• Title/Summary/Keyword: transport and diffusion

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Numerical Study of Flow Around Impulsively Started Elliptic Cylinder Using Vortex Particle Method (입자와법에 의한 급 출발하는 타원형 실린더 주위 유동해석)

  • Lee, Sang-Hwan;Joo, Nam-Soo
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.28 no.7
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    • pp.809-817
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    • 2004
  • In this paper, the unsteady behavior of the viscous flow field past an impulsively started elliptic cylinder is studied numerically. In order to analyze flow field, we introduce vortex particle method. The vorticity transport equation is solved by fractional step algorithm which splits into convection term and diffusion term. The convection term is calculated with Biot-Savart law, the no-through boundary condition is employed on solid boundaries. The diffusion term is modified based on the scheme of particle strength exchange. The particle redistributed scheme for general geometry is adapted. The flows around an elliptic cylinder are investigated for various attack angles at Reynolds number 200. The comparison between numerical results of present study and experimental data shows good agreements.

Electrochemical Properties of Polypyrrole-Glucose Oxidase Enzyme Electrode Depending on Dopant Size (Polypyrrole-Glucose Oxidase 효소전극의 배위자 크기에 따른 전기 화학적 특성)

  • 김현철;구할본;사공건
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.745-748
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    • 2001
  • We synthesized polypyrrole (PPy) by electrolysis of the pyrrole monomer solution containing support electrolyte KCl and/or p-toluene sulfonic acid sodium salt (p-TS). The electrochemical behavior was investigated using cyclic voltammetry and AC impedance. In the case of using electrolyte p-TS, the redox potential was about -0.3 V vs. Ag/AgCl reference electrode, while the potential was about 0 V for using electrolyte KCl. It is considered as the backbone forms a queue effectively by doping p-T S. Therefore, it is possible to be arranged regularly. That leads to improvement in the electron hopping. The AC impedance plot gave a hint of betterment of mass transport. PPy doped with p-TS has improved in mass transport, or diffusion. That is because the PPy doped with p-TS has a good orientation, and is more porous than PPy with KCl.

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Electrochemical Properties of Polypyrrole Enzyme Electrode Immobilized Glucose Oxidase with Different Ligand (포도당 산화효소를 고정화한 Polypyrrole 효소전극의 배위자 변화에 다른 전기화학적 특성)

  • Kim, Hyun-Cheol;Gu, Han-Bon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11b
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    • pp.529-532
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    • 2001
  • We synthesized polypyrrole (PPy) by electrolysis of the pyrrole monomer solution containing support electrolyte KCl and/or p-toluene sulfonic acid sodium salt (p-TS). The electrochemical behavior was investigated using cyclic voltammetry and AC impedance. In the case of using electrolyte p-TS, the redox potential was about -0.3 V vs. Ag/ AgCl reference electrode, while the potential was about 0 V for using electrolyte KCl. It is considered as the backbone forms a queue effectively by doping p-TS Therefore, it is possible to be arranged regularly. That leads to improvement in the electron hopping. The AC impedance plot gave a hint of betterment of mass transport. PPy doped with p-TS has improved in mass transport, or diffusion. That is because the PPy doped with p-TS has a good orientation, and is more porous than PPy with KCl.

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Analysis of electron transport properties in $SF_6$+He mixture gas used by MCS-BE (MCS-BE에 의한 $SF_6$+He 혼합기체의 전자수송특성 해석)

  • 하설철;송병두;유회영;김상남;백승권
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.13 no.4
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    • pp.359-364
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    • 2000
  • The paper describes the electron transport characteristics in SP$_{6}$+He gas calculated E/N values 0.1~700[Td] by the Monte Carlos simulation and Boltzmann equation method using a set of electron collision cross sections determined by the authors and the values of electron swarm parameters obtained by TOF method. This study gained the values of the electron swarm parameters such as the electron drift velocity the electron ionization or attachment coefficients longitudinal and transverse diffusion coefficients for SF$_{6}$+He gas at a range of E/N.E/N.

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Electrochemical Properties of Polypyrrole Enzyme Electrode Immobilized Glucose Oxidase with Different Ligand (포도당 산화효소를 고정화한 Polypyrrole 효소전극의 배위자 변화에 따른 전기화학적 특성)

  • 김현철;구할본
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11a
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    • pp.529-532
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    • 2001
  • We synthesized polypyrrole (PPy) by electrolysis of the pyrrole monomer solution containing support electrolyte KCl and/or p-toluene sulfonic acid sodium salt (p-TS). The electrochemical behavior was investigated using cyclic voltammetry and AC impedance. In the case of using electrolyte p-75, the redox potential was about -0.3 V vs. Ag/AgCl reference electrode, while the potential was about 0 V for using electrolyte KCl. It is considered as the backbone forms a queue effectively by doping p-TS Therefore, it is possible to be arranged regularly. That leads to improvement in the electron hopping. The AC impedance plot gave a tent of betterment of mass transport. PPy doped with p-TS has improved in mass transport, or diffusion. That is because the PPy doped with p-TS has a good orientation, and is more porous than PPy with KCl.

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Ionization and Attachment Coefficients in Mixtures of $SF_6$ and Ar ($SF_6$-Ar 혼합기체에서의 전리와부착계수)

  • 김상남;하성철
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.14 no.9
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    • pp.773-778
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    • 2001
  • In this dissertation the results of the combined experimental and theoretical studies designed to understand and predict the spatial growth and transport coefficients for electrons in SF$_{6}$ and SF$_{6}$-Ar mixtures have described. The ionization and attachment coefficients in pure SF$_{6}$ and SF$_{6}$-Ar mixtures have been calculated over the range of 10$_{6}$ molecule and for Ar atom proposed by other authors. The transport coefficients for electrons in (0.2%)SF$_{6}$-Ar and (0.5%)SF$_{6}$-Ar mixtures were measured by time-of-flight method, and the electron energy distribution function and the parameters of the velocity and the diffusion were determined by the variation of the collision cross-sections with energy. The results obtained in this work will provide valuable information on the fundamental haviors of electrons in weakly ionized gases and the role of electron attachment in the choice of better gases and unitary gas dielectrics or electro negative components in dielectric gas mixtures. gas mixtures.

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Fluid Transport Properties of Skin Concrete and New Suggestion to Determine Minimum Cover Concrete (콘크리트 표면의 유체이동특성과 최소피복두께 결정을 위한 제안)

  • 이창수;윤인석
    • Proceedings of the Korea Concrete Institute Conference
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    • 2002.10a
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    • pp.543-546
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    • 2002
  • This paper discussed micro - structure of skin concrete to understand transport properties from surface and seek thickness from surface which is seriously influenced on durability. Concrete at nearer surface has high porosity relative to inner concrete. The porosity of concrete and ISAT value at region from surface to 20 mm depth is decreased with depth. On the other hand, according to the result of ASTM C 1202 with specimen thickness, critical depth which affects fast ionic penetration through interfacial transition zone (ITZ) equals 35mm and the critical depth would be directly influenced by the effects of ITZ on chloride diffusion unrelated with W/C ratio.

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Study on the electron transport properties in $SF_6$+He mixtures gas used by MCS-BE ($SF_6$+He 혼합기체의 MCS-BE에 의한 전자수송계수 연구)

  • Kim, Sang-Nam;Seo, Sang-Hyeon;Ha, Sung-Chul;Yu, Heoi-Young;Song, Byung-Doo
    • Proceedings of the KIEE Conference
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    • 1999.11a
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    • pp.16-19
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    • 1999
  • This paper describes the electron transport characteristics in $SF_6$+He gas calculated for range of E/N values from $50{\sim}700[Td]$ by the Monte Carlo simulation and Boltzmann equation method using a set of electron collision cross sections determined by the authors and the values of electron swarm parameters are obtained by TOF method. The results gained that the values of the electron swarm parameters such as the electron drift velocity, the electron ionization or attachment coefficients, longitudinal and transverse diffusion coefficients agree with the experimental and theoretical for a range of E/N.

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The Effect of Dislocation Pipe Diffusion on Electro-Migration-Induced Breakdown in an FCC Structure (면심입방구조에서 Electro-Migration-Induced Breakdown에 대한 전위파이프 확산의 영향)

  • 이득용
    • Journal of the Korean Ceramic Society
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    • v.28 no.11
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    • pp.878-884
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    • 1991
  • The mobility and diffusivity in an edge dislocation in an FCC crystal formed by the removal of one half of a (100) plane were evaluated in an applied field by analyzing a vacancy tight binding model using Stark's matrix technique. A model of an edge dislocation in an FCC crystal was constructed for a [100] Burgers vector where vacancy transport along the edge dislocation in an FCC crystal was constructed for a [100] Burgers vector where vacancy transport along the edge of the extrac half plane of ions was considered. The model considered a tight binding approximation of the vacancy to the compressed region of the core and carried the calculation to the limit of an infinite length of dislocation. The diffusivity and the ratio of mobility to diffusivity were found to increase without bounds in the limit where the correlation factor becomes zero. In contrast, as the correlation factor became unity, the diffusivity became zero and the ratio of mobility to diffusivity became unity associated with the uncorrelated limit of 1/kT. This implied that the phenomenon was not unique to the crystal structure but was unique to edge dislocations with vacancy tight binding.

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Analysis of electron transport coefficients in Air (Air에서의 전자수송계수 특성파악)

  • Seo, Sang-Hyun;Ha, Sung-Chul;Jun, Byung-Hun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.05c
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    • pp.181-184
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    • 2002
  • The electron transport coefficients in Air is analysed in range of E/N values from 100~1000(Td) by a MCS and BE method. This paper have calculated W, $ND_L$,$ ND_T$, Mean energy mixtures by $N_2+O_2$. The results gained that the values of the electron swarm parameters such as the electron drift velocity, longitudinal and transverse diffusion coefficients.

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