• Title/Summary/Keyword: toxic gas

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A Study on Characteristics of Fire Temperature and Concentration of Toxic Gases while the Door Opening or Closed on Multi-layered Construction (복층건물의 출입문 개방여부에 따른 화재온도분포 및 독성가스 농도 변화특성에 관한 연구)

  • Lee, Jungyun;Kim, Jeonghun;Kim, Eungsik;Kim, Hong
    • Journal of the Korean Society of Safety
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    • v.32 no.2
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    • pp.72-77
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    • 2017
  • In S. Korea, recently, building fire accidents of residential accommodations or recreational facilities have taken place more frequently than before. Among various building constructions, Multi-layered structure, such as office-residential complex, are mostly made in S. korea. $O_2$, $CO_2$, CO, $NO_x$, $SO_x$, and HCl, these gases has toxic hazard and harmful for human body. And it is predicted that different concentration of released gases from diesel pool fire with upper and lower layer. Therefore, this study reports the fire characteristics of Multi-layered structure by analyzing the fire behavior and concentration of combustion gases of a experimental compartment via real scale fire experiment, in order to predict risks and secure safety for similar fire accidents.

A Study on Quantitative Risk Presentation of LNG Station (LNG충전시설의 위험도 표현에 관한 연구)

  • Ko, Jae-Wook;Yoo, Jin-Hwan;Kim, Bum-Su;Lee, Heon-Seok;Kim, Min-Seop
    • Journal of the Korean Institute of Gas
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    • v.13 no.1
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    • pp.61-67
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    • 2009
  • There are lots of energy facilities using gas(storage facility, compressed gas pipe, station, tank lorry) on the domestic. These major gas facilities cause major accidents associated with fire, explosion, toxic and etc. With the increased interest in reducing air pollution, supply of natural gas for gas vehicles is increasing. Thus, the number of establishments of LNG (Liquefied Natural Gas) and CNG(Compressed Natural Gas) stations is increasing as well. However, due to major gas accidents such as the fire and explosion accident of a Buchen LPG (Liquefied Petroleum Gas) station, it is difficult to establish a new station. In this research, we present quantitative risk assessment for LCNG;LNG multi-station and compare it result against individual risk criteria of HSE.

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A study on the $NO_2$ Gas Detection Characteristics of Octa(2-ethylhexyloxy)Copper-Phthalocyanine Langmuir-Blodgett films (Octa(2-ethylhexyloxy)Copper-Phthalocyanine LB막의 $NO_2$ 가스 탐지 특성에 관한 연구)

  • 임준석;김영관;김정수
    • Electrical & Electronic Materials
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    • v.10 no.5
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    • pp.419-424
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    • 1997
  • It is well known that the metallo-phthalocyanines (MPcs) are sensitive to toxic gaseous molecules such as NO$_2$ as well as are chemically and thermally stable. Therefore, lots of MPcs have been studied as the potential chemical sensor for NO$_2$gas using quartz crystal microbalance(QCM) or electrical conductivity. In this study, thin films of octa(2-ethylhexyloxy)copper-phthalocyanine were prepared by Langmuir-Blodgett method and characterized by using UV-VIS absorption spectroscopy and ellipsometry. Optimal transfer condition of LB films was investigated and preliminary results of current-voltage(I-V) characteristics of these films exposed to NO$_2$gas as a function of film thickness, temperature and concentration were discussed.

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A Comparative Study of Radiation and Gas Sterilization. (방사선항균법과 개스항균법의 비교연구)

  • 정해원;유영수
    • Journal of Environmental Health Sciences
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    • v.8 no.1
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    • pp.81-97
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    • 1982
  • Ethylene oxide gas has been used as a cold sterilant for heat-sensitive medical equipments and as a fumigant for food for more than 30 years, and it is used more widely than radiation although radiation sterilization has made significant inroads in recent years. But according to recent studies of toxicities such as mutagenicity, haemolytic effect and possible carcinogenicity of Ethylene oxide (ETO) and its two main reaction products, Ethylene chlorohydrin (ETCH) and Ethylene glycol (ETG), Environmental Protection Agency in U.S.A. has suggested some regulations on residual gas in drug products and medical devices for human use. The mutagenic activity of ETO compared with that of X-ray has an equivalency of 1 ppm/hr for ETO as compared to 20 mrad for X-ray, and one could suggest the present maximum allowable concentration for ETO (50 ppm) should be 400 times lower than the radiation standard (2.5 mrad/hr). Although radiation sterilization has advantages of simplicity of operation and complete reliability, changes of physico-chemical properties with possible formation of toxic substances may occur. It is therefore necessary to make some regulations of our own for residual toxicities orginated from each sterilization method.

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A study on the $NO_2$ Gas Detection Characteristics of Octa(2-ethylhexyloxy)copper-phthalocyanine LB Films (Octa(2-ethylhexyloxy)copper-phthalocyanine LB막의 $NO_2$ 가스 탐지 특성에 관한연구)

  • Yim, Jun-Seok;Kim, Young-Kwan;Kim, Jung-Soo
    • Proceedings of the KIEE Conference
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    • 1996.07c
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    • pp.1716-1718
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    • 1996
  • It is well known that the metallophthalocyanine (MPcs) are sensitive to toxic gaseous molecules such as $NO_2$ and also chemically and thermally stable. Therefore, lots of MPcs are studied for the potential chemical sensor for $NO_2$ gas using quartz crystal microbalance(QCM) or electrical conductivity. In this study, thin films of octa(2-ethylhexyloxy) copper-phthalocyanine were prepared by Langmuir-Blodgett method and characterized by using UV-VIS spectrascopy and ellipsometry. Transfer condition, film characterization, and preliminary results of current-voltage(I-V) characteristics of these films exposed to $NO_2$ gas as a function of film thickness will be discussed.

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A study on the NO$_2$Gas Detection chracteristics of the Octa (2-ethylhexyloxy) copper-phthalocyanine LB film (Octa (2-ethyls expel oxy) copper-phthalocyanine LB막의 NO$_2$가스 탐지 특성에 관한 연구)

  • 임준석;김영관;김정수
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1996.11a
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    • pp.121-124
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    • 1996
  • It is well known that the metallo- phthalocyanine (MPcs) are sensitive to toxic gaseous molecules such as NO$_2$and also chemically and thermally stable. Therefore, lots of MPcs have been studied for the potential chemical sensor for NO$_2$gas using quartz crystal microbalance(QCM) or electrical conductivity. In this study, thin films of octa(2-ethylhexyloxy) copper-phthalocyanine were prepared by Langmuir -Blodgett method and characterized by using UV-VIS spectroscopy and ellipsometry. Transfer condition, and characterization of LB films were investigated and preliminary results of current-voltage(I-V) characteristics of these films exposed to NO$_2$gas as a function of film thickness, temperature and temperature were discussed.

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Production of Single-Cell Protein on Petroleum Hydrocarbon (석유탄화수소를 이용한 단세포단백질의 생산에 관한 연구 3)

  • 변유량;권태완
    • Korean Journal of Microbiology
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    • v.9 no.3
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    • pp.95-102
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    • 1971
  • The growth characteristics of Candida tropicalis KIST 351 on gas oil substrate under different culture conditions were investigated and the preliminary animal feeding experiments using this yeast as a partial substitute of fish meal was also conducted. The yeast assimilates effectively n-paraffins in gas oil ranging from $C_{16}$ to $C_{16}$ with its maximum cell growth at $33^{\circ}C$ and pH 5.5 with aeration of 3 vvn and agitation of 900 rpm. The optimal concentrations of nitrogen sources, $HK_2PO_4$ and $Na_2HPO$ were 4, 2 and 0.5g/1, respectively. Ferrous sulfate, manganese sulfate and zinc sulfate showed positive effect to cell growth with the optimal range of 5-10 ppm. In the feeding experiment with 3 and 5% incorporation of the gas oil grown yeast, neither adverse effects on growth of chicks nor toxic effect were observed. Protein content of the dried cell was 58.8% and its amino acid composition compared well with other single-cell protein products and FAO reference protein.

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A Study on the Influence of the Organic Matter Contents in Soil Deposited of Chlorine Gas (염소의 토양 침적특성에 미치는 토양 내 유기물 함량의 영향)

  • Song, Bo Hee;Lee, Kyung Eun;Yim, Sang Sik;Lee, Jin Han;Jo, Young Do
    • Journal of the Korean Institute of Gas
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    • v.21 no.1
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    • pp.1-5
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    • 2017
  • In the event of toxic gas accidents, soil deposition is a main factor which has an effect on extent of the damage. In this study, it presents the influence of soil deposition properties according to the change of soil depth and the organic matter contents in soil. In this experimentation, the soil deposition device developed in Air Force Research Laboratory in USA is recreated. The tested samples of mixing soil have each value of the organic matter contents. After a variety of synthetic soil were exposed to constant Cl2 concentration, the chlorinity is measured using an anion exchange chromatography(ICS-1100) to quantify the mount of deposition. As the results, the increase of soil depth causes an decreased soil deposition and the increase of exposure time causes an increased soil deposition in surface. Also, the increase of soil deposition mainly depended on the organic matter contents in surface.

Emission Character of PCDDs/PCDFs and Precusors in the Flue Gas of the MWSI(I) (도시쓰레기 소각로 배출가스 중 다이옥신류 및 전구물질의 배출특성(I))

  • Shin, S.K.;Chung, Y.H.;Kim, S.C.;Jang, S.K.;Lee, J.I.;Lee, W.S.;Lee, J.B.;Lee, D.H.
    • Analytical Science and Technology
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    • v.12 no.1
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    • pp.61-67
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    • 1999
  • Two of municipal waste incinerators were selected as surveying facilities to research on the emission of dioxin and precusors. The sampling of flue gas and analysis was performed in the selected facilities. From the result, the emission patterns of dioxin and precusors, their relatership were examined. The toxic equivalency quantity(TEQ) of dioxin concentration was evaluated in two municipal waste incinerators. The 76.24% and 60.84% of total dioxin concentration in A and B incinerator were made up of the penta-, hexa- and hepta-chlorinated dibenzo-p-dioxin, respectively. Therefore, to reduce the dioxins in flue gas have to control the formation of furans. The chlorobenzenes and chlorophenols were analyzed in two incinerators. The 1,2,4,5-tetrachlorobenzene, penta-, and hexachlorobenzene are discharged and 2,4,6-trichlorophenol, 2,3,4,6-tetrachlorophenol and pentachlorophenol are discharged mainly in A and B municipal waste incinerators.

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Hybrid Operational Concept with Chemical Detection UAV and Stand-off Chemical Detector for Toxic Chemical Cloud Detection (화학오염운 탐지를 위한 접촉식 화학탐지기를 탑재한 무인기와 원거리 화학탐지기의 복합 운용개념 고찰)

  • Lee, Myeongjae;Chong, Eugene;Jeong, Young-Su;Lee, Jae-Hwan;Nam, Hyunwoo;Park, Myung-Kyu
    • Journal of the Korea Institute of Military Science and Technology
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    • v.23 no.3
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    • pp.302-309
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    • 2020
  • Early-detection and monitoring of toxic chemical gas cloud with chemical detector is essential for reducing the number of casualties. Conventional method for chemical detection and reconnaissance has the limitation in approaching to chemically contaminated site and prompt understanding for the situation. Stand-off detector can detect and identify the chemical gas at a long distance but it cannot know exact distance and position. Chemical detection UAV is an emerging platform for its high mobility and operation safety. In this study, we have conducted chemical gas cloud detection with the stand-off chemical detector and the chemical detection UAV. DMMP vapor was generated in the area where the cloud can be detected through the field of view(FOV) of stand-off chemical detector. Monitoring the vapor cloud with standoff detector, the chemical detection UAV moved back and forth at the area DMMP vapor being generated to detect the chemical contamination. The hybrid detection system with standoff cloud detection and point detection by chemical sensors with UAV seems to be very efficient as a new concept of chemical detection.