• 제목/요약/키워드: transport and diffusion

검색결과 728건 처리시간 0.022초

고분자전해질형 연료전지의 유로 채널 모사를 통한 단일 액적의 불안정성 관찰 (Investigation on the Liquid Water Droplet Instability in a Simulated Flow Channel of PEMFC)

  • 김보경;김한상;민경덕
    • 한국자동차공학회논문집
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    • 제16권2호
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    • pp.93-98
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    • 2008
  • To investigate the characteristics of water droplet on the gas diffusion layer from both top-view and side-view of the flow channel, a rig test apparatus was designed and fabricated with prism attached plate. This experimental device is used to simulate the growth of single liquid water droplet and its transport process with various air flow velocity and channel height. The contact angle hysteresis and height of water droplet are measured and analyzed. It is found that droplet tends towards to be instable by decreasing channel height, increasing flow velocity or making GDL more hydrophobic. Also, the simplified force balance model matches with experimental data only in a restricted range of operating conditions and shows discrepancy as the air flow velocity and channel height increases.

$SF_6$-Ar 혼합기체(混合氣體)의 전자(電子) 평균(平均)에너지 (Mean energy of electrons in $SF_6$-Ar Mixtures Gas)

  • 김상남;성낙진
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2003년도 학술대회 논문집 전문대학교육위원
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    • pp.75-78
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    • 2003
  • Energy distribution function for electrons in $SF_6$-Ar mixtures gas used by MCS-BEq algorithm has been analysed over the E/N range $30\sim300$[Td] by a two term Boltzmann equation and by a Monte Carlo Simulation using a set of electron cross sections determined by other authors, experimentally the electron swarm parameters for 0.2[%] and 0.5[%] $SF_6$-Ar mixtures were measured by time-of-flight(TOF) method. The results show that the deduced electron drift velocities, the electron ionization or attachment coefficients, longitudinal and transverse diffusion coefficients and mean energy agree reasonably well with theoretical for a rang of E/N values. The transport coefficients for electrons in (0.2[%])$SF_6$-Ar and (0.5[%]$SF_6$ - Ar mixtures were measured by time-of-flight method, and the electron energy distribution function and the parameters of the velocity and the diffusion were determined by the variation of the collision cross-sections with energy. The results obtained from Boltzmann equation method and Monte Carlo simulation have been compared with present and previously obtained data and respective set of electron collision cross sections of the molecules.

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Eulerian-Lagrangian Analysis(ELA) 모형을 이용한 오염물질이동 예측 (Prediction of Pollutant Transport using by Eulerian-lagrangian)

  • 최병옥;권순국
    • 한국농공학회지
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    • 제36권1호
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    • pp.128-140
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    • 1994
  • Coastal areas, especially embayments are apt to be polluted easily and many embayments in Korea are already suffering from pollution problems. To manage such pollution, it is strongly needed to develop technique to trace movements of pollution. Such technique cove- ring the embayment affected by the tidal influence, should take account both of the convection and the diffusion motions which cause lots of problems in numerical calculation. In this study, a Eulerian-Lagrangian Analysis(ELA) model was applied to Young Il bay and tested for its applicablity, which was developed by using the Eulerian-Lagrangian Method that reduce the numerical disperison and oscillation by way of solving convection and diffusion terrns separately. Concentration of Chemical Oxygen Demand(COD) and Suspend Solid(SS) of the embay- ment area were estimated by the model and compared with the observed values and the sound results were obtained. At the same time the diffsion coefficient and decay coefficient for Chemical Oxygen Demand in the Young II Bay were found as Dx = Dy = 20m$^2$/sec, kd=2.5 ${\times}$ 10-5/sec respectively, and for Suspend Solid, Dx =Dy = 30m$^2$/sec, kd=5.0${\times}$ 10-5/sec

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수소-산소 대향류 확산 화염에서 산화제와 연료측에 첨가된 Co2의 화학적 효과에 관한 수치해석 연구 (A Numerical Study on Chemical Effects of Co2 Addition to Oxidizer and Fuel Streams in H2-O2 Counterflow Diffusion Flames)

  • 이기만;박정
    • 대한기계학회논문집B
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    • 제28권4호
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    • pp.371-381
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    • 2004
  • Numerical simulation of $CO_2$ addition effects to fuel and oxidizer streams on flame structure has been conducted with detailed chemistry in H$_2$-O$_2$ diffusion flames of a counterflow configuration. An artificial species, which displaces added $CO_2$ in the fuel- and oxidizer-sides and has the same thermochemical, transport, and radiation properties to that of added $CO_2$, is introduced to extract pure chemical effects in flame structure. Chemical effects due to thermal dissociation of added $CO_2$ causes the reduction flame temperature in addition to some thermal effects. The reason why flame temperature due to chemical effects is larger in cases of $CO_2$ addition to oxidizer stream is well explained though a defined characteristic strain rate. The produced CO is responsible for the reaction, $CO_2$+H=CO+OH and takes its origin from chemical effects due to thermal dissociation. It is also found that the behavior of produced CO mole fraction is closely related to added $CO_2$ mole fraction, maximum H mole fraction and its position, and maximum flame temperature and its position.

CF4 기체에서의 전리와 부착계수 (Ionization and Attachment Coefficients in CF4)

  • 김상남
    • 전기학회논문지P
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    • 제60권1호
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    • pp.27-31
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    • 2011
  • In this paper, the electron transport characteristics in $CF_4$ has been analysed over the E/N range 1~300[Td] by a two-term approximation Boltzmann equation method and by a Monte Carlo simulation. The motion has been calculated to give swarm parameters for the electron drift velocity, longitudinal diffusion coefficient, the ratio of the diffusion coefficient to the mobility, electron ionization and attachment coefficients, effective ionization coefficient, mean energy, collision frequency and the electron energy distribution function. The electron energy distribution function has been analysed in $CF_4$ at E/N=5, 10, 100, 200 and 300[Td] for a case of the equilibrium region in the mean electron energy and respective set of electron collision cross sections. The results of Boltzmann equation and Monte Carlo simulation have been compared with experimental data by Y. Nakamura and M. Hayashi. The swarm parameter from the swarm study are expected to serve as a critical test of current theories of low energy electron scattering by atoms and molecules, in particular, as well as crucial information for quantitative simulations of weakly ionized plasmas.

동층류 축대칭 확산화염내의 화염구조 및 매연입자 분포의 예측 (Predictions on the Flame Structure and Soot Distribution in the Coflowing Laminar Diffusion Flames)

  • 이정기;김상수
    • 대한기계학회논문집
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    • 제16권8호
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    • pp.1583-1594
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    • 1992
  • 본 연구에서는 동층류 축대칭 확산화염에서 이전까지의 화염해석 방법들을 면 밀히 고찰하여 층류 확산화염 방식의 연소문제를 해결하는데 있어서 접근이 용이하고 타당성을 가지는 화염해석 방법을 찾아내는데 있으며 매연 입자에 관한 생성및 산화모 델을 총체적으로 연결하여 실험결과와의 비교를 통해 적절한 모델인수를 결정하며 복 사효과와 열영동효과를 고려하여 화염해석과 화염내의 매연입자의 분포를 예측하는데 있다.

The Effect of SnO2 Addition on Sintering Behaviors in a Titanium Oxide-Copper Oxide System

  • Lee, Ju-Won;Oh, Kyung-Sik;Chung, Tai-Joo;Paek, Yeong-Kyeun
    • 한국분말재료학회지
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    • 제29권5호
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    • pp.357-362
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    • 2022
  • The low-temperature sinterability of TiO2-CuO systems was investigated using a solid solution of SnO2. Sample powders were prepared through conventional ball milling of mixed raw powders. With the SnO2 content, the compositions of the samples were Ti1-xSnxO2-CuO(2 wt.%) in the range of x ≤ 0.08. Compared with the samples without SnO2 addition, the densification was enhanced when the samples were sintered at 900℃. The dominant mass transport mechanism seemed to be grain-boundary diffusion during heat treatment at 900℃, where active grain-boundary diffusion was responsible for the improved densification. The rapid grain growth featured by activated sintering was also obstructed with the addition of SnO2. This suggested that both CuO as an activator and SnO2 dopant synergistically reduced the sintering temperature of TiO2.

층류 확산화염에서의 매연과 질소산화물의 배출특성 : 공기측/연료측 희석제 첨가에 따른 영향 (Soot and NOx Emissions in Laminar Diffusion Flames: Effects of Air-Side versus Fuel-Side Diluent Addition)

  • 이종호;엄재호;박철웅;전충환;장영준
    • 대한기계학회논문집B
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    • 제27권5호
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    • pp.596-603
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    • 2003
  • Present study has been conducted to see the relative effects of adding N: to fuel-side and air-side on flame structure, soot formation and NOx emissions. Experiments were carried out to ascertain to what degree chemical kinetics and/or molecular transport effects can explain the differences in soot formation and NOx emission by studying laminar diffusion flames. Direct photograph was taken to see the flame structure. CARS techniques was used to get the flame temperature profiles. And spatial distribution of soot could be obtained by PLII method. CHEMKIN code was also used to estimate the global residence time to predict NOx emissions at each condition. Results from these studies indicate that fuel-side dilution is more effective than air-side dilution in view of NOx emissions. However, air-side dilution shows greater effectiveness over fuel-side dilution in soot formation. And turbulent mixing and heat transfer problems were thought to be considered in practical applications.

화염편 모델을 이용한 층류확산화염장의 매연 생성 및 산화과정 해석 (Flamelet Modelling of Soot Formation and Oxidation in a Laminar $CH_4-Air$ Diffusion Flame)

  • 김군홍;김후중;김용모
    • 한국자동차공학회논문집
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    • 제13권1호
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    • pp.68-75
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    • 2005
  • By utilizing a semi-empirical soot model, the applicability of the laminar flamelet concept fur simulating the formation and oxidation of soot in the laminar diffusion flame has been studied. The source terms for two transport equations of the soot formation and oxidation are calculated in the mixture fraction/scalar dissipation rate space for laminar flamelets and stored in a library. In this study, emphasis is given to the interaction associated with radiation and soot formation. The radiative heat loss is obtained by solving the radiative transfer equation using the unstructured grid finite volume method with the WSGGM. The calculated temperatures and soot volume fractions agree relatively well with the experimental data and the previous numerical results of Kaplan et al. using the detailed chemistry.

Czochralski 방법에 의한 실리콘 단결정 성장에서 자장에 의한 산소의 전달 현상 제어 (Effect of applied magnetic fields on oxygen transport in magnetic Czochralski growth of silicon)

  • Chang Nyung Kim
    • 한국결정성장학회지
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    • 제4권3호
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    • pp.210-222
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    • 1994
  • 축방향의 균일한 자장이 Czochralski 도가니에 가하여졌을 때의 유동장, 온도장 및 산소의 농도장이 수치적으로 연구되었다.Czochralski 유동장과 농도장에 작용하는 부력, thermocapillarity, 원심력, 자성력, 산소의 확산계수, 산소의 segregation coefficient, SiO형태의 evaporation, 도가니벽의 ablation 등이 고려되었다. 회전방향으로의 대칭성으로부터 자오면에서의 속도성분과 회전방향의 속도성분, 온도, 전류의 흐름 등이 먼저 정상상태에 도달하였다고 가정하고 초기에 일정한 산소의 농도가 주어진 상황에서 비정상 상태의 산소의 농도장이 해석되었다. Czochralski 유동장에서의 대류와 확산에 의한 산소의 전달현상이 파악되었으며 결정성장 표면으로 흡수되는 산소의 농도가 연구되었다.

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