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The New X-ray Induced Electron Emission Spectrometer

  • Yu.N.Yuryev;Park, Hyun-Min;Lee, Hwack-Ju;Kim, Ju-Hwnag;Cho, Yang-Ku;K.Yu.Pogrebitsky
    • Proceedings of the Korea Crystallographic Association Conference
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    • 2002.11a
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    • pp.5-6
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    • 2002
  • The new spectrometer for X-ray Induced Electron Emission Spectroscopy (XIEES) .has been recently developed in KRISS in collaboration with PTI (Russia). The spectrometer allows to perform research using the XAFS, SXAFS, XANES techniques (D.C.Koningsberger and R.Prins, 1988) as well as the number of techniques from XIEES field(L.A.Bakaleinikov et all, 1992). The experiments may be carried out with registration of transmitted through the sample x-rays (to investigate bulk samples) or/and total electron yield (TEY) from the sample surface that gives the high (down to several atomic mono-layers in soft x-ray region) near surface sensitivity. The combination of these methods together give the possibility to obtain a quantitative information on elemental composition, chemical state, atomic structure for powder samples and solids, including non-crystalline materials (the long range order is not required). The optical design of spectrometer is made according to Johannesson true focusing schematics and presented on the Fig.1. Five stepping motors are used to maintain the focusing condition during the photon energy scan (crystal angle, crystal position along rail, sample goniometer rail angle, sample goniometer position along rail and sample goniometer angle relatively of rail). All movements can be done independently and simultaneously that speeds up the setting of photon energy and allows the using of crystals with different Rowland radil. At present six curved crystals with different d-values and one flat synthetic multilayer are installed on revolver-type monochromator. This arrangement allows the wide range of x-rays from 100 eV up to 25 keV to be obtained. Another 4 stepping motors set exit slit width, sample angle, channeltron position and x-ray detector position. The differential pumping allows to unite vacuum chambers of spectrometer and x-ray generator avoiding the absorption of soft x-rays on Be foil of a window and in atmosphere. Another feature of vacuum system is separation of walls of vacuum chamber (which are deformed by the atmospheric pressure) from optical elements of spectrometer. This warrantees that the optical elements are precisely positioned. The detecting system of the spectrometer consists of two proportional counters, one scintillating detector and one channeltron detector. First proportional counter can be used as I/sub 0/-detector in transmission mode or by measuring the fluorescence from exit slit edge. The last installation can be used to measure the reference data (that is necessary in XANES measurements), in this case the reference sample is installed on slit knife edge. The second proportional counter measures the intensity of x-rays transmitted through the sample. The scintillating detector is used in the same way but on the air for the hard x-rays and for alignment purposes. Total electron yield from the sample is measured by channeltron. The spectrometer is fully controlled by special software that gives the high flexibility and reliability in carrying out of the experiments. Fig.2 and fig.3 present the typical XAFS spectra measured with spectrometer.

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Comparison of the Marginal and Internal Gap of Metal Coping according to Processing Method of Dental CAD/CAM System (치과 캐드캠 시스템의 가공 방식에 따른 금속 코핑의 적합도 비교)

  • Kim, Dong-Yeon;Jeon, Jin-Hun;Park, Jin-Young;Kim, Ji-Hwan;Kim, Hae-Young;Kim, Woong-Chul
    • Journal of dental hygiene science
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    • v.15 no.1
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    • pp.12-17
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    • 2015
  • The purpose of this study was to evaluate the marginal and internal gap of metal coping fabricated using additive manufacturing (AM) group and subtractive manufacturing (SM) group by dental computer-aided design (CAD)/computer-aided manufacturing (CAM) systems. Twenty same cases of stone models of abutment teeth 16 by the universal numbering system were manufactured and scanned. Ten metal copings of control group were fabricated using SM and ten metal coping of experimental group were fabricated using AM. Marginal and internal gap of copings were measured using the silicone replica technique and digital microscope (${\times}140$). The data were analyzed using IBM SPSS 21.0 Statistical Software for independent samples t-test (${\alpha}=0.05$). Mean${\pm}$ standard deviation (SD) of marginal and internal gap total size of SM group was $101.00{\pm}40.33{\mu}m$ of AM group was $83.61{\pm}40.37{\mu}m$. Mean${\pm}$SD of marginal and internal gap total size of SM group was significantly greater than that of AM group (p<0.05). This study showed that AM metal copings had a better marginal and internal gap than SM metal copings.

Analysis of Status and Trend in Software Education : Focused on Educational Technology Survey(2014 - 2016) (초·중등 SW 교육 현황 및 추이 분석 : 교육정보화 실태조사(2014-2016)을 중심으로)

  • Yoon, Ilkyu;Kim, Hansung
    • Journal of The Korean Association of Information Education
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    • v.22 no.1
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    • pp.71-80
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    • 2018
  • The purpose of this study is to analyze objectively the current state of preparation of SW education in Korea based on the survey of educational technology of elementary and secondary school which is investigated periodically every year. For this purpose, we extracted indicators related to SW education from educational technology level indicators such as human, material, and utilization and analyzed the change in the level of domestic educational technology level from 2014 to 2016. The main results of this study are as follows. Firstly, the ratio of teachers who have informatics teacher certificates among middle school informatics teacher is continuously decreasing from 2014(71%) to 2016(54%), and the number of information and the number of informatics teachers moving from informatics subject to other subjects is steadily increasing. On the other hand, there is a paradoxical situation in which the total number of teachers in informatics subject is continuously increasing for three years. Secondly, the total amount of ICT related budgets for elementary and secondary schools has been steadily decreasing since 2014. Thirdly, The ratio of informatics(computer) related creative activities in elementary schools dropped to 87.7% in 2015 and 84.6% in 2016. Also, the ratio of informatics subject operating school in middle school is gradually decreasing from 34.8% in 2014, 30.8% in 2015, and 28.2% in 2016. Based on the results of this analysis, this study suggested a method for stable settlement of SW education in elementary and secondary public education field.

PSS Movement Prediction Algorithm for Seamless hando (휴대인터넷에서 seamless handover를 위한 단말 이동 예측 알고리즘)

  • Lee, Ho-Jeong;Yun, Chan-Young;Oh, Young-Hwan
    • Journal of the Institute of Electronics Engineers of Korea TC
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    • v.43 no.12 s.354
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    • pp.53-60
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    • 2006
  • Handover of WiBro is based on 802.16e hard handover scheme. When PSS is handover, it is handover that confirm neighbor's cell condition and RAS ID in neighbor advertisement message. Serving RAS transmits HO-notification message to neighbor RAS. Transmiting HO-notification message to neighbor RAS, it occurs many signaling traffics. Also, When WiBro is handover, It occurs many packet loss. Therefore, user suffer service degradation. LPM handover is supporting seamless handover because it buffers data packets during handover. So It is proposed scheme that predicts is LPM handover and reserves target RAS with pre-authentication. These schemes occur many signaling traffics. In this paper, we propose PSS Movement Prediction to solve signaling traffic. Target RAS is decided by old data in history cache. When serving RAS receives HO-notification-RSP message to target RAS, target RAS inform to crossover node. And crossover node bicast data packet. If handover is over, target RAS forward data packet. Therefore, It reduces signaling traffics but increase handover success rate. When history cache success, It decrease about 48% total traffic. But When history cache fails, It increase about 6% total traffic

Analysis of in vitro 2D-COSY on Human Brain Metabolites for Molecular Stereochemistry

  • Kim, Sang-Young;Woo, Dong-Cheol;Bang, Eun-Jung;Kim, Sang-Soo;Lim, Hyang-Sook;Choi, Chi-Bong;Choe, Bo-Young
    • Journal of the Korean Magnetic Resonance Society
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    • v.12 no.1
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    • pp.14-25
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    • 2008
  • To investigate the 3-bond connectivity of human brain metabolites by scalar coupling interaction through 2D-correlation spectroscopy (COSY) techniques using high field NMR spectroscopy. All NMR experiments were performed at 298K on Unity Inova 500 or 600 (Varian Inc.) equipped with a triple resonance probe head with z-shield gradient. Human brain metabolites were prepared with 10% $D_2O$. Two dimensional 2D COSY spectra were acquired with 4096 complex data points in $t_2$ and 128 or 256 increments in $t_1$ dimension. The spectral width was 9615.4 Hz and solvent suppression was achieved using presaturation using low power irradiation of the water resonance during 2s of relaxation delay. NMR data were processed using VNMRJ (Varian Instrument) software and all the chemical shifts were referenced to the methyl resonance of N-acetyl aspartate (NAA) peak at 2.0 ppm. Total 10 metabolites such as N-acetyl aspartate (NAA), creatine (Cr), choline (Cho), glutamine (Gln), glutamate (Glu), myo-inositol (Ins), lactate (Lac), taurine (Tau), ${\gamma}$-aminobutyricacid (GABA), alanine (Ala) were included for major target metabolites. Symmetrical 2D-COSY spectra were successfully acquired. Total 14 COSY cross peaks were observed even though there were parallel/orthogonal noisy peaks induced by water suppression. Except for Cr, all of human brain metabolites produced COSY cross peaks. The spectra of NAA methyl proton at 2.02 ppm and Glu methylene proton ($CH_2(3)$) at 2.11 ppm and Gln methylene proton ($CH_2(3)$) at 2.14 ppm were overlapped in the similar resonance frequency between 2.00 ppm and 2.15 ppm. The present study demonstrated that in vitro 2D-COSY represented the 3-bond connectivity of human brain metabolites by scalar coupling interaction. This study could aid in better understanding the interactions between human brain metabolites in vivo 2D-COSY study. Also it would be helpful to determine the molecular stereochemistry in vivo by using two-dimensional MR spectroscopy.

Finite Element Analysis of Heat Transfer Effects on Asphalt Pavement Heated by Pre-Heater Unit Used in Hot In-Place Recycling (유한요소해석을 통한 현장 가열 재활용 시공 장비의 가열판 용량에 따른 아스팔트 포장의 열전도성 평가)

  • Lee, Kang Hun;Lim, Jin Sun;Jeong, Kyu Dong;Im, Jeong Hyuk;Kwon, Soo Ahn;Kim, Yong Joo
    • International Journal of Highway Engineering
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    • v.18 no.2
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    • pp.73-82
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    • 2016
  • PURPOSES: The national highways and expressways in Korea constitute a total length of 17,951 km. Of this total length of pavement, the asphalt pavement has significantly deteriorated, having been in service for over 10 years. Currently, hot in-place recycling (HIR) is used as the rehabilitation method for the distressed asphalt pavement. The deteriorated pavement becomes over-heated, however, owing to uncontrolled heating capacity during the pre-heating process of HIR in the field. METHODS: In order to determine the appropriate heating method and capacity of the pre-heater at the HIR process, the heating temperature of asphalt pavement is numerically simulated with the finite element software ABAQUS. Furthermore, the heating transfer effects are simulated in order to determine the inner temperature as a function of the heating system (IR and wire). This temperature is ascertained at $300^{\circ}C$, $400^{\circ}C$, $500^{\circ}C$, $600^{\circ}C$, $700^{\circ}C$, and $800^{\circ}C$ from a slab asphalt specimen prepared in the laboratory. The inner temperature of this specimen is measured at the surface and five different depths (1 cm, 2 cm, 3 cm, 4 cm, and 5 cm) by using a data logger. RESULTS: The numerical simulation results of the asphalt pavement heating temperature indicate that this temperature is extremely sensitive to increases in the heating temperature. Moreover, after 10 min of heating, the pavement temperature is 36%~38% and 8%~10% of the target temperature at depths of 25 mm and 50 mm, respectively, from the surface. Therefore, in order to achieve the target temperature at a depth of 50 mm in the slab asphalt specimen, greater heating is required of the IR system compared to that of the gas. CONCLUSIONS : Numerical simulation, via the finite element method, can be readily used to analyze the appropriate heating method and theoretical basis of the HIR method. The IR system would provide the best heating method and capacity of HIR heating processes in the field.

Application of single-step genomic evaluation using social genetic effect model for growth in pig

  • Hong, Joon Ki;Kim, Young Sin;Cho, Kyu Ho;Lee, Deuk Hwan;Min, Ye Jin;Cho, Eun Seok
    • Asian-Australasian Journal of Animal Sciences
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    • v.32 no.12
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    • pp.1836-1843
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    • 2019
  • Objective: Social genetic effects (SGE) are an important genetic component for growth, group productivity, and welfare in pigs. The present study was conducted to evaluate i) the feasibility of the single-step genomic best linear unbiased prediction (ssGBLUP) approach with the inclusion of SGE in the model in pigs, and ii) the changes in the contribution of heritable SGE to the phenotypic variance with different scaling ${\omega}$ constants for genomic relationships. Methods: The dataset included performance tested growth rate records (average daily gain) from 13,166 and 21,762 pigs Landrace (LR) and Yorkshire (YS), respectively. A total of 1,041 (LR) and 964 (YS) pigs were genotyped using the Illumina PorcineSNP60 v2 BeadChip panel. With the BLUPF90 software package, genetic parameters were estimated using a modified animal model for competitive traits. Giving a fixed weight to pedigree relationships (${\tau}:1$), several weights (${\omega}_{xx}$, 0.1 to 1.0; with a 0.1 interval) were scaled with the genomic relationship for best model fit with Akaike information criterion (AIC). Results: The genetic variances and total heritability estimates ($T^2$) were mostly higher with ssGBLUP than in the pedigree-based analysis. The model AIC value increased with any level of ${\omega}$ other than 0.6 and 0.5 in LR and YS, respectively, indicating the worse fit of those models. The theoretical accuracies of direct and social breeding value were increased by decreasing ${\omega}$ in both breeds, indicating the better accuracy of ${\omega}_{0.1}$ models. Therefore, the optimal values of ${\omega}$ to minimize AIC and to increase theoretical accuracy were 0.6 in LR and 0.5 in YS. Conclusion: In conclusion, single-step ssGBLUP model fitting SGE showed significant improvement in accuracy compared with the pedigree-based analysis method; therefore, it could be implemented in a pig population for genomic selection based on SGE, especially in South Korean populations, with appropriate further adjustment of tuning parameters for relationship matrices.

A Study on the Spill-over Economic Effect Analysis of Cultural and Creative Industries in Henan Province, China (중국 허난(河南)성 문화창의산업의 경제적 파급효과 분석)

  • Zhang, Binyuan;Jia, Tingting;Bae, Ki-Hyung
    • The Journal of the Korea Contents Association
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    • v.21 no.7
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    • pp.363-373
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    • 2021
  • The purpose of this research is to analyze the Spill-over economic effect of the cultural and creative industries(CCI) in Henan Province, China. The research object is the CCI of Henan Province, which is mainly based on five sectors out of 42 industries in the industrial association table of the Statistical Bureau of Henan Province, China in 2017 (culture, sports; recreation and research sector; experimental development and integrated technical services sector; information transmission, computer services and software sector; education sector, etc), and is analyzed through secondary integration and redefinition of the CCI of Henan Province. Through the analysis of Henan Province Industry Association Table, this paper provides some enlightenment to the future direction of the cultural and creative industries. The main analysis results are as follows. The total production inducement of the CCI in Henan province is 48,848 billion yuan, and in particular, the production inducement coefficient of the industry in Henan province is 2.72809, 2.23909 (total of columns and rows), Index of the power of dispersion is 0.26325, and the index of the sensitivity of dispersion is 0.87535. Income induction coefficient is 0.55211, production tax induction coefficient is 0.09291. Because CCI of Henan Province has full development potential, the government needs to provide active support and policy support, in addition to the need for legal provisions and supervision of market management. In order to improve the innovative development of the CCI, it is necessary to develop a new model of "CCI+X".

Evaluation of Operational Options of Wastewater Treatment Using EQPS Models (EQPS 모델을 이용한 하수처리장 운전 평가)

  • Yoo, Hosik;Ahn, Seyoung
    • Journal of the Korean Society of Urban Environment
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    • v.18 no.4
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    • pp.401-408
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    • 2018
  • EQPS (Effluent Quality Prediction System, Dynamita, France) was applied to analyze the appropriateness of the design of a bioreactor in A sewage treatment plant. A sewage treatment plant was designed by setting the design concentration of the secondary clarifier effluent to total nitrogen and total phosphorus, 10 mg/L and 1.8 mg/L, respectively, in order to comply with the target water quality at the level of the hydrophilic water. The retention time of the 4-stage BNR reactor was 9.6 hours, which was 0.5 for the pre-anoxic tank, 1.0 for the anaerobic tank, 2.9 for the anoxic tank, and 5.2 hours for the aerobic tank. As a result of the modeling of the winter season, the retention time of the anaerobic tank was increased by 0.2 hours in order to satisfy the target water quality of the hydrophilic water level. The default coefficients of the one step nitrification denitrification model proposed by the software manufacturer were used to exclude distortion of the modeling results. Since the process modeling generally presents optimal conditions, the retention time of the 4-stage BNR should be increased to 9.8 hours considering the bioreactor margin. The accurate use of process modeling in the design stage of the sewage treatment plant is a way to ensure the stability of the treatment performance and efficiency after construction of the sewage treatment plant.

Comparative Analysis of Annual Tropospheric Delay by Season and Weather (계절과 날씨에 따른 연간 대류권 지연오차량 변화)

  • Lim, Soo-Hyeon;Kim, Ji-Won;Park, Jeong-Eun;Bae, Tae-Suk;Hong, Sungwook
    • Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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    • v.37 no.1
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    • pp.1-7
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    • 2019
  • In this study, we estimated the tropospheric delay of GNSS (Global Navigation Satellite System) signals during passing through the atmosphere in relation to weather and seasonal factors. For this purpose, we chose four CORS (Continuously Operating Reference Station) stations from inland (CCHJ and PYCH) and on the coast (GEOM and CHJU). A total of 48 days for each station (one set of data for each week) were downloaded from the NGII (National Geographic Information Institute) and processed it using the scientific GNSS software. The average tropospheric delays in winter are less than 2,400 mm, which is about 200 mm less than those in summer. The estimated tropospheric delay shows a similar pattern from all stations except the absolute bias in magnitude, while a large delay was observed for the station located on the coast. In addition, the delay during the day was relatively stable in winter, and the average tropospheric delay was strongly related to the orthometric height. The inland stations have tropospheric delays by the precipitation rather than humidity due to dry weather and difference in temperature. On the contrary, it was primarily caused by the humidity on the sea. The correlation between temperature and water vapor pressure is 0.9 or larger for all stations, and the tropospheric delay showed a high linear relationship with temperature. It is necessary to analyze the GNSS data with higher temporal resolution (e.g. all RINEX data of the year) to improve the stability and reliability of the correlation results.