• 제목/요약/키워드: transformation by-products

검색결과 238건 처리시간 0.024초

외관 검사의 정확도 개선을 위한 멱함수 변환 기법 개발 (Power-Law Transformation Method Development for Accuracy Improvement of Appearance Inspection)

  • 박세혁;강수민;허경무
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2007년도 심포지엄 논문집 정보 및 제어부문
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    • pp.11-13
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    • 2007
  • The appearance inspection of various electronic products and parts has been executed by the eyesight of human. But inspection by eyesight can't bring about uniform inspection result. Because the appearance inspection result by eyesight of human is changed by condition of physical and spirit of the checker. So machine vision inspection system is currently used to many appearance inspection fields instead of the checker. However the inspection result of machine vision is changed by the illumination of workplace. Therefore we have used a power-law transformation in this paper. for improvement of vision inspection accuracy and could increase inspection accuracy of vision system. Also this system has been developed only using PC, CCD Camera and Visual C++ for universal workplace.

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Comparison of TiO2 and ZnO catalysts for heterogenous photocatalytic removal of vancomycin B

  • Lofrano, Giusy;Ozkal, Can Burak;Carotenuto, Maurizio;Meric, Sureyya
    • Advances in environmental research
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    • 제7권3호
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    • pp.213-223
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    • 2018
  • Continuous input into the aquatic ecosystem and persistent structures have created concern of antibiotics, primarily due to the potential for the development of antimicrobial resistance. Degradation kinetics and mineralization of vancomycin B (VAN-B) by photocatalysis using $TiO_2$ and ZnO nanoparticles was monitored at natural pH conditions. Photocatalysis (PC) efficiency was followed by means of UV absorbance, total organic carbon (TOC), and HPLC results to better monitor degradation of VAN-B itself. Experiments were run for two initial VAN-B concentrations ($20-50mgL^{-1}$) and using two catalysts $TiO_2$ and ZnO at different concentrations (0.1 and $0.5gL^{-1}$) in a multi-lamp batch reactor system (200 mL water volume). Furthermore, a set of toxicity tests with Daphnia magna was performed to evaluate the potential toxicity of oxidation by-products of VAN-B. Formation of intermediates such as chlorides and nitrates were monitored. A rapid VAN-B degradation was observed in ZnO-PC system (85% to 70% at 10 min), while total mineralization was observed to be relatively slower than $TiO_2-PC$ system (59% to 73% at 90 min). Treatment efficiency and mechanism of degradation directly affected the rate of transformation and by-products formation that gave rise to toxicity in the treated samples.

Ginsenoside Rg3의 함량증가를 위한 변환 기술 (Transformation Techniques for the Large Scale Production of Ginsenoside Rg3)

  • 남기열;최재을;박종대
    • 한국약용작물학회지
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    • 제21권5호
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    • pp.401-414
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    • 2013
  • Ginsenoside Rg3 (G-Rg3) contained only in red ginseng has been found to show various pharmacological effects such as an anticancer, antiangiogenetic, antimetastastic, liver protective, neuroprotective immunomodulating, vasorelaxative, antidiabetic, insulin secretion promoting and antioxidant activities. It is well known that G-Rg3 could be divided into 20(R)-Rg3 and 20(S)-Rg3 according to the hydroxyl group attached to C-20 of aglycone, whose structural characteristics show different pharmacological activities. It has been reported that G-Rg3 is metabolized to G-Rh2 and protopanaxadiol by the conditions of the gastric acid or intestinal bacteria, thereby these metabolites could be absorbed, suggesting its absolute bioavailability (2.63%) to be very low. Therefore, we reviewed the chemical, physical and biological transformation methods for the production on a large scale of G-Rg3 with various pharmacological effects. We also examined the influence of acid and heat treatment-induced potentials on for the preparation method of higher G-Rg3 content in ginseng and ginseng products. Futhermore, the microbial and enzymatic bio-conversion technologies could be more efficient in terms of high selectivity, efficiency and productivity. The present review discusses the available technologies for G-Rg3 production on a large scale using chemical and biological transformation.

Enzymatic Production of High Molecular Weight Chitooligosaccharides Using Recombinant Chitosanase from Bacillus thuringiensis BMB171

  • Kang, Lixin;Jiang, Sijing;Ma, Lixin
    • 한국미생물·생명공학회지
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    • 제46권1호
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    • pp.45-50
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    • 2018
  • The chitosanase gene (btbchito) of Bacillus thuringiensis BMB171 was cloned and heterologously expressed in the yeast Pichia pastoris. After purification, about 300 mg of recombinant chitosanase was obtained from the 1-1 culture medium with a specific activity of 240 units/mg. Results determined by the combined use of thin layer chromatography (TLC) and matrix-assisted laser desorption ionization-time of flight (MALDI-TOF) mass spectrometry (MS) showed that the chitooligosaccharides (COSs) obtained by chitosan (N-deacetylated by 70%, 80%, and 90%) hydrolysis by rBTBCHITO were comprised of oligomers, with degrees of polymerization (DP) mainly ranging from trimers to heptamers; high molecular weight chitopentaose, chitohexaose, and chitoheptaose were also produced. Hydrolysis products was also deduced using MS since the COSs (n) are complex oligosaccharides with various acetyl groups from one to two, so the non-acetyl COSs (GlcN)n and COSs with more acetyls (> 2) were not detected. The employment of this method in the production of high molecular weight COSs may be useful for various industrial and biological applications, and the activity of chitosanase has great significance in research and other applications.

PHOTOCHEMICAL TRANSFORMATION OF CARBON MONOXIDE IN AQUEOUS AMMONIA

  • Kim, Hee-Jeong;Park, Hyoung-Ryun
    • Journal of Photoscience
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    • 제6권4호
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    • pp.177-181
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    • 1999
  • The photochemical transformation of carbon monoxide in aqueous ammonia solution has been investigated at 25${\pm}$0.1$^{\circ}C$ using 184.9 nm UV light. Amination and carbonylation processes were carried out by irradiating the aqueous ammonia solution saturated with carbon monoxide, and the formation of formamide, urea, hexamethylenetetramine, formaldehyde, glyoxal and hydrazine was observed. The formation of hydrazine was affected by the presence of ammonia, and the formation of carbonyl compounds such as formaldehyde and glyoxal was influenced by the presence of carbon monoxide. The formation of formamide, urea and hexamethylenetetramine was affected by both ammonia and carbon monoxide. The initial quantum yields of the products were determined and probable mechanisms for the photochemical reaction were presented on the basis of product analysis.

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Effect of Minerals surface characteristics On Reduction Dehalogenation of chlorination solvents in water-FeS/FeS$_2$ system

  • 김성국;허재은;박세환;장현숙;박상원;홍대일
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2000년도 창립총회 및 춘계학술발표회
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    • pp.108-111
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    • 2000
  • FeS/FeS$_2$ minerals have been known to be potentially useful reductant to the removal of common organic contaminants in groundwater and soil. This research is aimed at improving our understanding of factors affecting the pathways and rates of reductive transformation of Hexachloroethane by catalytical iron minerals in natural system. Hexachloroethane is reduced by FeS/FeS$_2$ minerals under anaerobic condition to tetrachloroethylene and trichloroethylene with pentachloroethyl radical as the intermediate products. The kinetics of reductive transformations of the Hexachloroethane have been investigated in aqueous solution containing FeS, FeS$_2$. The proposed reduction mechanism for the adsorbed nitrobenzene involves the electron donor-acceptor complex as a precursor to electron transfer. The adsorbed Hexachloroethane undergo a series of electron transfer, proton transfer and dehydration to achieve complete reduction. It can be concluded that the reductive transformation reaction takes place at surface of iron-bearing minerals and is dependent on surface area and pH. Nitrobenzene reduction kinetics is affected by reductant type, surface area, pH, the surface site density, and the surface charge. FeS/FeS$_2$-mediated reductive dechlorination may be an important transformation pathway in natural systems.

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Effect of Ammonium Persulfate Concentration on Characteristics of Cellulose Nanocrystals from Oil Palm Frond

  • ZAINI, Lukmanul Hakim;FEBRIANTO, Fauzi;WISTARA, I Nyoman Jaya;N, Marwanto;MAULANA, Muhammad Iqbal;LEE, Seung Hwan;KIM, Nam Hun
    • Journal of the Korean Wood Science and Technology
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    • 제47권5호
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    • pp.597-606
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    • 2019
  • Cellulose nanocrystals (CNCs) were successfully isolated from oil palm fronds (OPFs) using different concentrations of ammonium persulfate (APS), and their characteristics were analyzed by Fourier transform infrared spectroscopy (FTIR), transmission electron microscopy (TEM), X-ray diffraction (XRD) analysis, and thermogravimetric analysis (TGA). APS oxidation effectively isolated CNCs with rod-like morphology in nanometer scale. The dimensions of the CNCs decreased with increasing APS concentration. FTIR and XRD analyses revealed that all the CNCs showed crystals in the form of cellulose I without crystal transformation occurring during APS treatment. The relative crystallinity of the CNCs increased with increasing APS concentration, whereas their thermal stability decreased. An APS concentration of 2 M was found to be optimal for isolating the CNCs.

형질전환(形質轉換)에 의한 Ti Plasmid의 Bradyrhizobium japonicum에의 도입(導入) (Introduction of Ti Plasmid into Bradyrhizobium japonicum by Spheroplast Transformation)

  • 윤한대;조무제;박찬영;이계호
    • Applied Biological Chemistry
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    • 제30권4호
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    • pp.293-299
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    • 1987
  • Bradyrhizobium japonicum ROKS 26 균주를 glycine및 Iysozyme을 처리하여 spheroplast를 형성시킨 후 Agrobacterium tumefaciens에서 분리한 Ti plasmid를 분리하여 형질전환 시키고 octopine 영양 요구성에 의하여 transformants를 분리하였다. 그 결과 Ti plasmid가 도입된 transformants의 형질전환율은 $1{\times}10^{-7}$ 정도 되었다. 얻어진 transformant의 plasmid를 조사한 결과 도입된 Ti plasmid 존재가 확인되었으며, 2차원 전기영동법으로 균체 단백질을 분석한 결과 수용세포인 Bredyrhizobium japonicum ROKS 26과 transformant간의 단백질 구성 차이도 화인되었다. 또한 transformant의 근류 형성력을 조사한 결과 본래의 근류의근류형성력을 가지고 있었으나, crown gall형성에 있어서는 Agrobacterium tumefaciens 15955에 의한 gall보다는 크기에 있어 차이가 있었다.

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Dynamic Kinetic Resolutions and Asymmetric Transformations by Enzyme-Metal Combo Catalysis

  • Kim, Mahn-Joo;Ahn, Yang-Soo;Park, Jai-Wook
    • Bulletin of the Korean Chemical Society
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    • 제26권4호
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    • pp.515-522
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    • 2005
  • Enzyme-metal combo catalysis is described as a useful methodology for the synthesis of optically active compounds. The key point of the method is the use of enzyme and metal in combination as the catalysts for the complete transformation of racemic substrates to single enantiomeric products through dynamic kinetic resolution (DKR). In this approach, enzyme acts as an enantioselective resolving catalyst and metal does as a racemizing catalyst for the efficient DKR. Three kinds of enzyme-metal combinations - lipase-ruthenium, subtilisin-ruthenium, and lipase-palladium –have been developed as the catalysts for the DKRs of racemic alcohols, esters, and amines. The scope of the combination catalysts can be extended to the asymmetric transformations of ketones, enol acetates, and ketoximes via the DKRs. In most cases studied, enzyme-metal combo catalysis provided enantiomerically-enriched products in high yields.

디지털 데이터를 이용한 목제품 및 금속제품 디자인 개발에 관한 연구 (A Study on Design Development of Wood & Metal Products Using Digital Data)

  • 윤여항;이성원
    • 한국가구학회지
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    • 제23권2호
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    • pp.110-121
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    • 2012
  • With people's recent increasing interest in good design products, wood and metal products have gained great popularity. However, it was believed that it would be necessary to have a transformation to the manufacturing method based on digital data and equipments from existing analog-based manufacturing method, in order to meet consumers' demand. This study was aimed to seek for the possibility of mass-producing wood and metal products through the research on the type, usage and development conditions of digital data and the methods of utilizing digital equipments. As for research methods, the study analyzed the concepts and types of digital data through various internet and literature reviews and suggested perpetual calendar products as the final outcome of design development using computer data. Through this, the study summarized and organized actual design development processes by stage to provide basic data that could become the foundation of research on the design of wood and metal products using digital data. Through the outcome of this project, the following effects could be expected by developing wood and metal products through digital data. First, its accurate and precise process would help mass-produce complex forms of products and reduce their defective rate. Second, the compatible production of various types of digital equipments would lead to a cost reduction. Third, the diversity of design could be pursued by overcoming technical limitations. In order to satisfy the above expectation effects, such as realization of developing and producing various wood and metal products, there should be designers' creative experimental spirits, their active information exchange and cooperation with the companies concerned.

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