• Nuclear Engineering and Technology
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• 제34권3호
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• pp.218-231
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• 2002

Using a three-dimensional numerical code, B3R developed for nuclide transport of an arbitrary length of decay chain in the buffer between the canister and adjacent rock in a high- level radioactive waste repository by adopting a finite difference method utilizing the control- volume scheme, some illustrative calculations have been done. A linear sorption isotherm, nuclide transport due to diffusion in the buffer and the rock matrix, and advection and dispersion along thin rigid parallel fractures existing in a saturated porous rock matrix as well as diffusion through the fracture wall into the matrix is assumed. In such kind of repository, buffer and rock matrix are known to be important physico-chemical harriers in nuclide retardation. To show effects of buffer and rock matrix on nuclide transport in HLW repository and also to demonstrate usefulness of B3R, several cases of breakthrough curves as well as three- dimensional plots of concentration isopleths associated with these two barriers are introduced for a typical case of decay chain of $^{234}$ Ulongrightarrow$^{230}$ Thlongrightarrow$^{226}$ Ra, which is the most important chain as far as the human environment is concerned.

• Nuclear Engineering and Technology
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• 제52권2호
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• pp.223-229
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• 2020

The present work proposes a solution to the static Boltzmann transport equation approximated by the simplified P₃ (SP₃) on angular, and the analytic coarse mesh finite difference (ACMFD) for spatial variables. Multi-group SP₃-ACMFD equations in 3D rectangular geometry are solved using the GMRES solution technique. As the core time dependent analysis necessitates the solution of an eigenvalue problem for an initial condition, this work is hence devoted to development and verification of the proposed static SP₃-ACMFD solver. A 3D multi-group static diffusion solver is also developed as a byproduct of this work to assess the improvement achieved using the SP₃ technique. Static results are then compared against transport benchmarks to assess the proximity of SP₃-ACMFD solutions to their full transport peers. Results prove that the approach can be considered as an acceptable interim approximation with outputs superior to the diffusion method, close to the transport results, and with the computational costs less than the full transport approach. The work would be further generalized to time dependent solutions in Part II.

• Journal of Pharmaceutical Investigation
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• 제28권1호
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• pp.25-33
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• 1998

Intestinal absorption of ${\beta}-lactam$ antibiotics and angiotensin converting enzyme(ACE) inhibitors has been shown to use the carrier-mediated transport system. In vitro experiments have established that the efficacy of uptake by enterocytes depends on an inwardly directed proton gradient. It was suggested that benazepril was mediated by tripeptide transport system and that amoxicillin was transported by dipeptide transport carrier. The aim of this study is to assess the influence of amoxicillin on the intestinal absorption of benazepril using in vitro diffusion chamber and in situ single pass perfusion technique in the rat in order to elucidate whether the above transport systems are competitive or not. We obtained the gastrointestinal pemeability coefficient of amoxicillin, benazepril and both of them using in vitro diffusion chamber. And also the gastrointestinal absorption clearance of amoxicillin, benazepril and both of them using in situ single-pass perfusion method at steady state were calculated. Amoxicillin and benazepril were analyzed by HPLC. The results by the use of diffusion chamber in vitro indicated that the apparent intestinal permeability coefficient of benazepril was significantly(p<0.01) decreased by amoxicillin(45.2%) and vice versa significantly(p<0.01) decreased(89.1%). The results by the in situ gastrointestinal single-pass perfusion method indicated that the intestinal absorption clearance of benazepril was significantly(p<0.05) decreased by amoxicillin (40.2%) and vice versa significantly(p<0.05) decreased(54.8%). These results might suggest that they share the same peptide carrier pathway for oral absorption.

• Nuclear Engineering and Technology
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• 제26권2호
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• pp.285-293
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• 1994

압축 벤토나이트에서 핵종이동은 확산에 의해 지배된다. 국산 벤토나이트에 대한 음이온핵종의 확산 특성 규명을 위해서 요오드이온을 대상으로 관통확산실험을 수행하였다. 대상매질은 동해안 지역의 벤토나이트를 사용하였으며, 실험용액은 합성 모의지하수에 I-125를 첨가하여 사용하였다. 압축 벤토나이트의 충전밀도는 1.2, 1.4, 1.7Mg/㎥등 세가지로 하였다. 요오드이온의 겉보기확산계수와 유효확산계수는 충전밀도가 증가함에 따라 감소하였고, 이들 확산계수의 값은 각자 3.80-7.12$\times$$10^{-11}$ $m^2$/s와 1.25-7.97$\times$$10^{-12}$ $m^2$/s의 범위에 있었다. 실험결과, 겉보기확산계수는 벤토나이트의 공극구조에 의존하였으며, 유효확산계수는 공극구조는 물론 핵종확산이동에 이용된 유효공극율에 의해 좌우되었다. 본 연구에서 얻어진 결과는 처분장안전성평가의 기초자료로 활용될 것이다.

• 멤브레인
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• 제14권1호
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• pp.75-84
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• 2004

폴리아미드계 역삼투 분리막의 투과성능을 비교하기 위하여 NaCl과 NaOCl을 함유하는 혼합용액을 공급수로 사용하여 연속운전과 단속운전 하에서 실험하여 보았다. 이 결과를 가지고 막 이동 모델의 선택적 적용이 가능함을 제시하고자 하였으며 투과 성능 분석 결과, 용액 확산 모델과 선흡착-모세관이동 모델이 운전 모드에 따라 상대적으로 유용함을 볼수 있었다. 연속 운전에서는 선흡착-모세관이동 모델을, 단속 운전에서는 용액 확산 모델을 따름을 알 수 있었다 NaOCl에 의한 표면 변화를 SEM 사진을 통하여 확인 할 수 있었다. 연속운전 후의 막은 염소 투과 결과 표면에서 부분적인 ridge and valley 구조가 나타났으며 단속 운전 후의 막은 표면 전반에서 변성이 일어난 것을 볼 수 있었다.

• 제어로봇시스템학회:학술대회논문집
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• 제어로봇시스템학회 1994년도 Proceedings of the Korea Automatic Control Conference, 9th (KACC) ; Taejeon, Korea; 17-20 Oct. 1994
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• pp.747-752
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• 1994

Ussing's flux ratio theorem (1978) reflects a reciprocal relationship behavior between the unidirectional fluxes in asymmetric steady diffusion-convection in a membrane slab. This surprising result has led to many subsequent studies in a wide range of applications, in particular involving linear models of time dependent problems in biology and physiology. Ussing's theorem and its extensions are inherently linear in character. It is of considerable interest to ask to what extent these results apply, if at all, in situations involving, for example, nonlinear reaction. A physiologically interesting situation has been considered by Weisiger et at. (1989, 1991, 1992) and by McNabb et al. (1990, 1991) who studied the role of albumin in the transport of ligands across aqueous diffusion barriers in a liver membrane slab. The results are that there exist reciprocal relationships between unidirectional fluxes in the steady state, although albumin is chemically interacting in a nonlinear way of the diffusion processes. However, the results do not hold in general at early times. Since this type of study first started, it has been speculated about when and how the Ussing's flux ratio theorem fails in a general diffusion-convection-reaction system. In this paper we discuss the validity of Ussing-type theorems in time-dependent situations, and consider the limiting time behavior of a general nonlinear diffusion system with interaction.

• 대기
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• 제14권4호
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• pp.3-18
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• 2004

Neglecting the vertical transport from the surface, most of the previous studies on the long-range transport of pollutants have only considered the horizontal transport caused by the free atmosphere wind. I used a three dimensional numerical model, MM5 (The fifth generation Penn State Univ./NCAR Mesoscale Model) for the simulation of vertical transport of pollutants and investigated the mechanism of the vertical transport of atmospheric pollutants between planetary boundary layer(PBL) and free atmosphere by fronts. From the three dimensional simulation of MM5, the amount of pollutants transport from PBL to free atmosphere is 48% within 18 hour after the development of front, 55% within 24 hour, and 53% within 30 hour. The ratios of the vertically transported pollutant for different seasons are 62%, 60%, 54%, and 43% for spring, summer, fall, and winter, respectively. The most active areas for the vertical transport are the center of low pressure and the warm sector located east side of cold front, in which the strong upward motion slanted northward occurs. The horizontal advection of pollutants at the upper level is stronger than at the lower level simply because of the stronger wind speed. The simulation results shows the well known plum shape distribution of pollutants. The high concentration area is located in the center and north of the low pressure system, while the second highest concentration area is in the warm sector. It is shown that the most important mechanism for the vertical transport is vertical advection, while the vertical diffusion process plays an important role in the redistribution of pollutants in the PBL.

• 한국결정성장학회지
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• 제31권3호
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• pp.127-136
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• 2021

This paper is dedicated to numerical simulation for diffusion-advective convection in a square cavity during physical vapor transport of Hg₂Br₂. Flow characteristics of the temperature difference between the source and crystal regions, 50℃ (300℃ → 250℃), partial pressures of component argon of 20 Torr and 100 Torr are investigated and presented as velocity vectors and streamlines, isotherms and iso-mass concentrations contours. Moreover, alterations of average Nusselt and average Sherwood numbers with (a) the source and crystal regions, (b) the pressures of component argon of 20 Torr and 100 Torr are analyzed and addressed in details. Both average Nusselt and average Sherwood numbers are seen to decrease with the increasing values of the partial pressures of component argon. Also, it is found that for the two different partial pressures of component argon, average Nusselt numbers at the source region are greater than at the crystal region, and inversely, average Sherwood numbers at the crystal region are greater than the source region by a factor of 3.

• Corrosion Science and Technology
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• 제16권4호
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• pp.209-225
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• 2017

Development of high strength steel requires proper understanding of hydrogen behavior since the higher the steel strength the greater the susceptibility of hydrogen assisted cracking. This paper provides a brief but broad overview on hydrogen entry and transport behavior of high-strength ferritic steels. First of all, hydrogen absorption, diffusion and trapping mechanism of the steels are briefly introduced. Secondly, several experimental methods for analyzing the physical/chemical nature of hydrogen uptake and transport in the steels are reviewed. Among the methods, electrochemical permeation technique utilized widely for evaluating the hydrogen diffusion and trapping behavior in metals and alloys is mainly discussed. Moreover, a modified permeation technique accommodating the externally applied load and its application to a variety of steels are intensively explored. Indeed, successful utilization of the modified permeation technique equipped with a constant load testing device leads to significant academic progress on the hydrogen assisted cracking (HAC) phenomenon of the steels. In order to show how the external and/or residual stress affects mechanical instability of steel due to hydrogen ingress, the relationship among the microstructure, hydrogen permeation, and HAC susceptibility is briefly introduced.

• 분석과학
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• 제8권4호
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• pp.663-668
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• 1995

Ion transport of a polypyrrole/chloride (PPy/Cl) film and a polypyrrole/poly(styenesulfonate) (PPy/PSS) film as a function of applied dc potential was investigated by employing electrogravimetric impedance technique and electrochemical impedance technique. The cation and anion contribution to the whole charge capacitance and the diffusion coefficients of cation and anion in a PPy/PSS film were calculated by fitting the electrogravimetric impedance data with proposed model circuit. The diffusion coefficients of $Na^+$ in a 1 M $NaClO_4$ solution are over 1 order of magnitude larger than those of $ClO{_4}^-$, and $ClO{_4}^-$ contribution to charge compensation decreases as dc potential lowers. The charge compensation of a PPy/Cl film ir a 1 M CsCl solution is carried out largely by $Cl^-$ at 0.2 V vs. Ag/AgCl and by $Cs^+$ as well as $Cl^-$ at -0.4 V.