• Title/Summary/Keyword: transformation ratio

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Reactivity of the Biheterocyclic Betaine with the para-Substituted Phenacyl Bromides for the Ring Transformation Reaction

  • Yoo, Kyung-Ho;Kim, Dong-Jin;Kim, You-Seung;Park, Sang-Woo
    • Bulletin of the Korean Chemical Society
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    • 제9권3호
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    • pp.164-166
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    • 1988
  • 7-Dithiocarboxy-3-phenyl-5,6-dihydro imidazo[2,1-b]thiazolium-betaine (2) was prepared by treatment of 3-phenyl-5,6-dihydro imidazo[2,1-b]thiazole (1) with carbon disulfide in acetone at room temperature. On the reaction of 2 with para-substituted phenacyl bromides (4) having the electron withdrawing property by virtue of (+) resonance (R) < (-) inductive (I) or (-) resonance (R), (-) inductive (I) effect, ring transformation product p-substituted-2-[2-[7-(p-substituted benzoyl)-5-thioxo-2,3-dihydro-1H-imidazo[1,2-c] thiazol-1-yl]-2-phenylvinylthio] acetophenone (6) was obtained; however, when R is electron donating grops with (+) resonance (R) > (-) inductive (I) effect the quarternary ammonium salt 7-(p-substituted phenyl) carbonyl methyl-3-phenyl-5,6-dihydro imidazo [2,1-b] thiazolium bromide (8) is formed. The reaction of 2 with unsubstituted-phenacyl bromide (R = H), on the other hand, gives 6a and 8a to the similar ratio, respectively.

Development of Transformation-Core for Magnetic Field in Switchgear

  • Gwan-hyung Kim
    • Journal of information and communication convergence engineering
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    • 제21권4호
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    • pp.316-321
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    • 2023
  • In this study, we developed a conversion core that produces power by utilizing the unused magnetic field in a switchboard. The conversion core makes it possible to utilize power that is normally wasted. The conversion core is composed of a core, filter, and battery. A prototype was installed in a switchboard to conduct tests on the output, battery storage, and output boosting of multiple batteries. Energy was harvested from the magnetic field generated by a busbar of the switchboard, and the power conversion ratio of the core yielded 1.08-1.01 mW per 1 A of bus current. Supplying this technology to the market after further R&D and commercialization is expected to greatly assist in the dissemination of energy harvesting, which has not yet spread widely to the general public.

In-X(X=Pb,Sn) 합금의 마르텐사이트변태거동 특성에 관한 연구 (A Study on the Characteristics of Martensitic Transformation Behaviors in In-X(X=Pb,Sn) Alloys)

  • 한창석;한승오
    • 열처리공학회지
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    • 제23권5호
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    • pp.233-238
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    • 2010
  • The phase transformations and the shape memory effect in In-rich Pb alloys and In rich-Sn alloys have been studied by means of X-ray diffractometry supplemented by metallographic observations. The alloys containing 12~15 at.%Pb transform from the ${\alpha}_2$ (fct) phase to the ${\alpha}_1$ (fct) phase by way of an intermediate phase (m phase) on cooling. The results of X-ray diffraction show that the metastable intermediate phase is observed both on cooling and heating, and has a face-centered orthorhombic (fco) structure. It is concluded that the ${\alpha}_1{\rightleftarrows}{\alpha}_2$ transformation is expressed by the ${\alpha}_1{\rightleftarrows}m{\rightleftarrows}{\alpha}_2$ transformation both on usual cooling and heating with the rate more than $8{\times}10^{-3}$ K/s. The $m{\rightleftarrows}{\alpha}_2$ transformation takes place with a mechanism involving macroscopic shear and are of diffusionless (martensitic) type. The temperature hysteresis in the two transformations is 10~13 K between the heating and cooling transformations. The alloys containing 0~11 at.%Sn are -phase solid solutions with a face centered tetragonal structure (c/a > 1) at room temperature, the axial ratio increasing continuously with tin content. The In-(11~15) at.%Sn alloys are mixtures of ${\alpha}$ and ${\beta}$ phases, the ${\beta}$ phase having a f. c. tetragonal structure (c/a < 1). The alloys containing more than 15 at.%Sn are ${\beta}$-phase solid solutions. The In-(12.9~15.0) at.%Sn alloys show a shape memory effect only when quenched to the temperature of liquid nitrogen, although their effect becomes weak and finally disappears after keeping at room temperature for a long time. The ${\beta}{\rightarrow}{\alpha}^{\prime}$ phase transformation is of the diffusionless (martensitic) type, and takes place between 330 K at 12.9 at.%Sn and 150 K at 14.5 at.%Sn. The hysteresis of transformation temperatures on heating and cooling is considerably large (29~40 K), depending on the composition. Both In-Pb and In-Sn alloys showed distinct the shape memory effects.

Capacity and the moment-curvature relationship of high-strength concrete filled steel tube columns under eccentric loads

  • Lee, Seung-Jo
    • Steel and Composite Structures
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    • 제7권2호
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    • pp.135-160
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    • 2007
  • Recently, CFT column has been well-studied and reported on, because a CFT column has certain superior structural properties as well as good productivity, execution efficiency, and improved rigidity over existing columns. However, CFT column still has problems clearing the capacity evaluation between its steel tube member and high-strength concrete materials. Also, research on concrete has examined numerical values for high-strength concrete filled steel square tube columns (HCFT) to explain transformation performance (M-${\phi}$) when a short-column receives equal flexure-moment from axial stress. Moment-curvature formulas are proposed for HCFT columns based on analytic assumption described in this paper. This study investigated structural properties (capacity, curvature), through a series of experiments for HCFT with key parameters, such as strength of concrete mixed design (58.8 MPa), width-thickness ratio (D/t), buckling length to sectional width ratio (Lk/D) and concrete types (Zeolite, Fly-ash, Silica-fume) under eccentric loads. A comparative analysis executed for the AISC-LRFD, AIJ and Takanori Sato, etc. Design formulas to estimate the axial load (N)-moment (M)-curvature (${\phi}$) are proposed for HCFT columns based on tests results described in this paper.

광대역 정규 프로세스에 대한 주파수 영역 기반 피로해석법의 적용성에 관한 연구 I : 레일리 PDF (Study on Applicability of Frequency Domain-Based Fatigue Analysis for Wide Band Gaussian Process I : Rayleigh PDF)

  • 정준모;김경수;남지명;구정본;김민수;심용래;엄항섭
    • 대한조선학회논문집
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    • 제49권4호
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    • pp.350-358
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    • 2012
  • This paper deals with accuracy of accumulated fatigue damage estimation using stochastic fatigue analysis method based on Rayleigh PDF. From full scale measurement data on an 8100TEU container vessel, zero-order spectral moments for wave- and vibration-induced energy spectral densities are determined on the probability level of 99%. 80 simulation cases in total are prepared according to the variation of ratio of zero-order spectral moments and center frequency of vibration ESD. By using inverse Fourier transformation and rainflow cycle counting for the combined ESD of wave and vibration, exact fatigue damages are derived. Fatigue damages in frequency domain based on Rayleigh PDF show large conservativeness compared to exact fatigue damages in times domain. The main cause of the excessive conservativeness is analyzed by two aspects: ratio of zero crossing and peak frequencies and ratio of initial zero order spectral moments and zero order spectral moments from rainflow stress range distributions. Finally, a guideline of applicability of Rayleigh PDF is proposed for wide band processes.

변환각 트러스 모델에 의한 축력을 받는 철근콘크리트 부재의 전단강도 예측 (Shear Strength Prediction of Reinforced Concrete Members Subjected In Axial force using Transformation Angle Truss Model)

  • 김상우;이정윤
    • 콘크리트학회논문집
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    • 제16권6호
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    • pp.813-822
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    • 2004
  • 축하중을 받는 철근콘크리트 부재의 전단강도를 예측하기 위하여, 본 연구에서는 전단력과 축하중 및 휨모멘트를 받는 철근 콘크리트 부재의 전단거동을 예측할 수 있는 변환각 트러스 모델(TATM)을 제안하였다. TATM에서, 축력의 영향을 고려하기 위하여 축압축력이 증가할수록 고정각은 감소하며 균열 방향의 콘크리트 전단저항은 증가한다. TATM의 예측결과가 축력을 받는 철근콘크리트 부재에 대하여 정확성과 신뢰성을 가지는지 검증하기 위하여, 축력을 받는 총 67개의 전단실험 결과를 수집하였으며, TATM 및 기존의 트러스 모델(MCFT, RA-STM FA-STM)과 비교하였다. 수집한 실험결과와 해석결과를 비교한 결과, TATM에 의한 해석결과는 실험결과를 평균 0.95, 변동계수 $12.0\%$로 기존의 트러스 모델보다 더 정확히 예측하였으며, 철근능력비, 축력, 전단경간비 및 압축철근비의 영향을 받지 않았다.

날개형 및 격막형 배플을 이용한 유체저장탱크 내부의 슬로싱 저감 연구 (A Study on the Reduction of the Sloshing of Storage Tank Using Wing and Diaphragm Baffle)

  • 이영신;김현수;이재형;김영완;고성호
    • 대한기계학회논문집A
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    • 제27권12호
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    • pp.2039-2046
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    • 2003
  • Storage tank filled with fluid has unique dynamic characteristics compared to general structures, due to the interaction between fluid and structure. The oscillation of the fluid surface caused by external forces is called sloshing, which occurs in moving vehicles with contained liquid masses, such as trucks, railroad cars, aircrafts, and liquid missles. In this study, the evaluation method for the reduction of sloshing, the optimized size and location of wing and diaphragm baffles are suggested based on the experimental results. The experimental device can simulate the translation motion. A rectangular tank and various baffles are fabricated to study on the sloshing characteristics. The forces measured using the load cell at tank wall and those are compared with each other through the Fourier transformation for various conditions. The study of the sloshing of the rectangular tank equipped with baffles is conducted under the same conditions with non-baffled rectangular tank experiment. From the experimental results, the sloshing reduction effect by the baffles is observed. In conclusion in case of diaphragm baffles, the optimized size ratio of the width of baffle to the water height is 0.44 and the installation location has no effect to the damping of sloshing. In case of wing baffles, the optimized size ratio of the width of baffle to the length of a rectangular tank is 0.1 and the optimized location ratio of the baffle to the water height is 0.9.

완전한 인볼류트 베벨기어쌍의 기구학적 고찰 및 형상 모형화 (Kinematical Investigation and Geometry Modeling of the Perfect Involute Bevel Gearsets)

  • Park, N.G.
    • 한국정밀공학회지
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    • 제12권5호
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    • pp.46-56
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    • 1995
  • As demands on the precision bevel gears are increased in the related industry, the exact kinematical investigations of a pair of spherical involute bevel gears are required for the computer aided design. The exact angular velocity ratio based on the characteristics of the spherical involute tooth is derived and verified from the relationship between rotational angles. Elementary kinematics of the gearsets is investigated by applying the transformation of the coordinate systems. The tooth contact lines based on logarithmic tooth-wise curve are examines in three dimentional space. Contact ratio is formulated and simulated according to the system parameters such as shaft angles, pressure angle, and spiral angles. The condition of teeth interference is dervied and the critical numbers of gear teeth are calculated. The whole surface geometry of a spiral bevel gearsets are discretized and visualized by a computer graphic tool.

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왜곡률을 이용한 고정자 권선고장 자동진단 (Automatic Diagnosis for Stator Winding Faults Using Distortion Ratio)

  • 송명현;박규남;한동기;양철오
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2007년도 제38회 하계학술대회
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    • pp.358-360
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    • 2007
  • In this paper, an auto-diagnosis method of the stator winding fault for small induction motor is suggested. 3-phase stator currents are sampled, filtered, and transformed with Park's vector transformation. After then Park's vector patterns are obtained. To detect the stator winding fault automatically, a distortion ratio (id/iq) is newly defined and compared with the one of healthy motor, and the threshold levels are suggested. The 2-turn, 4-turn, 8-turn winding fault are tested with no load, 25%, 50%, 75%, and 100% rated load. The distortion ratio of the Park's vector patterns are increased as the increase of the faulted turns, but are same as the increase of the load.

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Control Bandwidth Extension Method Based on Phase Margin Compensation for Inverters with Low Carrier Ratio

  • Wei, Qikang;Liu, Bangyin;Duan, Shanxu
    • Journal of Power Electronics
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    • 제18권6호
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    • pp.1760-1770
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    • 2018
  • This paper presents a control bandwidth extension method for inverters with a low carrier ratio. The bandwidth is extended at the price of decreasing the phase margin. Then the phase margin is compensated by introducing an extra leading angle into an inverse Park transformation. The model of the controller with the proposed method is established. The magnitude and phase characteristics are also analyzed. Then the influence on system stability when the leading angle is introduced is analyzed. The proposed method is applied to design an inverter controller with both a large bandwidth and a desired phase margin, and the experimental results verify that the controller performs well in the steady-state and in terms of transient response.