• Title/Summary/Keyword: transition region

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The Physical Properties and Dyeability of Poly(trimethylene terephthalate) Fibers (Poly(trimethylene terephthalate) 섬유의 물성과 염색성)

  • 윤석한;김태경;임용진;조규민
    • Textile Coloration and Finishing
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    • v.13 no.3
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    • pp.197-202
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    • 2001
  • The mechanical properties and dyeability of Poly(trimethylene terephthalate)(PTT) were investigated and compared to PET. Glass transition temperature of PTT was lower than that of PET, because amorphous region of PTT is mote flexible. n has smaller molecular and specific stress and larger strain than those of PET, due to the difference of molecular structure. Dyeing transition temperature of PTT was lower by $20^\circ{C}$ than that of PET. Because PTT has flexible chain and zigzag structure, dyeing Fate of PTT is faster than PET and dyeing of PTT is begun at lower temperature. As the hydrophobicity of disperse dyes increased, the ratio of equilibrium dye uptake on PTT to that on PET was increased.

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A Study on Transition From Cycle-dependent to Time-dependent Crack Growth in SUS304 Stainless Steel (SUS304강의 사이클의존형에서 시간의존형균열성장으로의 천이에 관한 연구)

  • 주원식;조석수
    • Journal of Welding and Joining
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    • v.14 no.1
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    • pp.38-46
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    • 1996
  • High temperature low cycle fatigue crack growth behavior is investigated over a range of two temperatures and various frequencies in SUS 304 stainless steel. It is found that low frequency and temperature can enhance time-dependent crack growth. With high temperature, low frequency and long crack length, ${\Delta}J_c/{\Delta}J_ f$, the ratio of creep J integral range to fatigue J integral range is increased and time-dependent crack growth is accelerated. Interaction between ${\Delta}J_f$ and ${\Delta}J_c$ is occured at high frequency and low temparature and ${\Delta}J_c$, creep J integral range is fracture mechanical parameter on transition from cycle-dependent to time dependent crack growth in creep temperature region.

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A Study on the Crystallinity in Silk Fibers(II) -Crystallization in Silk Fibroin by Acid Treatment and Its Photoyellowing Reduction Effect- (견의 결정성에 관한 연구(II) -견 피브로인의 산 처리에 의한 결정화와 황변억제효과에 대하여-)

  • 장정대;최석철
    • Textile Coloration and Finishing
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    • v.6 no.2
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    • pp.24-29
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    • 1994
  • In order to investigate the crystallization in silk fibroin induced by acid treatment and its photo-yellowing reduction effect. silk fibroin were immersed in PH 3.5~4.0 sulfuric acid and 0.01N hydro-chloric acid at 2$0^{\circ}C$, and the changes of crystallinity were measured by infrared spectroscopy, X-ray diffraction. Yellowness index caused by UV irradiation were also observed. The results are as follows : 1. ${\beta}$-form transition occurs when the silk fibroin are immersed at 2$0^{\circ}C$ in pH 3.5~4.0 sulfuric acid and 0.01N hydro-chloric acid. Formation of new hydrogenbond in molecules on the amorphous region induced ${\beta}$-form structure, and increased crystallinity. 2. Crystallization owing to $\beta$-form transition reduced the initial yellowness index by ultraviolet irradiation.

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Return Migration in Regional Innovation Systems

  • Sternberg, Rolf;Muller, Claudia
    • Journal of Technology Innovation
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    • v.13 no.2
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    • pp.71-95
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    • 2005
  • This study aims to explore and understand the role of return migrants in the regional innovation system of a transition economy (China) by analyzing the activities of returning entrepreneurs in two emerging high-tech industries in Shanghai. The empirical analysis is based on in-depth interviews with founders of high-tech companies and experts in Shanghai. The results of the analysis reveal that return migrants are a significant factor for the Shanghai innovation system, which is presently in a transition from a former manufacturing site to a metropolitan region comprising a range of industries (including high-tech) and services. First of all, return migrants are important for the Shanghai RIS in terms of numbers. Second, they engage in activities in the medium range of high-tech which reflects prevailing weaknesses of the framework conditions for innovation in Shanghai. However, due to their international background, returning entrepreneurs are able to overcome these weaknesses, and thus contribute to the development of high-tech industries in Shanghai and to a reduction of the technological lock-in.

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Electrical Properties and Structures of Spinel Type LiMn$_{2-y}$M$_y$O$_4$(M=Cr$^{3+}$) Doped with Transition Metal (전이금속으로 치환된 Spinel형 LiMn$_{2-y}$M$_y$O$_4$(M=Cr$^{3+}$)의 구조 및 전기적 성질)

  • 형경우;김중헌;권태윤
    • Journal of the Korean Ceramic Society
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    • v.36 no.9
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    • pp.930-936
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    • 1999
  • For LiMn2O4 based spinel structures the stoichiometric reaction conditions need be considered carefully because the electrical properties depend on the structural stability. In order to obtain the homogeneous compound the Pechini process was chosen which could obtain a stoichiometry phase even low temperature and dependency of the synthetic condition on structural stability and electrochemical performance was investigated. X-ray diffraction studies showed that the compounds doped with transition metal have smaller lattice constants than those un doped. The dc conductivity was evaluated by a four probe method in the low and high temperature region respectively. The variations of basal spacings for the cathode were detected to be dependent on the extent of current flows (under dc)

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A Study on Characteristics of Secondary Vortices in the Near Wake of a Circular Cylinder by PIV Measurement (PIV 계측에 의한 실린더 근접후류에서 2차 와류의 특성 연구)

  • Sung, Jae-Yong;Yoo, Jung-Yul
    • Proceedings of the KSME Conference
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    • 2000.11b
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    • pp.404-409
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    • 2000
  • Characteristics of secondary vortices is topologically investigated in the near-wake region of a circular cylinder where the Taylor hypothesis does not hold. The three-dimensional flow fields in the wake-transition regime were measured by a time-resolved PIV. For the analysis in a moving frame of reference, the convection velocity of the Karman vortices is evaluated from the trajectory of vortex center which is defined as the centroid of the vorticity field. Then, a saddle point is obtained by applying the critical point theory. Science the distributions of fluctuating Reynolds stresses defined by triple-decomposition are closely related with the existence of secondary vortices. the physical meaning of them is explained in conjunction with vortex center and saddle point trajectories. Finally, the temporal evolution of streamwise vortex is also discussed.

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Electron Spin Transition Line-width of Mn-doped Wurtzite GaN Film for the Quantum Limit

  • Park, Jung-Il;Lee, Hyeong-Rag;Lee, Su-Ho;Hyun, Dong-Geul
    • Journal of Magnetics
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    • v.17 no.1
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    • pp.13-18
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    • 2012
  • Starting with Kubo's formula and using the projection operator technique introduced by Kawabata, EPR lineprofile function for a $Mn^{2+}$-doped wurtzite structure GaN semiconductor was derived as a function of temperature at a frequency of 9.49 GHz (X-band) in the presence of external electromagnetic field. The line-width is barely affected in the low-temperature region because there is no correlation between the resonance fields and the distribution function. At higher temperature the line-width increases with increasing temperature due to the interaction of electrons with acoustic phonons. Thus, the present technique is considered to be more convenient to explain the resonant system as in the case of other optical transition systems.

A Study on Degradation Characteristic and Flow Behavior in De-NOx Catalyst (탈질촉매 내 열화특성과 유동상태에 관한 연구)

  • Hwang, Seung-Min
    • Journal of Environmental Science International
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    • v.19 no.9
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    • pp.1093-1101
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    • 2010
  • In this study, the indirect correlation of degradation characteristic and flow behavior in the de-NOx catalyst is investigated experimentally. The inner flow behavior in the de-NOx catalyst is varied from turbulent flow to laminar flow and the degradation of the de-NOx catalyst is remarkably affected by the inner flow. The degradation of the catalyst is increased in the upstream region near the inlet because injected turbulent flow enhances the adhesion of ash particle on the catalyst surface. The degradation of the catalyst near the inlet also governs the overall efficiency of the catalyst. The amount of adhered ash particles on the catalyst surface decreases as they progress downstream. This is due to the inner flow transition from turbulent flow to laminar flow.

A Study on the Text-to-Speech Conversion Using the Formant Synthesis Method (포만트 합성방식을 이용한 문자-음성 변환에 관한 연구)

  • Choi, Jin-San;Kim, Yin-Nyun;See, Jeong-Wook;Bae, Geun-Sune
    • Speech Sciences
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    • v.2
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    • pp.9-23
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    • 1997
  • Through iterative analysis and synthesis experiments on Korean monosyllables, the Korean text-to-speech system was implemented using the phoneme-based formant synthesis method. Since the formants of initial and final consonants in this system showed many variations depending on the medial vowels, the database for each phoneme was made up of formants depending on the medial vowels as well as duration information of transition region. These techniques were needed to improve the intelligibility of synthetic speech. This paper investigates also methods of concatenating the synthesis units to improve the quality of synthetic speech.

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A Study of the numerical method on the molecular transition flow for the rotating blades (회전날개주위 분자천이유동의 수치해석방법에 관한 연구)

  • 허중식;황영규;박종윤
    • Journal of the Korean Vacuum Society
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    • v.8 no.2
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    • pp.83-92
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    • 1999
  • Pumping performance of a disk-type molecular drag pump for a hybrid molecular pump is numerically analyzed by the direct simulation onte-Carlo method. The flows in pumping channels are three-dimensional (3D) in a molecular transition regime. The main difficulty in modeling a 3D case comes from the rotating frame of reference. Thus, trajectories of particles ar no longer straight lines. In the present study, trajectories of particles are calculated by integrating a system of differential equations including the Coriolis and centrifugal forces. The null-collisions. The present numerical results molecular model is used for calculation of molecular collisions. The present numerical results significantly disagree with the previously known ones. This indicates that an actual pumping passage is very limited to a narrow region due to the significant backstreaming of molecules from the outlet.

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