• Transactions of the Korean Society of Automotive Engineers
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• v.13 no.1
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• pp.68-75
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• 2005

By utilizing a semi-empirical soot model, the applicability of the laminar flamelet concept fur simulating the formation and oxidation of soot in the laminar diffusion flame has been studied. The source terms for two transport equations of the soot formation and oxidation are calculated in the mixture fraction/scalar dissipation rate space for laminar flamelets and stored in a library. In this study, emphasis is given to the interaction associated with radiation and soot formation. The radiative heat loss is obtained by solving the radiative transfer equation using the unstructured grid finite volume method with the WSGGM. The calculated temperatures and soot volume fractions agree relatively well with the experimental data and the previous numerical results of Kaplan et al. using the detailed chemistry.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.4 no.3
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• pp.210-222
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• 1994

The characteristics of flows, temperatures, and concentrations of oxygen are numerically studies in the Czochralski furnace with a uniform axial magnetic field. Important governing factors to the flow fields include buoyancy, thermocapillarity, centrifugal force, magnetic force, diffusion and segregation coefficients of the oxygen, evaporation coefficient in the form of SiO, and ablation rate of crucible wall. With an assumption that the flow fields have reached the steady state, which means that two velocity components in the meridional plane and circumferential velocity, temperatures, electric current intensity become non-transient, then unsteady concentration field of oxygen has been analyzed with an initially uniform oxygen concentration. Oxygen transports due to convection and diffusion in the Czochralski flow field and oxygen flux through the growing crystal surface has been investigated.

• Transactions of the Korean hydrogen and new energy society
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• v.24 no.4
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• pp.320-325
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• 2013

TUnitized reversible fuel cells (URFC) combine the functionality of a fuel cell and electrolyzer in one unitized device. For a URFC with proton exchange membrane, a titanium (Ti)-felt is applied to the gas diffusion layer (GDL) substrate at the oxygen electrode, and additionally titanium (Ti)-powders and TiN-powders are loaded in the GDL substrate as a micro porous layer (MPL). Double porous layer with TiN MPL was not acceptable for the URFC because both of fuel cell performance and electrolysis performance are degraded. The double porous layer with Ti-powder loading in the Ti-felt substrate influence rearly for the electrolysis performance. In contrast, the change of pore-size distribution brings a significant improvement of fuel cell performance under fully humidification conditions. This fact indicates that the hydrophobic meso-pores in the GDL play an important role for mass transport.

• Journal of the Korea Concrete Institute
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• v.15 no.2
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• pp.345-351
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• 2003

The transport characteristics of deleterious ions such as chlorides depend on the pore structures of concrete and are the major factors in the durability of concrete structures in subjected to chloride attack such as in marine environments. In this paper, the effect of the pore structure on compressive strength and chloride diffusivity of concrete was investigated. Six types of concretes were tested. The pore volume of concrete containing mineral admixtures increased in the range of 3∼30nm due to micro filling effect of hydrates of the mineral admixtures. There was a good correlation between the median pore diameter, the pore volume above 50nm and compressive strength of concrete, but there was not a significant correlation between the total pore volume and compressive strength. The relationship between compressive strength and chloride diffusivity were not well correlated, however, pore volume above 50nm were closely related to the chloride diffusion coefficient.

• Journal of the Korean Ceramic Society
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• v.44 no.11
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• pp.597-606
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• 2007

With the advent of ubiquitous age, the high quality dielectric materials have been required for the wireless communications available to the millimeterwave as well as microwave frequencies. The utilizable region for the frequency has been expanding to the millimeter-wave region because of the shortage of radio frequency (RF) resources. These high frequencies would be expected for ultra high speed LAN, ETS and car anti-collision system on the intelligent transport system (ITS) and so on. Silicates are good candidates for microwave/millimeterwave dielectrics, because of their low dielectric constant ${\epsilon}_r$ and high quality factor (High Q). Forsterite ($Mg_2SiO_4$) is one of the silicates with low ${\epsilon}_r$ of 6.8 and Q f of 240000 GHz. In this paper, we reviewed following three categories for synthesis of forsterite: (1) Synthesis of high Q forsterite (2) Adjust the temperature coefficient of resonant frequency $TC_f$ (3) Diffusion of $SiO_{4^-}$ and Mg-ions on the formation of forsterite.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.13 no.2
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• pp.95-101
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• 1999

The electron energy distributions function were analysed in sulIitur hexaflowide at E/N : 500~800(Td) for a case of non-equilibrium region in the nran electron energy. This papa- describes the electron transport characteristics in $ SF_6$ gas calculated for range of E/N values from 150~800(Td) by the Monte Carlo simulation and Boltzmann equation Irethod using a set of electron collision cross sectioos determined by the authors and the values of electron swarm parameters. The results gained that the value of an electron swarm parameter such as the electron drift velocity, the electron ionization or attachment coefficients, longitudinal and transverse diffusion coefficients agree with the experimental and theoretical for a range of E/N. The properties of electron avalanches in an electron energy non-equilibrium region.region.

• Journal of the Korean Ceramic Society
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• v.52 no.5
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• pp.331-337
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• 2015

$LaBO_3$ (B = Cr, Mn, Fe, Co, and Ni) perovskites, the most common perovskite-type mixed ionic-electronic conductors (MIECs), are promising candidates for intermediate-temperature solid oxide fuel cell (IT-SOFC) cathodes. The catalytic activity on MIEC-based cathodes is closely related to the bulk ionic conductivity. Doping B-site cations with other metals may be one way to enhance the ionic conductivity, which would also be sensitively influenced by the chemical composition of the dopants. Here, using density functional theory (DFT) calculations, we quantitatively assess the activation energies of bulk oxide ion diffusion in $LaBO_3$ perovskites with a wide range of combinations of B-site cations by calculating the oxygen vacancy formation and migration energies. Our results show that bulk oxide ion diffusion dominantly depends on oxygen vacancy formation energy rather than on the migration energy. As a result, we suggest that the late transition metal-based perovskites have relatively low oxygen vacancy formation energies, and thereby exhibit low activation energy barriers. Our results will provide useful insight into the design of new cathode materials with better performance.

• Metals and materials international
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• v.24 no.6
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• pp.1232-1240
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• 2018

Corrosion properties of dissimilar friction stir welded 6061 aluminum and HT590 steel were investigated to understand effects of galvanic corrosion. As cathode when coupled, HT590 was cathodically protected. However, the passivation of AA6061 made the aluminum alloy cathode temporarily, which leaded to corrosion of HT590. From the EIS analysis showing Warburg diffusion plot in Nyquist plots, it can be inferred that the stable passivation layer was formed on AA6061. However, the weld as well as HT590 did not show Warburg diffusion plot in Nyquist plots, suggesting that there was no barrier for corrosion or even if it exists, the barrier had no function for preventing and/or retarding charge transport through the passivation layer. The open circuit potential measurements showed that the potential of the weld was similar to that of HT590, which lied in the pitting region for AA6061, making the aluminum alloy part of the weld keep corrosion state. That resulted in the cracked oxide film on AA6061 of the weld, which could not play a role of corrosion barrier.

• 한국해양학회지
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• v.17 no.1
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• pp.12-18
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• 1982

Tidal exchanges of sea water are studied by using drogue experiments and tidal current measurement data in Gamag Bay which has two channels. At the spring tide, the volume of tidal transport in the bay was estimated to be 46∼52% of the total volume of sea water in Gamag Bay, 7.1 10$\^$8/㎥. The tidal transport through the wide channel occupies 87% of the total tide transport of the bay. Residual current was deduced to flow north-northeastward at the rate of 3.254 10$\^$5/㎥ per tidal cycle. the tidal exchange of the sea water during the flood flow was estimated to be approximately 26% of the tidal transport, while that during the ebb flow was 41%. The tidal exchange through the wide channel during the flood flow occupies 77% of total tidal exchange of the bay through both channels, whereas that during the ebb flow does 88%. The diffusion coefficient of 2.08∼ 2.30 10$\^$7/$\textrm{cm}^2$/sec at the narrow channel was greater than that at the wide channel which was 1.2∼2.8 10$\^$6/$\textrm{cm}^2$/sec.

• Journal of computational fluids engineering
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• v.4 no.1
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• pp.8-18
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• 1999

In devising a numerical approximation for the convective spatial transport of a fluid mechanical quantity, it is noted that the convective motion of a scalar quantity occurs in one-way, or from upstream to downstream. This consideration leads to a new scheme termed a pure upwind difference scheme (PUDS) in which an estimated value for a fluid mechanical quantity at a control surface is not influenced from downstream values. The formal accuracy of the proposed scheme is third order accurate. Two typical benchmark problems of a wall-driven fluid flow in a square cavity and a buoyancy-driven natural convection in a tall cavity are computed to evaluate performance of the proposed method. for comparison, the widely used simple upwind scheme, power-law scheme, and QUICK methods are also considered. Computation results are encouraging: the proposed PUDS sensitized to the convection direction produces the least numerical diffusion among tested convection schemes, and, notable improvements in representing recirculation of fluid stream and spatial change of a scalar. Although the formal accuracy of PUDS and QUICK are the same, the accuracy difference of approximately a single order is observed from the revealed results.