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Study on the Leaching Characteristics of Simulated Nuclear Waste Glass with variable Composition (핵폐기용 모의글라스의 조성변화에 따른 용출특성에 관한 연구)

  • 한호현;이승한;류수착;류봉기
    • Journal of the Korean institute of surface engineering
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    • v.28 no.5
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    • pp.259-266
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    • 1995
  • In order to manufacture an attractive waste glass for the permanent and secure disposal of high-level radioactive waste, the complex composition of the simulated nuclear waste glass PNL-7668 was simplified to a composition of sodium borosilicate glass. The substitutions of $Fe_2O_3$ and $Al_2O_3$ were added to examine on the leaching characteristics of simulated nuclear waste glass with variable composition. The leach tests for these glasses were performed according to 'MCC-1, Static Leach Test Procedure' in acid and basic solution. In this study, for the $Al_2O_3$-containing glasses, Na ion release from these glasses was higher in acid solution than in basic solution. As the content of $Fe_2O_3$ was increased in glasses, Na ion release was increased in acid solution, in spite of decrease of amount of total mass diminution.

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Development of Pareto-Optimal Technique for Generation Planning According to Environmental Characteristics in term (환경특성을 반영한 급전계획의 파레토 최적화기법 개발)

  • Lee, Buhm;Kim, Yong-ha;Choi, Sang-kyu
    • Journal of Energy Engineering
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    • v.13 no.2
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    • pp.128-132
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    • 2004
  • This paper presents a new methodology to get pareto-optimal solution for generation planning. First, we apply dynamic programming, and we can get an optimal economic dispatch considering total quantity of contamination for the specified term. Second, we developed a method which can get pareto-optimal solution. This solution is consisted of a set of optimal generation planning. As a result, decision maker can get pareto-optimal solutions, and can choose a solution. We applied this method to the test system, and showed the usefulness.

A study of Optimal Reconfiguration in Distribution Power System using Initial Operating Point (초기 운전점 선정을 통한 배전계통 최적 재구성에 관한 연구)

  • Seo, Gyu-Seok;Kim, Jung-Nyun;Baek, Young-Sik
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.56 no.3
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    • pp.451-456
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    • 2007
  • This paper presents a problem that reconfigure distribution power system using branch exchange method. Optimal reconfiguration problem calculates line loss, voltage condition about system states of all situations that become different according to line On/off status, and search for optimum composition of these. However, result is difficult to be calculated fast. Because radiated operation condition of system is satisfied using many connection and sectionalize switches in the distribution power system. Therefore, in this paper, optimization method for reducing system total loss and satisfying operating condition of radial and constraints condition of voltage is proposed using the fastest branch exchange. And optimal solution at branch exchange algorithm can be wrong estimated to local optimal solution according to initial operating state. Considering this particular, an initial operating point algorithm is added and this paper showed that optimal solution arrives at global optimal solution.

Photocatalysis Characteristics of Nano Cu/TiO2 Composite Powders Fabricated from Salt Solution (염용액으로부터 제조된 Cu/TiO2복합분말의 광촉매 특성)

  • 고봉석;안인섭;배승열;이상진
    • Journal of Powder Materials
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    • v.10 no.2
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    • pp.136-141
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    • 2003
  • In the present study, $TiO_2$ imbedded copper matrix powders have been successfully prepared from the ($CuSO_4+TiO_2+Zn$) composite salt solution. The composite $Cu/TiO_2$ powders were formed by drying the solution at $200{\sim}~400^{\circ}C$ in the hydrogen atmosphere. Photocatalytic characteristics was evaluated by detecting TOC (total organic carbon) amount with TOC analyzer (model 5000A Shimadzu Co). Phase analysis of $Cu/TiO_2$ composite powders was carried out by XRD, DSC and powder size was measured with TEM. The mean particle size of composite powders was about 100 nm and a few zinc and copper oxide phases was included. The reduction ratio of TOC amount was 60% by the composite $Cu/TiO_2$ powders under the UV irradiation for 8 hours.

An Analysis of the Relationship between Problem Characteristics and Algorithm Performance : A Case Study on 0-1 Knapsack Problems (문제 특성과 알고리듬 수행 능력 간 관계에 관한 분석 : 0-1 Knapsack 문제에 관한 사례 연구)

  • Yang Jae-Hwan;Kim Hyun-Soo
    • Journal of the Korean Operations Research and Management Science Society
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    • v.31 no.1
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    • pp.55-71
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    • 2006
  • We perform a computational study on 0-1 knapsack problems generated under explicit correlation induction. A total of 2000 100-variable test problems are solved. We use two solution methods: (1) a well known heuristic and (2) a representative branch and bound type algorithm. Two different performance measures are considered: (1) the number of nodes needed to find an optimal solution and (2) the relative error of the heuristic solution. We also examine the effect of different joint probability mass functions (pmfs) for the coefficient values on the performance of the solution procedure.

Remediation of Groundwater Contaminated with Zinc Using Permeable Reactive Barriers Containing Foundry Sands (주물사가 포함된 투수반응벽체(PRB)를 이용한 아연으로 오염된 지하수 처리기법 연구)

  • ;Benson, Craig H
    • Journal of the Korean Geotechnical Society
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    • v.18 no.5
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    • pp.159-167
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    • 2002
  • Partition coefficients for zinc vary on a broad range depending on properties of the foundry sands (TOC, clay content, total iron content) and solution pH. Among these properties, solution pH was found to be the most important factor. Empirical equations were developed from batch tests to predict partition coefscients and rate constants as a function of foundry sand properties and solution pH. Rate constants obtained from batch (kinetic) tests and batch sorption tests were found to be comparable when the solution pHs were comparable.

Pump Performance Analyses with High Viscosity Fluids (고점성용 펌프의 성능해석)

  • Roh, Hyung-Woon;Suh, Sang-Ho;Kim, Dong-Joo;Kim, Young-Dae
    • 유체기계공업학회:학술대회논문집
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    • 2003.12a
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    • pp.367-370
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    • 2003
  • In this study the effects of fluid viscosity on the pump performances of a conventional centrifugal pump were experimentally studied. The study aimed to compare the pump characteristics for water and high viscosity fluids. The Working fluids are water, aqueous sugar solution and glycerin solution. The pump characteristics of total head and efficiency with high viscosity fluids were different. The performance curves of efficiency for the sugar and glycerin solutions were decreased up to 8.1% and 12.9% than that of water.

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Reusing Techniques of Nutrient Solution for Recycling Hydroponic Culture of Lettuce (순환식 상추 양액재배시 양액재활용 기술)

  • 이성재;서명훈;이상우;심상연;이수연
    • Journal of Bio-Environment Control
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    • v.8 no.3
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    • pp.172-182
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    • 1999
  • Leaf lettuce(Lacaug sativa L.) was cultivated in deep flow culture to investigate growth and yield in relation to different reusing method of nutrient solution after once cultivation. Five different treatments were allocated to the nutrient solutions - Control(total renewal of solution), NSS(nutrient solution supplement), U control, NSAC(nutrient solution analysis and compensation), NSAC and Humus supply(NSAC with supply of Humus). The pH of solution was kept stable below 7.0 during 4 successive culture in NSAC and NSAC and Humus supply. U was sharply declined in NSS as the number of cultivation was increased. Gmwth and yield of NSAC was similar to those of Control because nutrient elements were kept the balance to the better growth, while the lettuce grown in NSS and EC control was shown lower growth rate. In the nutrient solutions, Content of N $O_3$-N and N $H_4$-N were remarkably decreased after the cultivation in all treatments. Ca and Mg were shown to be accumulated in nutrient solution regardless of culture times and treatments. After the first culture in NSAC and Humus supply, total N and P$_2$ $O_{5}$ content in leaves were lower than any other treatments, but Ca content was higher. Those were not significant as following cultures, and no significant difference of K and Mg content were shown among the treatments.

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Effects of Earthenware Vase on Vase Life of Cut Gerbera Flowers and Microbial Multiplication (옹기 화병이 절화 거베라의 수명 및 미생물 증식에 미치는 영향)

  • Lim, Young-Hee;Oh, Wook
    • Horticultural Science & Technology
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    • v.29 no.2
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    • pp.110-115
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    • 2011
  • To examine the availability of onggi (earthenware) as a floral vase, we compared the vase life of cut gerberas (Gerbera jamesonii) with generally used vases made of glass and porcelain. After holding cut gerbera 'Honeymoon' and 'Golden Time' in vases made of glass, porcelain, and onggi containing holding solution (tap water or preservative solution), vase life, fresh weight, and water uptake of cut flowers, and total number of microbes in holding solution were collected. In onggi vase, vase life of both the cultivars was longer than the other vases and floral preservative prolonged vase life compared with tap water. Cut gerberas applied with preservative solution in onggi vase maintained their ornamental value for more than 14 days. Cumulative water uptake by cut gerberas was greatest in onggi vase, where 'Honeymoon' and 'Golden Time' absorbed water by 19.2 and 15.8 mL, respectively, for 10 days. Fresh weight of cut flowers in onggi vase was greater than those of the others, and the preservative solution delayed the reduction of fresh weight compared with tap water. Especially, onggi vase with preservative solution maintained 89% of the initial fresh weight at the 8th day of the treatments due to smooth water uptake with comparison with 71% in porcelain. Total number of microbes in the holding solution was smallest in onggi vase. At the 8th day, microbes number in onggi vase was 435 cfu/mL, that was 20-30% level of those of glass and porcelain vases. In conclusion, onggi vase inhibited microbial proliferation in holding solution, maintained water uptake by cut flower, and delayed bending of flower stalks due to vascular blockage, and then prolonged vase life in gerbera. Therefore, onggi with numerous micropores will be a good material for flower vase and preservative solution can improve its function.

Determination of Bi Impurity in Lead Stock Standard Solutions by Hydride-generation Inductively Coupled Plasma Mass Spectrometry

  • Park, Chang J.
    • Bulletin of the Korean Chemical Society
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    • v.25 no.2
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    • pp.233-236
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    • 2004
  • Total impurity analysis of a primary standard solution is one of the essential procedures to determine an accurate concentration of the standard solution by the gravimetry. Bi impurity is determined in Pb standard solutions by inductively coupled plasma mass spectrometry (ICP-MS). The direct nebulization of the Pb standard solution produces a significant amount of the Pb matrix-induced molecular ions which give rise to a serious spectral interference to the Bi determination. In order to avoid the spectral interference from the interferent $^{208}PbH^+$, the hydride generation method is employed for the matrix separation. The Bi hydride vapor is generated by reaction of the sample solution with 1% sodium borohydride solution. The vapor is then directed by argon carrier gas into the ICP after separation from the mixture solution in a liquid-gas separator made of a polytetrafluoroethylene membrane tube. The presence of 1000 ${\mu}$g/mL Pb matrix caused reduction of the bismuthine generation efficiency by about 40%. The standard addition method is used to overcome the chemical interference from the Pb matrix. Optimum conditions are investigated for the hydride-generation ICPMS. The detection limit of this method is 0.5 pg/mL for the sample solutions containing 1000 ${\mu}$g/mL Pb matrix.