• Journal of the Optical Society of Korea
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• v.19 no.6
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• pp.566-574
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• 2015

We report for the first time highly efficient trans-reflective color filters capable of demonstrating coloration in both transmission and reflection modes by taking advantage of a multilayer stack consisting of MgF₂ and TiO₂ used respectively as the low and high index materials. In order to enable such trans-reflective performance, securing an optimal stop band assuming an appropriate bandwidth within the visible regime is pivotal, which was realized by tailoring the thicknesses and the numbers of TiO₂-MgF₂ bi-layers. Three devices were designed through rigorous simulations and developed via e-beam evaporation to demonstrate vivid blue, green, and red colors in the reflection mode, and yellow, magenta, and cyan colors in the transmission mode, featuring an enhanced efficiency exceeding 90% under normal incidence. The color performance of the filters was examined by referring to the chromaticity coordinates of the transmission and reflection spectra, alongside photographed color images. The dependence of the performance on the angle of incidence was explored with respect to incident polarization, indicating that a transmission surpassing 60% could be stably maintained up to an angle of 75°. Polarization independent transfer characteristics were especially achieved for the normal incidence. The proposed devices may be readily extended to other spectral regimes by adjusting the thicknesses of the films.

• Bulletin of the Korean Chemical Society
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• v.24 no.3
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• pp.318-324
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• 2003

A time-resolved probe beam deflection (PBD) technique was employed to study the energy relaxation dynamics of photofragments produced by photodissociation of $CH_3I$ at 266 nm. Under 500 torr argon environment, experimental PBD transients revealed two energy relaxation processes; a fast relaxation process occurring within an acoustic transit time (less than 0.2 ㎲ in this study) and a slow relaxation process with the relaxation time in several tens of ㎲. The fast energy relaxation of which signal intensity depended linearly on the excitation laser power was assigned to translational-to-translational energy transfer from the photofragments to the medium. As for the slow process, the signal intensity depended on square of the excitation laser power, and the relaxation time decreased as the photofragment concentration increased. Based on experimental findings and reaction rate constants reported previously, the slow process was assigned to methyl radical recombination reaction. In order to determine the rate constant for methyl radical recombination reaction, a theoretical equation of the PBD transient for a radical recombination reaction was derived and used to fit the experimental results. By comparing the experimental PBD curves with the calculated ones, the rate constant for methyl recombination is determined to be $3.3({\pm}1.0)\;{\times}\;10^6\;s^{-1}torr^{-1}$ at 295 ± 2 K in 500 torr Ar.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.02a
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• pp.403-404
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• 2013

최근 scaling down의 한계에 부딪힌 DRAM과 Flash Memory를 대체하기 위한 차세대 메모리(Next Generation Memory)에 대한 연구가 활발히 진행되고 있다. ITRS (international technology roadmap for semiconductors)에 따르면 PRAM (phase change RAM), RRAM (resistive RAM), STT-MRAM (spin transfer torque magnetic RAM) 등이 차세대 메모리로써 부상하고 있다. 그 중 RRAM은 간단한 구조로 인한 고집적화, 빠른 program/erase 속도 (100~10 ns), 낮은 동작 전압 등의 장점을 갖고 있어 다른 차세대 메모리 중에서도 높은 평가를 받고 있다 [1]. 현재 RRAM은 주로 금속-산화물계(Metal-Oxide) 저항 변화 물질을 기반으로 연구가 활발하게 진행되고 있다. 하지만 근본적으로 공정 과정에서 산소에 의한 오염으로 인해 수율이 낮은 문제를 갖고 있으며, Endurance 및 Retention 등의 신뢰성이 떨어지는 단점이 있다. 따라서, 본 연구진은 산소 오염에 의한 신뢰성 문제를 근본적으로 해결할 수 있는 다양한 금속-질화물(Metal-Nitride) 기반의 저항 변화 물질을 제안해 연구를 진행하고 있으며, 우수한 열적 안정성($>450^{\circ}C$, 높은 종횡비, Cu 확산 방지 역할, 높은 공정 호환성 [2] 등의 장점을 가진 WN 박막을 저항 변화 물질로 사용하여 저항 변화 메모리를 구현하기 위한 연구를 진행하였다. WN 박막은 RF magnetron sputtering 방법을 사용하여 Ar/$N_2$ 가스를 20/30 sccm, 동작 압력 20 mTorr 조건에서 120 nm 의 두께로 증착하였고, E-beam Evaporation 방법을 통하여 Ti 상부 전극을 100 nm 증착하였다. I-V 실험결과, WN 기반의 RRAM은 양전압에서 SET 동작이 일어나며, 음전압에서 RESET 동작을 하는 bipolar 스위칭 특성을 보였으며, 읽기 전압 0.1 V에서 ~1 order의 저항비를 확보하였다. 신뢰성 분석 결과, $10^3$번의 Endurance 특성 및 $10^5$초의 긴 Retention time을 확보할 수 있었다. 또한, 고저항 상태에서는 Space-charge-limited Conduction, 저저항 상태에서는 Ohmic Conduction의 전도 특성을 보임에 따라 저항 변화 메카니즘이 filamentary conduction model로 확인되었다 [3]. 본 연구에서 개발한 WN 기반의 RRAM은 우수한 저항 변화 특성과 함께 높은 재료적 안정성, 그리고 기존 반도체 공정 호환성이 매우 높은 강점을 갖고 있어 핵심적인 차세대 메모리가 될 것으로 기대된다.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.02a
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• pp.658-658
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• 2013

Graphene is an attractive material for various device applications due to great electrical properties and chemical properties. However, lack of band gap is significant hurdle of graphene for future electrical device applications. In the past few years, several methods have been attempted to open and tune a band gap of graphene. For example, researchers try to fabricate graphene nanoribbon (GNR) using various templates or unzip the carbon nanotubes itself. However, these methods generate small driving currents or transconductances because of the large amount of scattering source at edge of GNRs. At 2009, Bai et al. introduced graphene nanomesh (GNM) structures which can open the band gap of large area graphene at room temperature with high current. However, this method is complex and only small area is possible. For practical applications, it needs more simple and large scale process. Herein, we introduce a photosensitive graphene device fabrication using CdSe QD coated nano-porous graphene (NPG). In our experiment, NPG was fabricated by thin film anodic aluminum oxide (AAO) film as an etching mask. First of all, we transfer the AAO on the graphene. And then, we etch the graphene using O2 reactive ion etching (RIE). Finally, we fabricate graphene device thorough photolithography process. We can control the length of NPG neckwidth from AAO pore widening time and RIE etching time. And we can increase size of NPG as large as 2 $cm^2$. Thin CdSe QD layer was deposited by spin coatingprocess. We carried out NPG structure by using field emission scanning electron microscopy (FE-SEM). And device measurements were done by Keithley 4200 SCS with 532 nm laser beam (5 mW) irradiation.

• Computers and Concrete
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• v.2 no.1
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• pp.79-96
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• 2005

The use of high-strength concrete (HSC) has significantly increased over the last decade, especially in offshore structures, long-span bridges, and tall buildings. The behavior of such concrete is noticeably different from that of normal-strength concrete (NSC) due to its different microstructure and mode of failure. In particular, the shear capacity of structural members made of HSC is a concern and must be carefully evaluated. The shear fracture surface in HSC members is usually trans-granular (propagates across coarse aggregates) and is therefore smoother than that in NSC members, which reduces the effect of shear transfer mechanisms through aggregate interlock across cracks, thus reducing the ultimate shear strength. Current code provisions for shear design are mainly based on experimental results obtained on NSC members having compressive strength of up to 50MPa. The validity of such methods to calculate the shear strength of HSC members is still questionable. In this study, a new approach based on artificial neural networks (ANNs) was used to predict the shear capacity of NSC and HSC beams without shear reinforcement. Shear capacities predicted by the ANN model were compared to those of five other methods commonly used in shear investigations: the ACI method, the CSA simplified method, Response 2000, Eurocode-2, and Zsutty's method. A sensitivity analysis was conducted to evaluate the ability of ANNs to capture the effect of main shear design parameters (concrete compressive strength, amount of longitudinal reinforcement, beam size, and shear span to depth ratio) on the shear capacity of reinforced NSC and HSC beams. It was found that the ANN model outperformed all other considered methods, providing more accurate results of shear capacity, and better capturing the effect of basic shear design parameters. Therefore, it offers an efficient alternative to evaluate the shear capacity of NSC and HSC members without stirrups.

• Computers and Concrete
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• v.16 no.3
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• pp.357-380
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• 2015

In this study, a simple indeterminate strut-tie model which reflects complicated characteristics of the ultimate structural behavior of continuous reinforced concrete deep beams was proposed. In addition, the load distribution ratio, defined as the fraction of applied load transferred by a vertical tie of truss load transfer mechanism, was proposed to help structural designers perform the analysis and design of continuous reinforced concrete deep beams by using the strut-tie model approaches of current design codes. In the determination of the load distribution ratio, a concept of balanced shear reinforcement ratio requiring a simultaneous failure of inclined concrete strut and vertical steel tie was introduced to ensure the ductile shear failure of reinforced concrete deep beams, and the primary design variables including the shear span-to-effective depth ratio, flexural reinforcement ratio, and compressive strength of concrete were reflected upon. To verify the appropriateness of the present study, the ultimate strength of 58 continuous reinforced concrete deep beams tested to shear failure was evaluated by the ACI 318M-11's strut-tie model approach associated with the presented indeterminate strut-tie model and load distribution ratio. The ultimate strength of the continuous deep beams was also estimated by the experimental shear equations, conventional design codes that were based on experimental and theoretical shear strength models, and current strut-tie model design codes. The validity of the proposed strut-tie model and load distribution ratio was examined through the comparison of the strength analysis results classified according to the primary design variables. The present study associated with the indeterminate strut-tie model and load distribution ratio evaluated the ultimate strength of the continuous deep beams fairly well compared with those by other approaches. In addition, the present approach reflected the effects of the primary design variables on the ultimate strength of the continuous deep beams consistently and reasonably. The present study may provide an opportunity to help structural designers conduct the rational and practical strut-tie model design of continuous deep beams.

• Journal of the Earthquake Engineering Society of Korea
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• v.10 no.3 s.49
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• pp.113-123
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• 2006

An experimental investigation on the behavior of reinforced concrete coupling beams is presented. The test variables are the span-to-depth ratio, the ratio of flexural reinforcements and the ratio of shear rebars. The distribution of arch action and truss action which compose the mechanism of shear resistance is discussed. The increase of plastic deformation after yielding transforms the shear transfer by arch action into by truss action. This study proposes the deformation model for reinforced concrete coupling beams considering the bond slip of flexural reinforcement. The strain distribution model of shear reinforcements and flexural reinforcements based on test results is presented. The yielding of flexural reinforcements determines yielding states and the ultimate states of reinforced concrete coupling beam are defined as the ultimate compressive strain of struts and the degradation of compressive strength due to principal tensile strain of struts. The flexural-shear failure mechanism determines the ultimate state of RC coupling beams. It is expected that this model can be applied to displacement-based design methods.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.20 no.6
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• pp.699-708
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• 2007

Reinforced concrete deep beams are general structural members used as transfer-girder, pile cap, foundation wall and so on. They have a complex stess formation. Generally, failure mechanisms differ from either continuous deep beams or simple supported deep beams. In continuous deep beams, a negative moment is occurred over intermediate support and the location of maximum moment coincide with high shear force. Therefore, failure usually occurs at this region. While on the other hand, in simple supported deep beam, the region of high shear coincides with the region of low moment. The web opening of deep beams for accepting a facility makes shear behaviors of deep beams more complex and gives rise to an expansion of crack around the opening and a decline of shear capacity of deep beams. Therefore, Engineers must determine a delicate reinforcement method to control a crack and increase a shear capacity. The purpose of this report is a computation of an effective reinforcement method through non-linear finite element method by means of adopting various reinforcement method as variables and a computation of shear capacity formula taking an effectiveness of reinforcement into consideration.

• Fire Science and Engineering
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• v.28 no.5
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• pp.52-57
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• 2014

When structural elements of steel framed structures are exposed to fire situations, the structural stability begins to decrease due to dislocation of substantial. The increase of the beam length causes an additional stress and deflection. These can be serious factors to cause a severe failure of structures. To improve the fire resistance of beams, prevention of the heat from a fire by coating with fire protection material is essential for beams. The FR 490 was developed to enhance fire resistance compared with SM 490 steel. However, the fire resistance of FR 490 H-beams has not been evaluated by analysis method since it was developed. In this paper, materials properties in high temperature and a heat transfer and thermal stress theory were used in the evaluation of the fire resistance of FR490 H-beams. The fire resistance of FR490 steel beams was compared with that of SM490 beams. The comparison verified that the structural stability of FR490 beams at high temperature was superior to that of SM490 beams.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.21 no.11
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• pp.968-972
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• 2008

Ni/Ti/Al multilayer system ('/'denotes the deposition sequence) was tested for low-resistance ohmic contact formation to Al-implanted p-type 4H-SiC. Ni 30 nm / Ti 50 nm / Al 300 nm layers were sequentially deposited by e-beam evaporation on the 4H-SiC samples which were implanted with Al (norminal doping concentration = $4\times10^{19}cm^{-3}$) and then annealed at $1700^{\circ}C$ for dopant activation. Rapid thermal anneal (RTA) temperature for ohmic contact formation was varied in the range of $840\sim930^{\circ}C$. Specific contact resistances were extracted from the measured current vs. voltage (I-V) data of linear- and circular transfer length method (TLM) patterns. In constrast to Ni contact, Ni/Ti/Al contact shows perfectly linear I-V characteristics, and possesses much lower contact resistance of about $2\sim3\times10^{-4}\Omega{\cdot}cm^2$ even after low-temperature RTA at $840^{\circ}C$, which is about 2 orders of magnitude smaller than that of Ni contact. Therefore, it was shown that RTA temperature for ohmic contact formation can be lowered to at least $840^{\circ}C$ without significant compromise of contact resistance. X-ray diffraction (XRD) analysis indicated the existence of intermetallic compounds of Ni and Al as well as $NiSi_{1-x}$, but characteristic peaks of $Ti_{3}SiC_2$, a probable narrow-gap interfacial alloy responsible for low-resistance Ti/Al ohmic contact formation, were not detected. Therefore, Al in-diffusion into SiC surface region is considered to be the dominant mechanism of improvement in conduction behavior of Ni/Ti/Al contact.