A study on the destruction of organic cation and anion exchange resins by electro-generated Ag(II) as a mediator was carried out to develop the ambient-temperature aqueous process, known as Ag(II)-mediated electro-chemical oxidation (MEO) process, for the treatment of a large quantity of spent organic ion exchange resins as the low and Intermediated-level radioactive wastes arising from the operation, maintenance and repairs of nuclear facilities. The effects of controllable process parameters such as applied current density, temperature, and nitric acid concentration on the MEO of organic ion exchange resins were investigated. The cation exchange resin was completely decomposed to $CO_2$. The current efficiency increased with a decrease in applied current density while nitric acid concentration and temperature on the MEO of cation exchange resin did not affect the MEO. On the other hand, anion exchange resins were decomposed to CO and $CO_2$. The ultimate conversion to CO was about $10\%$ regardless of temperature. The destruction efficiencies to $CO_2$ were dependent upon temperature and the effective destruction of anion exchange resin could be obtained above $60^{\circ}C$.
Journal of Korean Society for Atmospheric Environment
/
v.24
no.1
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pp.72-82
/
2008
Benzene is a very harmful and toxic compound known as human carcinogen by all routes of exposure. Owing to the risky feature of benzene, several countries such as Japan, UK and EU have established the ambient air quality standard and protect from that risk of it. Korea also has designated it as one of the criteria air pollutants and established the concentration limit ($5\;{\mu}g/m^3$) in the air and is going to apply the standard from 2010. Benzene is emitted from various sources such as combustion plants, production processes, waste treatment facilities and also automobiles. Mobile source is known as one of the major emission sources of benzene. In this study, we estimated the domestic emissions of benzene from mobile source and compared the results with those of advanced countries. Mobile source was divided into 2 categories, Le., on-road source and non-road source. The total emissions of benzene from mobile source were estimated as 3,106 tons/yr and 1,612 tons/yr was emitted from on-road source and 1,494 tons/yr was from non-road source. Emission ratio of benzene from on-road source showed that 80.0% was from passenger cars, 10.1% was from taxis, 7.2% was from light-duty vehicles, 2.5% was from heavy-duty vehicles and 0.2% was from buses. In the case of non-road source, the distribution showed that 66.3% was from construction machineries, 14.5% was from locomotives, 11.7% was from ships, 7.1% was from agriculture equipments and 0.5% was from aircrafts. The cold-start emissions were estimated as 942 tons/yr and this value was almost 1.5 times greater than that for hot engine emissions (608 tons/yr). In addition, the fuel-based distribution was 65.9%, 31.1% and 2.8% from gasoline, LPG and diesel vehicles, respectively. The emission ratio from mobile source occupied 65% and 30% of total benzene emissions in USA and UK, respectively. In case of Korea, the emission ratio of benzene from mobile source occupied 29% (15% from on-road source, 14% from non-road source) which showed similar value with UK.
Journal of the Korean Institute of Landscape Architecture
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v.43
no.1
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pp.96-107
/
2015
Brownfield sites are beginning to be considered as potentially useful areas for landscape design and planning, with post-industrial areas such as water treatment facilities and military training bases being converted into useful landscapes such as parks and recreation areas. These redevelopments bring broad benefits through revitalizing communities and increasing property values, thus, increasing the demand for comprehensive management and planning policies. This study examines changes in U.S. brownfield policies and programs and, identifies their periodic characteristics over the thirty years since the Superfund program was introduced in 1980. A descriptive and interpretive approach was utilized, focusing specifically on a time sequential analysis of the data gathered from the overview of the Environmental Protection Agency's web-based documents and related literature. The primary changes in and characteristics of programs and policies were analyzed and divided into three periods : environmental protection, remediation and reuse, and comprehensive planning. Four major features were identified: relaxation and readjustment of regulation, diversification of support programs, a mix of top-down and bottom-up approaches, and database system building. The study examines how common brownfield problems such as site identification difficulties and assessment and remediation cost have been dealt with in the regulatory context and has implications for future policies and programs for effective brownfield planning and management in Korea.
Journal of the Korean Recycled Construction Resources Institute
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v.8
no.2
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pp.227-234
/
2020
Under consideration of construction waste recycling, candidate secondary products applicable for the civil and construction areas can be reliably employed based on the recycling cost analysis. For the validation purpose, probability-based cost analyses were performed to estimate recycling cost profit considering uncertainties. When recycling construction wastes, the costs at each stage are fully dependent on target products to be adopted. To achieve commercialization of each product, its quality has to be improved with economic efficiency through accurate evaluation of input costs. Based on the probabilistic recycling cost analysis, the cost benefit for target products was estimated with waste classification cost, transportation cost to recycling treatment facilities and production cost. All necessary information on the cost analysis were collected from literature, disclosure, and existing recycling companies. In addition, a cost difference between recycled and non-recycled events was made. As a result, a probability-based recycling cost estimate for candidate secondary products was herein presented.
Park, Jin Young;Jang, Eugene;Kim, Hak Joon;Ihm, Myeong Hyeok
The Journal of Engineering Geology
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v.27
no.2
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pp.153-164
/
2017
The geological factors for causing ground subsidence are very diverse. It can be affected by any geological or extrinsic influences, and even within the same geological factor, the soil depression impact factor can be determined by different physical properties. As a result of reviewing a large number of papers and case histories, it can be seen that there are seven categories of ground subsidence factors. The depth and thickness of the overburden can affect the subsidence depending on the existence of the cavity, whereas the depth and orientation of the boundary between soil and rock are dominant factors in the ground composed of soil and rock. In case of soil layers, more various influencing factors exist such as type of soil, shear strength, relative density and degree of compaction, dry unit weight, water content, and liquid limit. The type of rock, distance from the main fracture and RQD can be influential factors in the bedrock. When approaching from the hydrogeological point of view, the rainfall intensity, the distance and the depth from the main channel, the coefficient of permeability and fluctuation of ground water level can influence to ground subsidence. It is also possible that the ground subsidence can be affected by external factors such as the depth of excavation and distance from the earth retaining wall, groundwater treatment methods at excavation work, and existence of artificial facilities such as sewer pipes. It is estimated that to evaluate the ground subsidence factor during the construction of underground structures in urban areas will be essential. It is expected that ground subsidence factors examined in this study will contribute for the reliable evaluation of the ground subsidence risk.
Journal of Korean Society of Environmental Engineers
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v.34
no.1
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pp.1-6
/
2012
Down Stream K River has high COD (4-10 mg/L) and high $NH_3$-N concentration (3.5 mg/L during winter period). Although $NH_3$-N itself is not reported harmful at this level, it must be removed to meet drinking water standard (0.5 mg/L). We constructed a pilot plant modifying the processes of conventional drinking water facilities. Prechlorination and powdered activated carbon (PAC) dechlorination was adopted prior to a flocculation tank to remove ammonia and prevent disinfection byproducts (DBPs) formation. Also, GAC processes was included after sand filter to remove residual DOC. This pilot having a capacity of 36 ton/day was operated for one year. The GAC processes were successful to remove ammonia and many organic pollutants (DOC, MBAS, UV-254 nm absorbance, etc). Influent DOC concentrations were very high as 3~6 mg/L throughout the plant operation. It was impossible to achieve 1.0 mg/L effluent DOC, indicating that bed depth (2 m) should be increased to achieve more strict DOC quality standards. When $Cl_2$ dose was well controlled ($Cl_2/NH_3$-N ratio 10~11 on a weight basis), $NH_3$-N removal was 98% and THMs was very low possibly due to low free residual chlorine and PAC dechlorination.
Journal of Korean Society of Environmental Engineers
/
v.38
no.6
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pp.323-328
/
2016
Pressurized membrane used for side-stream MBR process requires fouling control strategy both for normal and abnormal operation conditions for stable operation of the facilities. In this study, $85m^3/day$ of pilot-scale side-stream MBR process was constructed for the evaluation of fouling mitigation by air bubble injection into the membrane module. In addition, fouling phenomena at abnormal operation conditions of low influent and/or loading rate were also investigated. Injection of air bubble was found to be effective in delaying transmembrane pressure (TMP) increase mainly due to scouring effect on the membrane surface, resulting in expanded filtration cycle at a high flux of $40L/m^2{\cdot}h$ (LMH). At abnormal operation condition, injection of PACl (53 mg/L as Al) into the bioreactor showed 19% reduction of TMP increase. However, inhibition of nitrifying bacteria by continuous PACl injection was observed from batch experiments. In contrast, injection of powdered activated carbon (PAC, 0.6 g/L) was able to maintain the initial TMP of $0.2kg/cm^2$ for 5 days at the abnormal conditions. It may have been caused from the adsorption of extracellular polymeric substances (EPS), which was known to be excessively released during growth inhibition condition and act as the major foulants in MBR operations.
This study was conducted to improve the Nonpoint-source pollutant treatment plant efficiency and maintenance. Field and laboratory permeability test were conducted three times each before and after displacement. The removal efficiency such as TSS, BOD, CODmn, T-N, and T-P were investigated from the year of 2006 to 2011. The coefficient of permeability right after displacement was calculated to be $1.07{\times}10^{-3}(cm/s)$, coefficient of permeability after a year was calculated to be $0.88{\times}10^{-3}(cm/s)$, and after five years, it was calculated to be $0.3{\times}10^{-3}(cm/s)$ and accordingly, the amount of infiltration decreased. In case of the removal efficiency, it generally tended to decrease, but it showed the higher rates than the expected rates BOD 40%, SS 76%, T-N 39% and T-P 53%. It is concluded that displacement cycle should be at least five years and that dredging cycle should be at least three months and at most one year.
Journal of the Korea Academia-Industrial cooperation Society
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v.12
no.4
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pp.1628-1636
/
2011
The purpose of this study is to analyze the effectiveness of horticultural therapy on children from broken homes: this treatment program, implemented in the social welfare field, targets the children's depression, self-esteem, and social and emotional stress. Its object was composed of 13 lower grade students enrolled in special facilities according to the life-cycle method, and its data were collected as making use of the structured questionnaire. The horticultural Therapy Program was practiced 14 sessions in total from September 2nd to December 16th, 2010, and its results in summary are as follows; The sociality in horticultural therapy was higher by .53 point in 2.76 after practice than in 2.23 before practice, and its value of the ability to cope with stress was higher by 0.52 point in 2.82 after coping with stress than in 2.30 before that. That was meaningful (t=-1.4398, p<.05). The value of anxiety was lower by .15 in 1.45 post-anxiety than in 1.60 pre-anxiety, and that was meaningful (t=-2.3842, p<.05). The value of self-esteem is higher by .42 in 2.92 post-self-esteem than in 2.50 pre-self-esteem, and that was strategically meaningful (t=-1.1871, p<.05). The value of emotional assessment was higher by 2.05 in 5.25 post-emotional assessment than in 3.20 pre-emotional assessment, and that was strategically meaningful (t=-2.4599, p<.05). Based on these results, this study suggests that this horticultural therapy program should apply to the issues of children in social welfare field as one of various approaches.
Domestic railway industry has grown in numbers, scale of railway ndustrial and operation because was focused on an environmentally sustainable transportation. However, it is not enough to treat and prevent heavy metals which occur as the railway operation increases. The heavy metals occurred when the operating railway and it will be flow into water system with rainfall effluent during rainfall. will flow out along with the rainfall effluent when rainfall comes. In case of a railway bridge, In particular, heavy metals were flow into the water system without any treatment from railway bridges where located nearby rivers and lakes. So, rainfall effluent from railway facilities was occurred pollution of water system. For the prevent of heavy metal runoff during rainfall, the adsorptivity of material in railway roadbed is important.In this study, adsorptivity of gravel which is main gravel and blast-furnace slag were conducted adsorption test and deducted Freundlich's and Langmuir's isothermal adsorption equations. Safety as railway subbase course material was evaluated using modeling. As a result, absorption amount of slag, Cd and Cu, was shown higher than gravel and Pb along with Zn showed higher absorption amount of gravel. However, absorption amount of slag was shown higher than gravel used as railway subbase course material as time passes by. Absorption features had more suitable determination coefficient of heavy metals in warm absorption type such as Langnmuir compared to warm absorption type like Freundlich. To add, they showed less transformation by about 10% compared to gravel in safety evaluation through modeling. This is a railway subbase course material that prevents water outflow of heavy metal thus we can know slag is needed to be used.
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