• Korean Journal of Soil Science and Fertilizer
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• v.10 no.1
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• pp.69-74
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• 1977

This study has been conducted to identify physico-chemical and clay mineralogical characteristics of bentonites produced in Korea for the purpose of finding good quality bentonite for agricultural ure. The results are summarized as follows: 1. Bentonites are mainly composed of montmorillonite developed from tuffs in a lava flow. 2. Chemical properties of bentonites are: pH in $H_2O$(1:1), 7:cation exchange capacity, 60-96me/100g; content of $SiO_2$, 54-72%; ratio of $SiO_2$ to $Al_2O_3$, 4.1-10.0;oven dry loss of $H_2O$ is higher than the ingnition loss of $H_2O$. 3. The x-ray diffrection patterns of powder bentonites show peaks at $14-15{\AA}$, $4.4{\AA}$, and $2.5{\AA}$, and that of swellen one show $17{\AA}$ when treated with ethylene glycol. 4. Distribution areas of the good quality bentonites were (1) Dogu-Dong, Donghae-Myeon, Yeonil-Gun, Gyeongsangbug-Do (2) Hamyeon-Ri, Yangnam-Myeon, Weolseong-Gun, Gyeongsanbug-Do. (3) Joam-Ri, Gangdong-Myeon, Weolseong-Gun, Gyeongsangbug-Do. (4) Sanha-Ri, Gangdong-Myeon, Ulju-Gun, Gyeongsangnam-Do. (5) Sinhyeon-Ri, Gangdong-Myeon, Ulju-Gun, Gyeongsangnam-Do. (6) Yonghang-Ri, Pyeongchang-Myeon, Pyeongchang-Gun, Gangweon-Do.

• The Journal of the Petrological Society of Korea
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• v.8 no.2
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• pp.92-105
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• 1999

The Cretaceous Chaeyaksan basaltic rocks consist mainly of basaltic tuffs intercalating three layers of basalt. Stratigraphically, the rocks are located between the upper Songnaedong Formation and the lower Geoncheonri Formation and contain plagioclase, augite, hornblende, and a few olivine phenocrysts. Geochemically, they show calc-alkaline characteristics in some immobile element content, but show the alkaline suite feature in the mobile major element composition. The basalts are widely spilitized but some of them is altered to shoshonitic rocks with more calcic plagioclase, calcite, and chlorite, and adularia veinlets are common in the rocks. It is supposed that the post-eruption alteration of the rocks is done through alkali-replacement by hydrothermal solution or vapor rather than by low grade regional metamorphism. It is considered that A1 in hornblende will be available for estimating the pressure of the pre-eruption magma in the reservoir although the plagioclase of the rocks are highly albitized. The crystallization pressure was calculated as 5.7Kb by the equation of Johnson and Rutherford(l989) incorporating of the effect of overestimate of .41T in hornblende in the case of quartz-free rocks. Application of the estimated temperature, pressure and the constituent of phenocrysts of the rocks to the experimental P-T phase diagram for basalts established by Green(1982) indicates the crystallization course and succession of growth of the phenocrysts during of rising and cooling of the magma reservoir; augite + augite and olivine + augite, olivine, and hornblende -+ augite and hornblende+ augite, hornblende, and plagioclase. Such evolution course of the magma may include crystal fractionation by the phenocrysts crystallization and contamination by country rock in lower crust.

• Economic and Environmental Geology
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• v.13 no.3
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• pp.167-184
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• 1980

The granitic plutons associated with Ogcheon geosynclinal zone can be grouped into three different subzones; SE-Subzone for the migmatitic and schistose granites of the southeast margin, 101-181m.y. old; NW-Subzone for those of the northwest margin, 112-163m. y. old; and C-Subzone for those of central part of the zone, 63-183m.y. old. The intrusives in C-Subzone are further subdivided into the older, adamellite to granodiorite (148-183m.y. old) and the younger, perthitic granites (63-106m,y. old). The metallogenic distribution of South Korea suggests that, in the Ogcheon Zone, it is possible to delineate an elongated polymetallogenic province in the general orientation of the zone intimately related with the migmatite and plutonic zones mentioned. Moreover, the mineralization in the province was basically controlled by the patterns of local geology involving country rocks and related igneous bodies, that permit subdivision of the province into the following three parts: Northeast (NE) Province consists dominantly of thick Paleozoic calcareous sediments; Middle (M) Province is characterized by predominant argillaceous and partly calcareous sediments of Precambrian to Late Paleozoic age; and Southwest (SW) Province consisting mainly of volcanic and arenaceous sediments of Mesozoic age. The three different plutonic zones with three different country rock provinces above mentioned make a combination which consists of nine classes. Each class can be assumed to be characterized by specific mineralization type. In order to classify the mineralization types, the present study sampled twenty six ore deposits and mineralized areas in Ogcheon zone as shown figure 2; eight ore deposits from plutonic SE-Subzone, ten from the plutonic NE-Subzone and eight from the plutonic C-Subzone. The characteristics of the classes are as follows: NE-SE is predominant in Au-Ag vein and Sn-migmatite of katazonal occurrence; NE-C is most productive in Pb-Zn and remarkable in Fe contact deposit in mesozone and partly Pb-Zn-Cu skarn in limestone and subordinate in mesozone and partly Pb-Zn pipes; M-SE is considerable in Au-Ag vein and rare elements (Nb, Ta, etc.) of pegmatite; M-C is predominant in F-veins in epizone and Mo-W, Fe, Cu veins occur in replacement type; M-NW is productive in Fe metamorphic and skarn types, partly remarkable in Cu, Pb-Zn contact; SW-SE is barren in mineralization related to Jurassic igneous rocks; SW-C is predominant in alunite and pyrophyllite in tuffs; and SW-NW is scarece in Pb-Zn, Cu, As and Au-Ag veins.

• The Journal of the Petrological Society of Korea
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• v.22 no.3
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• pp.235-249
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• 2013

The Gusandong Tuff (Kusandong Tuff), known as a very significant key bed in the Cretaceous Gyeongsang Basin, is divided into (1) Northern Gusandong Tuff (NKT), (2) Southern Gusandong Tuff (SKT), and (3) Sinsudo Tuff, which were derived from different vents. In order to suggest their more accurate eruption times and to contribute to establishing stratigraphy of the basin, SHRIMP U-Pb zircon ages were determined from the three tuffs. As a result, the virtually same ages of $103.0{\pm}1.2$ Ma and $104.1{\pm}1.3$ Ma were obtained from NKT and SKT, respectively, which mean that they simultaneously erupted during 103~104 Ma. The zircon ages obtained from the Sinsudo Tuff are however divided into two groups i.e. $103.4{\pm}2.1$ and $95.79{\pm}0.98$ Ma. Based on distinctive morphology and cathodoluminescence image of the younger zircons, the younger age, $95.79{\pm}0.98$ Ma, is much more reasonable as the eruption time of the Sinsudo Tuff.

• Economic and Environmental Geology
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• v.24 no.4
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• pp.399-408
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• 1991

There are several tuff cones and tuff rings, now only apparent on the western shoreline in Cheju Island. The observation of their landform, bedform, particle size and sorting reveals that these deposits are mainly emplaced by base surges and/or slurries originating from Surtseyan eruption which is attributed to explosive hydrovolcanism influenced by interaction of magma with external water. These are subdivided into two groups based on the plateau basalt. It is recognized that the distal limb of early tuff cones and ring at Dangsanbong, Dansan, Sanbangsan and Hwasun (lower group) are overlain by plateau basalt, on which later tuff rigns at Suwolbong and Songaksan(upper group) further extend the distal limb from each vent. The tuff cones and tuff rings are closely associated with the evidences which shelly fragments are comprised within them, and reworked tuffs, raised beach deposits, Sinyangri formation and littoral cones are deposited around them. The evidences suggest that the Surtseyan eruption resulted from direct or indirect interaction of magma with sea water.

• The Journal of the Petrological Society of Korea
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• v.14 no.4 s.42
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• pp.195-211
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• 2005

The Kusandong Tuff, known as a representative key bed in the Cretaceous Gyeongsang Basin, is a crystal-rich tuff of pyroclastic flow and surge origin. It is 1-4 m thick and laterally extends for more than 200 km intercalated in the upper part of the Hayang Croup. Observations and analyses of the feldspar crystals in the tuff, using polarizing microscopes, EPMA, and BSE images, reveal that the plagioclase crystals in the tuff were completely albitized (>$97\%$ Ab) whereas those in the southernmost localities where the tuff is rich in fine ash matrix are unaltered or partly albitized. K-feldspars are partly albitized at all localities, irrespective of the matrix content of the tuff, Perthitic textures, chessboard twinning, albitization along micro-fractures and cleavages, and the relationship between matrix content and the degree of albitization suggest that feldspars in the Kusandong Tuff were albitized by Na-rich fluid after burial. Albitization is interpreted to start preferentially along micro-fractures and cleavages and be hampered in matrix-rich tuffs with a low permeability. Original composition of the plagioclases in the Kusandong Tuff is also interpreted to have ranged between oligoclase and andesine ($Ab_{62.5}-Ab_{83.3}$) before the albitization.

• The Journal of the Petrological Society of Korea
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• v.12 no.1
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• pp.1-15
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• 2003

The Paekrogdam summit crater area, Mt. Halla, Jeju Island, Korea, composed of Paekrogdam trachyte, Paekrogdam trachybasalt, and Manseidongsan conglomerate in ascending order. Joint systems show concentric and radial patterns around the summit crate wall. The Paekrogdam crater is a summit crater lake which erupted the tuffs, scorias and lava flows of Paekrogdam trachybasalt after the emplaceent of Paekrogdam trachyte dome. SiO$_2$ contents of mafic and felsic lavas are respectively, 48.0∼53.7 wt.％ and 60.7∼67.4 wt.%, reflecting bimodal volcanism. And lavas with SiO$_2$ between 53.7 wt.% and 60.7 wt.％ are not found. According to TAS diagram and K$_2$O-Na$_2$O diagram, the volcanic rocks belong to the normal alkaline rock series of alkali basalt-trachybasalt-basaltic trachyandesite and trachyte association. Oxide vs. MgO diagrams represent that the mafic lavas fractionated with crystallization of olivine, clinopyroxene, magnetite and ilmenite and felsic trachyte of plagioclase and apatite. The characteristics of trace elements and REEs shows that primary magma for the trachybasalt magma would have been derived from partial melting of garnet peridotite mantle. In the discrimination diagrams, the volcanic rocks are plotted at the region of within plate basalt (WPB).

• Journal of the Mineralogical Society of Korea
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• v.2 no.2
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• pp.81-89
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• 1989

Alunite occurs as massive, cavity-filling and veinlets in the Cretaceous Hwangsan Formation in the Sungsan mine, Korea. It is a hydrothermal alteration product of rhyolitic tuffs, and associated with dickite, quartz and barite. The average chemical formula of alunite in the mine is $(K_{0.93}Na_{0.07})_{1.00}Al_{3.00}(SO_4)_{2.00}(OH)_6$. Atomic percentage of Na substituting for K in A site of the alunite structure varies from 5.9 to 9.2. Unit-cell volume and c dimension decrease with increasing Na atomic percentage. On the basis of thermal and high temperature XRD analyses, the decomposition of alunite into $KAl(SO_4)_2$ and $NaAl(SO_4)_2$ concomitant with the liberation of structural water (12.86%) occurs at about $550^{\circ}C$. The reconstruction of $KAl(SO_4)_2$ and $NaAl(SO_4)_2$ to $Al_2(SO_4)_3$, arcanite and thenardite, and the crystallization of ${\gamma}-Al_2O_3$ take place at about $720^{\circ}C$. The destruction of $Al_2(SO_4)_3$ structure takes place at about $760^{\circ}C$ removing 3/4 of total $SO_3$ (27.32%).

• Journal of the Korean Geotechnical Society
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• v.21 no.5
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• pp.83-92
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• 2005

The aim of this study was to investigate damage conditions of cut slope structures due to acid rock drainage (ARB) and to assess the acid production potential of various rocks. Acid rock drainage is produced by the oxidation of sulfide minerals contained in coal mine zone and mineralization belt of Pyeongan supergroup and Ogcheon group, pyrite-bearing andesite, and Tertiary acid sulfate soils in Korea. Most of cut slopes producing ARB have been treated with shotcrete to reduce ARD. According to the field observations, ARD had an adverse effect on slope structures. The corrosion of shotcrete, anchors and rock bolts and the bad germination and growth diseases of covering plants due to ARD were observed in the field. The concentration of heavy metals and pH of ARD from cut slope exceeded the environmental standard, indicating a high potential of environmental pollution of surrounding soil, surface water and ground water by the ARD. According to acid base accounting (ABA) of the studied samples, hydrothermally altered volcanic rocks, tuffs, coaly shales, tailings of metallic mine had a relatively high potential of acid production but gneiss and granite had no or less acid production potential. It is expected that the number of cut slopes will increase hereafter considering the present construction trend. In order to reduce the adverse effect of ARD in construction sites, we need to secure the data base for potential ARD producing area and to develop the ARD reduction technologies suitable.

• Economic and Environmental Geology
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• v.25 no.2
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• pp.179-190
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• 1992

The Yeongchun area is located at the central part of the Danyang Coalfield, where Precambrian granitoids, Cambro-Ordovician Choseon Supergroup, Carboniferous-early Triassic Pyeongan Supergroup, middle Triassic-Jurassic Bansong Group and extrusive tuffs are exposed. The rocks in the area underwent four phases of deformation, which are (a) $D_1$ : Movement of the Okdong Fault, (b) $D_2$ : Formation of NW-SE trending folds and stretching lineations, (c) $D_3$: Movement of the Gagdong Thrust Fault and associated structures of NNE-SSW trending folds, and (d) $D_4$ : E-W trending strike-slip faults and folds. During the $D_3$-event, flexural slip deformation intensively affected rocks in the area. Strain measurements show relatively low strain intensity in the area. The types of strain ellipsoid are prolate in the hangingwall area and those near to the footwall area range from plane strain to weak oblate. The oblate type is developed in the region far from the footwall area.