• Elastomers and Composites
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• v.27 no.4
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• pp.255-261
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• 1992

Chlorosulfonated polyethylene(CSM) was moisture-cure after treating them with silane coupling agents such as ${\gamma}-mercapto$ propyl trimethoxy silane, ${\gamma}-glycidoxy$ propyl triethoxy silane and methyl triethoxy silane, 3-(trimethoxy silyl) propyl methacrylate and 3-thiocyanopropyl triethoxy silane. The cure reaction is composed two steps. The first is the reaction between chlorosulfonyl groups of CSM and silane coupling agents. The second is the formation of cross-links which are siloxane linkage. The linkage is formed by the condensation of silanol groups which are produced by the hydrolysis of alkoxysilyl groups. CSM was mixed with MPS etc., and dilaurate dilaurate as catalyst on two open mill and the compounds were lured in hot water at $70^{\circ}C$ Physical properties of moisture-cured CSM was measured. CSM was effectively moisture-cured and r-mercapto propyl trimethoxy silane and r-glycidoxy propyl trimethoxy silane were capable of the vulcanizing agents.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.61 no.10
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• pp.1454-1460
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• 2012

In order to develop an new electric insulation material for heavy electric equipments, epoxy/micro/nano composite (EMNC) was prepared by mixing micro-silica with nano layered silicate, where the nano layered silicate was synthesized by our electric field dispersion method, EMNSC was prepared by treating the EMNC with a silane coupling agent. Thermal properties such as glass transition temperature (Tg) and thermal expansion coefficient, and DMA characteristics were studied, and mechanicla properties such as tensile and flexural tests were performed. AC electrical insulation strength was also tested. All properties of EMNSC were modified by treating EMNC with silane coupling agent and it was confirmed that our new developed composites could be used in the heavy electric equipments.

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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• 2003.05a
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• pp.813-816
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• 2003

The dielectric breakdown of epoxy composites used for transformers was experimented and then its data were applied to Weibull distribution probability. First of all, speaking of dielectric breakdown properties, the more hardener increased, the stronger breakdown strength became at low temperature because of cross-linked density by the virtue of ester radical. The breakdown strength of specimens with filler was lower than it of non-filler specimens because it is believed that the adding filler forms interface and charge is accumulated in it, therefore the molecular motility is raised and the electric field is concentrated. In the case of filled specimens with treating silane, the breakdown strength become much higher. Finally, according to Weibull distribution analysis, reducing breakdown probability of equipment insulation lower than 0.1 % level requires the allowable field intensity values to be kept under 21.5 MV/cm.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2001.07a
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• pp.92-95
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• 2001

The dielectric breakdown of epoxy composites used for transformers was experimented and then its data were simulated by Weibull distribution probability. First of all, speaking of dielectric breakdown properties, the more hardener increased the stronger breakdown strength at low temperature because of cross-linked density by the virtue of ester radical. The breakdown strength of specimens with filler was lower than it of non-filler specimens because it is believed that the adding filler forms interface and charge is accumulated in it, therefore the molecular motility is raised and the electric field is concentrated. In the case of filled specimens with treating silane, the breakdown strength become much higher Finally, from the analysis of weibull distribution, it was confirmed that as the allowed breakdown probability was given by 0.1[%], the applied field value needed to be under 21.5 [Mv/cm].

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2002.07a
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• pp.414-419
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• 2002

The dielectric breakdown of epoxy composites used for transformers was experimented and then its data were simulated by Weibull distribution probability. First of all, speaking of dielectric breakdown properties, the more hardener increased the stronger breakdown strength at low temperature because of cross-linked density by the virtue of ester radical. The breakdown strength of specimens with filler was lower than it of non-filler specimens because it is believed that the adding filler forms interface and charge is accumulated in it, therefore the molecular motility is raised and the electric field is concentrated. In the case of (idled specimens with treating silane, the breakdown strength become much higher Finally, from the analysis of weibull distribution, it was confirmed that as the allowed breakdown probability was given by 0.1[%], the applied field value needed to be under 21.5 MV/cm.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2003.07b
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• pp.1200-1203
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• 2003

The dielectric breakdown of epoxy composites used for transformers was experimented and then its data were applied to Weibull distribution probability. First of all, speaking of dielectric breakdown properties, the more hardener increased, the stronger breakdown strength became at low temperature because of cross-linked density by the virtue of ester radical. The breakdown strength of specimens with filler was lower than it of non-filler specimens because it is believed that the adding filler forms interface and charge is accumulated in it, therefore the molecular motility is raised and the electric field is concentrated. In the case of filled specimens with treating silane, the breakdown strength become much higher. Finally, according to Weibull distribution analysis, reducing breakdown probability of equipment insulation lower than 0.1% level requires the allowable field allowable field intensity values to be kept under 21.5 MV/cm.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2002.05c
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• pp.212-217
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• 2002

The dielectric breakdown of epoxy composites used for transformers was experimented and then its data were simulated by Weibull distribution probability. First of all, speaking of dielectric breakdown properties, the more hardener increased the stronger breakdown strength at low temperature because of cross-linked density by the virtue of ester radical. The breakdown strength of specimens with filler was lower than it of non-filler specimens because it is believed that the adding filler forms interface and charge is accumulated in it, therefore the molecular motility is raised and the electric field is concentrated. In the case of filled specimens with treating silane, the breakdown strength become much higher Finally, from the analysis of weibull distribution, it was confirmed that as the allowed breakdown probability was given by 0.1[%], the applied field value needed to be under 21.5 MV/cm.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.14 no.8
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• pp.647-651
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• 2001

The dielectric breakdown of epoxy composites used for transformers was experimented and then its data were applied to Weibull distribution probability. First of all, speaking of dielectric breakdown properties, the more hardener increased, the stronger breakdown strength became at low temperature because of cross-linked density by the virtue of ester radical. The breakdown strength of specimens with filler was lower than it of non-filler specimens because it is believed that the adding filler forms interface and charge is accumulated in it, therefore the molecular motility is raised and the electric filed is concentrated. In the case of filled specimens with treating silane, the breakdown strength become much higher. Finally, from the analysis of weibull distribution, it was confirmed that to low allowed breakdown probability under 0,.1%, the applied field value needed to be under 21.5MV/cm.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.62 no.2
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• pp.213-218
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• 2013

In this study, epoxy/mica composite was prepared by mixing with mechanical stirrer together with homogenizer, and the effect of amino-type silane coupling agent was also studied. To reduce the viscosity without any decrement of other properties, 1,4-Butanediol diglycidyl ether (1,4-BDGE) as an aliphatic epoxy reactive diluent was introduced to the epoxy/mica composite in order to use as vanish for high voltage motor and generator stator winding. It was confirmed by scanning electron microscopy (SEM) observation that interfacial characteristics between organic epoxy and inorganic mica was modified by coupling agent treatment so that glass transition temperature increased, and tensile strength and electrical breakdown strength increased. The properties were estimated by Weibull statistical analysis and the ac electrical breakdown strength was 20.2% modified by treating silane coupling agent.

• Elastomers and Composites
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• v.26 no.2
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• pp.115-122
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• 1991

Polychloroprene rubber was moisture-cured after treating them with silane coupling agents such as 3-mercaptopropyltrimethoxysilane(MPS), 3-methacryloxypropyltrimethoxysilane(MAS) and vinyltriethoxysilane(VES), especially MPS. The cure reaction is composed of two steps. The first is the reaction between chlorine atoms of CR and silane coupling agents. The second is the formation of cross-links which are siloxane linkage. The linkage is formed by the condensation of silanol groups which are produced by the hydrolysis of alkoxysilyl groups. The first reaction was kinetically studied and the reactivity of CR to silane coupling agents was determined in previous literature. Crosslinking density and mechanical properties of the moisture-cured elastomer filled with silica or non-filled were studied and the feasibility of this cure system was discussed.