\cdot}2H_2SIP{\cdot}2H_2O$ 1 and $[Ni(phen)_3]{\cdot}2H_2SIP{\cdot}3H_2O$ 2, have been obtained by incorporating 1,10-phenanthroline (phen) and 5-sulfoisophthalic acid monosodium salt ($NaH_2SIP$) ligands under hydrothermal conditions. Meanwhile, the two compounds were characterized by element analysis, IR, XRD, TG-DTA and single-crystal X-ray diffraction. Both 1 and 2 present 3D supramolecular structures via O-H${\cdots}$O hydrogen bond interactions. Luminescent properties for 1 and 2 were also studied. The compound 1 has two fluorescence emission peaks centered at 398 nm attributed to the intraligand emission from the SIP ligand and at 438 nm assigned to the combined interaction of intraligand ${\pi}^*-{\pi}$ transitions of the phen ligand and ligand-to-metal-charge-transfer (LMCT) transitions (${\lambda}_{ex}$ = 233 nm). The compound 2 shows one emission band centered at 423 nm with a shoulder peak at 434 nm which may be originated from the intraligand ${\pi}^*-{\pi}$ transitions of the phen ligand (${\lambda}_{ex}$ = 266 nm).

Wet to Shrink: an Approach to Realize Negative Expansion upon Wetting

  • Sun, L.;Huang, W.M.
    • Advanced Composite Materials
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    • v.18 no.2
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    • pp.95-103
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    • 2009
  • Composites can be designed to have special properties, and even such properties that are difficult to find in nature. We propose a simple approach to realize negative expansion upon wetting, i.e., contraction upon wetting, using swelling materials. The key parameters in one-dimensional case are investigated, and the possible configurations for two and three-dimensional cases are presented. The feasibility is demonstrated through a simple test.

Three dimensional flow analysis within a profile extrusion die by using control volume finite-element method

  • Kim, Jongman;Youn, Jae-Ryoun;Hyun, Jae-Chun
    • Korea-Australia Rheology Journal
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    • v.13 no.2
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    • pp.97-106
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    • 2001
  • Three-dimensional flow analysis was performed by using the control volume finite-element method for design of a profile extrusion die. Because polymer melt behavior is complicated and cross-sectional shape of the profile extrusion die is changing continuously, the fluid flow within the die must be analyzed three-dimensionally. A commercially available polypropylene is used for theoretical and experimental investigations. Material properties are assumed to be constant except for the viscosity. The 5-constant modified Cross model is used for the numerical analysis. A test problem is examined in order to verify the accuracy of the numerical method. Simulations are performed for conditions of three different screw speeds and three different die temperatures. Predicted pressure distribution is compared with the experimental measurements and the results of the previous two-dimensional study. The computational results obtained by using three dimensional CVFEM agree with the experimental measurements and are more accurate than those obtained by using the two-dimensional cross-sectional method. The velocity profiles and the temperature distributions within several cross-sections of the die are given as contour plots.

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Dimensional Responses of Wood Under Cyclical Changing Temperature at Constant Relative Humidity

  • Yang, Tiantian;Ma, Erni;Shi, Yi
    • Journal of the Korean Wood Science and Technology
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    • v.43 no.5
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    • pp.539-547
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    • 2015
  • To investigate dimensional responses of wood under dynamic temperature condition, poplar (populous euramericana Cv.) specimens, 20 mm in radial (R) and tangential (T) directions with two thicknesses of 4 and 10 mm along the grain, were exposed to cyclic temperature changes in square wave between $25^{\circ}C$ and $40^{\circ}C$ at 60% relative humidity (RH) for three different cycling periods of 6 h, 12 h and 24 h. R and T dimensional changes measured during the cycling gave the following results: 1) Transverse dimensional changes of the specimens were generally square but at an opposite phase and lagged behind the imposed temperature changes. The phase lag was inversely correlated with cycling period, but positively related to specimen thickness, while the response amplitude was directly proportional to cycling period, but in a negative correlation with specimen thickness. 2) The specimens showed swelling hysteresis behavior. The heat shrinkage coefficient (HSC) became greater as cycling period increased or specimen thickness decreased. 3) Dimensional changes of the specimens produced deformation accumulation during repeated adsorption and desorption. The deformation accumulating ratio decreased with an increase in cycling period and specimen thickness. 4) Wood suffered 1.5 times as many dimensional changes per unit temperature variation as per unit humidity variation, and this deformation behaved even more seriously under static condition.

A Study on the Production Efficiency Considering the Dimensional Change Rate of Circular Knitted Jacket (환편 니트 재킷의 치수변화율을 고려한 생산효율에 관한 연구)

  • Hwang, Song-Lee;Lee, Jin-Hee
    • Fashion & Textile Research Journal
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    • v.18 no.6
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    • pp.776-786
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    • 2016
  • This study intends to suggest production process of circular knitted jackets and dimensional change data of finished clothes after washing. the study provides pattern design method of circular knitted jackets by applying dimensional change. By doing so, the purpose of this study is to increase production efficiency through accurate order in consideration of loss amount of the fabrics in production. With the three fabric materials selected, this study investigated dimensional change of circular knitted jackets after sewing and washing by varying the parts to be attached to padding cloth and with or without inner lining. As for the fabric F-C (including the spandex, thicker and weightier than the other two fabrics), front width shrunk by 4.6%, which showed the biggest shrinkage among the jackets made of test fabrics. Then it suggested design methods of circular knitted jacket patterns to which dimensional change is applied according to materials, and analyzed the amount of fabric required for production by comparison of the materials. When using the fabric F-C without inner lining, there is big dimensional change and more than double amount of fabric is required. It is expected that the research results will be a basic data for pattern design and production process of circular knitted clothing.

Investigation of the effects of storage time on the dimensional accuracy of impression materials using cone beam computed tomography

  • Alkurt, Murat;Duymus, Zeynep Yesil;Dedeoglu, Numan
    • The Journal of Advanced Prosthodontics
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    • v.8 no.5
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    • pp.380-387
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    • 2016
  • PURPOSE. The storage conditions of impressions affect the dimensional accuracy of the impression materials. The aim of the study was to assess the effects of storage time on dimensional accuracy of five different impression materials by cone beam computed tomography (CBCT). MATERIALS AND METHODS. Polyether (Impregum), hydrocolloid (Hydrogum and Alginoplast), and silicone (Zetaflow and Honigum) impression materials were used for impressions taken from an acrylic master model. The impressions were poured and subjected to four different storage times: immediate use, and 1, 3, and 5 days of storage. Line 1 (between right and left first molar mesiobuccal cusp tips) and Line 2 (between right and left canine tips) were measured on a CBCT scanned model, and time dependent mean differences were analyzed by two-way univariate and Duncan's test (${\alpha}=.05$). RESULTS. For Line 1, the total mean difference of Impregum and Hydrogum were statistically different from Alginoplast (P<.05), while Zetaflow and Honigum had smaller discrepancies. Alginoplast resulted in more difference than the other impressions (P<.05). For Line 2, the total mean difference of Impregum was statistically different from the other impressions. Significant differences were observed in Line 1 and Line 2 for the different storage periods (P<.05). CONCLUSION. The dimensional accuracy of impression material is clinically acceptable if the impression material is stored in suitable conditions.