• Title/Summary/Keyword: transformation rate

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Polymorphism of Sulpiride and its Pharmaceutical Applications(II) Transformation Kinetics of Sulpiride Polymorphs (Sulpiride의 Polymorphism 및 그 약제학적 연구(II) Polymorph 상호간의 Transformation Kinetics)

  • 김길수;이민화
    • YAKHAK HOEJI
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    • v.26 no.4
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    • pp.231-237
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    • 1982
  • The transformation kinetics between polymorphs of sulpiride and the effect of additives on the transformation kinetics were studied. The results could be summarized as follows. 1. Transformation kinetics of the polymorph form I to form II in water suspenion was first order type and transformation rate constant at $25^{\circ}C$ is $2.61{\times}10^{-2}min^{-1}$, the half life of form I was about 27 minutes and the activation energy for transformation was 21.35 Kcal/mole. 2. Glycerine and coloring agents increased the rate of transformation., In the case of polysorbate 80, the rate constant increased in proportion to the concentration of polyserbate 80. Simple syrup showed no effect 3n transformation kinetics.

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Effects of Ni addition on continuous cooling transformation behavior of low carbon HSLA steels (저탄소${\cdot}$저합금 강의 연속 냉각 변태에 미치는 Ni의 영향)

  • Kang J. S.;Jun J. H.;Park C. G.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2005.10a
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    • pp.456-459
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    • 2005
  • Continuous cooling transformation behaviors were studied fur low carbon HSLA steels containing three different level $(1\~3\;wt\%)$ of Ni addition. Thermo-mechanical processing (TMP) simulations to construct continuous cooling (CCT) diagram were conducted by using Gleeble system. As cooling rate increased, pearlite, granular bainite, acicular ferrite, bainitic ferrite and lath martensite were transformed from deformed austenite. Fully bainitic microstructure were developed at all cooling rate condition in high Ni containing steel due to hardenability increasing effects of Ni. Ni also influenced the transformation kinetics. At the slowest cooling rate of $0.3^{\circ}C/s$, transformation delayed with decreasing Ni contents because of the diffusion of substitutional alloy elements. However, cooling rate slightly increased to $1^{\circ}C/s$, transformation kinetics accelerated with decreasing Ni contents because nucleation of bainite was sluggish due to hardening of residual austenite.

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The Effects of Physicochemical Factors and Cell Density on Nitrite Transformation in a Lipid-Rich Chlorella

  • Liang, Fang;Du, Kui;Wen, Xiaobin;Luo, Liming;Geng, Yahong;Li, Yeguang
    • Journal of Microbiology and Biotechnology
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    • v.25 no.12
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    • pp.2116-2124
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    • 2015
  • To understand the effects of physicochemical factors on nitrite transformation by microalgae, a lipid-rich Chlorella with high nitrite tolerance was cultured with 8 mmol/l sodium nitrite as sole nitrogen source under different conditions. The results showed that nitrite transformation was mainly dependent on the metabolic activities of algal cells rather than oxidation of nitrite by dissolved oxygen. Light intensity, temperature, pH, NaHCO3 concentrations, and initial cell densities had significant effects on the rate of nitrite transformation. Single-factor experiments revealed that the optimum conditions for nitrite transformation were light intensity: 300 μmol/m2/s; temperature: 30℃ pH: 7-8; NaHCO3 concentration: 2.0 g/l; and initial cell density: 0.15 g/l; and the highest nitrite transformation rate of 1.36 mmol/l/d was achieved. There was a positive correlation between nitrite transformation rate and the growth of Chlorella. The relationship between nitrite transformation rate (mg/l/d) and biomass productivity (g/l/d) could be described by the regression equation y = 61.3x (R2 = 0.9665), meaning that 61.3 mg N element was assimilated by 1.0 g dry biomass on average, which indicated that the nitrite transformation is a process of consuming nitrite as nitrogen source by Chlorella. The results demonstrated that the Chlorella suspension was able to assimilate nitrite efficiently, which implied the feasibility of using flue gas for mass production of Chlorella without preliminary removal of NOX.

Cold Rolling and Heat Treatment Characteristics of TiNi Based Shape Memory Wire (TiNi계 형상기억합금 선재의 냉간압연 및 열처리 특성)

  • Kim, R.H.;Kim, H.S.;Jang, W.Y.
    • Journal of the Korean Society for Heat Treatment
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    • v.30 no.6
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    • pp.251-257
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    • 2017
  • The effect of annealing temperature on the martensitic transformation behavior, tensile deformation chracteristics and shape recovery etc., has been studied in TiNi based shape memory ribbon fabricated by coldrolling of wire. TiNi based shape memory wire (${\phi}=500{\mu}m$) of which structure is intermetallic compound could be cold-rolled without process annealing up to the reduction rate in thickness of 50%, but a few cracks appear in cold-rolled ribbon in the reduction rate in thickness of 65%. The $B2{\rightarrow}R{\rightarrow}B19^{\prime}$ martensitic transformation or $B2{\rightarrow}B19^{\prime}$ martensitic transformation occurs in annealing conditions dissipating lattice defects introduced by coldrolling. However, in case of higher reduction rate or lower annealing temperature, martensitic transformation in cold-rolled and then annealed ribbons does not occur. The maximum shape recovery rate of cold-rolled ribbons with the reduction rate of 35 and 65% could be achieved at annealing temperatures of 250 and $350^{\circ}C$, respectively. The shape recovery rate seems to be related to the stress level of plateau region on stress-strain curve.

The Latent Heat of Phase Transformation of the Carbon Steel and the Calculation of Cooling Curves Including the Latent Heat in Quenching (탄소강 담금질시의 상변태열과 이를 포함한 냉각곡선의 계산)

  • 윤석훈;김경근
    • Journal of Advanced Marine Engineering and Technology
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    • v.18 no.3
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    • pp.10-16
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    • 1994
  • This study aimed at measuring the latent heat of phase transformation of S45C carbon steel in quenching and at conducting the analytical researches into the calculation of cooling curves including the latent heat. The temperature of phase transformation of steel and its latent heat are dependant upon the cooling rates at the temperature of A1 phase transformation point. The effect of the latent heat of phase transformation is especially manifest at the cooling curve of center of specimens. The higher the cooling rates became, the lower fell the temperature region of phase transformation. In the figures of cooling rates, the phenomena of cooling rate dropping into zero was caused by the latent heat of phase transformation.

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Prediction Model for the Microstructure and Properties in Weld Heat Affected Zone: V. Prediction Model for the Phase Transformation Considering the Influence of Prior Austenite Grain Size and Cooling Rate in Weld HAZ of Low Alloyed Steel (용접 열영향부 미세조직 및 재질 예측 모델링: V. 저합금강의 초기 오스테나이트 결정립크기 및 냉각 속도의 영향을 고려한 용접 열영향부 상변태 모델)

  • Kim, Sang-Hoon;Moon, Joon-Oh;Lee, Yoon-Ki;Jeong, Hong-Chul;Lee, Chang-Hee
    • Journal of Welding and Joining
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    • v.28 no.3
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    • pp.104-113
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    • 2010
  • In this study, to predict the microstructure in weld HAZ of low alloyed steel, prediction model for the phase transformation considering the influence of prior austenite grain size and cooling rate was developed. For this study, six low alloyed steels were designed and the effect of alloying elements was also investigated. In order to develop the prediction model for ferrite transformation, isothermal ferrite transformation behaviors were analyzed by dilatometer system and 'Avrami equation' which was modified to consider the effect of prior austenite grain size. After that, model for ferrite phase transformation during continuous cooling was proposed based on the isothermal ferrite transformation model through applying the 'Additivity rule'. Also, start temperatures of ferrite transformation were predicted by $A_{r3}$ considering the cooling rate. CCT diagram was calculated through this model, these results were in good agreement with the experimental results. After ferrite transformation, bainite transformation was predicted using Esaka model which corresponded most closely to the experimental results among various models. The start temperatures of bainite transformation were determined using K. J. Lee model. Phase fraction of martensite was obtained according to phase fractions of ferrite and bainite.

An efficient transformation method for a potato (Solanum tuberosum L. var. Atlantic)

  • Han, Eun-Hee;Goo, Young-Min;Lee, Min-Kyung;Lee, Shin-Woo
    • Journal of Plant Biotechnology
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    • v.42 no.2
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    • pp.77-82
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    • 2015
  • We found that a long period of in vitro culture is a critical factor on the low transformation rate for a specific potato genotype, Solanum tuberosum L. var. Atlantic when phosphinothricin (PPT) was added to select putative transformants in a solid media. The fresh explants of the newly produced plants from a micro-tuber was able to increase the transformation rate significantly while the old explants prepared from a plant maintained for longer than 6 months in vitro by sub-culturing every 3 ~ 4 weeks resulted in a very low transformation frequency. However, Jowon cultivar was not so much influenced by the period of in vitro culture with high transformation rate (higher than 10.0%). Further research need to be explored for the reason why a particular potato genotype, Atlantic is more vulnerable than the Jowon cultivar during the regeneration stage resulting in the low transformation frequency.

A study on prediction for reflecting variation of fertility rate by province under ultra-low fertility in Korea (초저출산율에 따른 시도별 출산율 변동을 반영한 예측 연구)

  • Oh, Jinho
    • The Korean Journal of Applied Statistics
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    • v.34 no.1
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    • pp.75-98
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    • 2021
  • This paper compares three statistical models that examine the relationship between national and provincespecific fertility rates. The three models are two of the regression models and a cointegration model. The regression model is by substituting Gompit transformation for the cumulative fertility rate by the average for ten years, and this model applies the raw data without transformation of the fertility data. A cointegration model can be considered when fitting the unstable time series of fertility rate in probability process. This paper proposes the following when it is intended to derive the relation of non-stationary fertility rate between the national and provinces. The cointegrated relationship between national and regional fertility rates is first derived. Furthermore, if this relationship is not significant, it is proposed to look at the national and regional fertility rate relationships with a regression model approach using raw data without transformation. Also, the regression model method of substituting Gompit transformation data resulted in an overestimation of fertility rates compared to other methods. Finally, Seoul, Busan, Daegu, Incheon, Gwangju, Daejeon and Gyeonggi province are expected to show a total fertility rate of 1.0 or less from 2025 to 2030, so an urgent and efficient policy to raise this level is needed.

Comparison of Recurrence Rates with Contour-Loop Excision of the Transformation Zone (C-LETZ) and Large Loop Excision of the Transformation Zone (LLETZ) for CIN

  • Boonlikit, Sathone;Srichongchai, Hemwadee
    • Asian Pacific Journal of Cancer Prevention
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    • v.15 no.15
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    • pp.6005-6008
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    • 2014
  • Aim: To compare recurrence rates of large loop excision of the transformation zone (LLETZ) with those of contour-loop excision of the transformation zone (C-LETZ) in the management of cervical intraepithelial neoplasia (CIN). Materials and Methods: The medical records of 177 patients treated consecutively by LLETZ and C-LETZ for CIN at Rajavithi Hospital between 2006 and 2009 were retrospectively reviewed. Results: Of the 87 women in the C-LETZ group, 2 cases (2.30%) had recurrence compared with 13 cases (14.4%) of the 90 women in the LLETZ group, the higher recurrence rate in the latter being statistically significant (p<0.05). Median times of follow up in the C-LETZ and LLETZ groups were 12 months and 14 months respectively (p>0.05). The C-LETZ group showed less intraoperative bleeding compared to the LLETZ group, but the rate of achievement of single specimens and positive margins were similar in the two groups. Conclusions: The present study demonstrated the superiority of C-LETZ over LLETZ in terms of efficacy; C-LLETZ is associated with a lower recurrence rate and also carries a smaller risk of intraoperative bleeding than LLETZ. The rotating technique still has a potential role in treating precancerous lesions of the cervix.

The Nexus Between Education and Structural Transformation: Evidence from Vietnam

  • TRUONG, Cong Bac;TRAN, Van
    • The Journal of Asian Finance, Economics and Business
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    • v.8 no.10
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    • pp.259-267
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    • 2021
  • Both structural transformation and education are the predominant subjects in the literature of development economics. This study examines the relationship between education before the tertiary level and the structural transformation of provinces by using Vietnam as a case study. In this study, education before the tertiary level would be disaggregated into three groups: primary, lower secondary, and upper secondary, then analyzed simultaneously on three-panel data models. Research data is taken from the statistical yearbook of provinces in Vietnam for 2015-2018. Research results show that education before the tertiary level plays a vital role in structural transformation. The enrolment rate of various education levels has a different influence on economic structure, and the lower secondary level has more significant effects than the upper secondary level. This reflects that participating in lower secondary is a fundamental requirement for taking some jobs in the non-agriculture sector, while upper secondary helps to upgrade the learner's abilities to respond to higher requirement jobs. The high rate of repeaters in upper secondary education will slow down the structural shift towards non-agriculture, and changing the traditional attitude about repeaters plays an essential role in improving this rate.