• Economic and Environmental Geology
• /
• v.26 no.3
• /
• pp.363-370
• /
• 1993

Various sizes of dolerite sills occur in the Mungyong area, one of well-exposed areas in Okchon belt. All of previous geochemical studies concluded that chemical variations of basic rocks, so-called Sangnae-ri amphibolite, result from the fractional crystallization. The second sill, which is a well differentiated one in the Sangnae-ri area, displays systematic compositional variation associated with gradual change of grain size in vertical sections. In order to clarify the chemical variation in the sill, whether chemical composition of each part of the sill is appropriately derived from the original liquid (represented by the average composition) by addition or subtraction of initial phenocystic minerals are tested(Iwamori program, 1989). According to the calculation, it is shown that major vertical chemical variation of the sill resulted from the accumulation of phenocrysts(olivine, clinopyrxoene, plagioclase, titanomagnetite) which already existed at the time of emplacement or formed just after the emplacement.

• Resources Recycling
• /
• v.31 no.1
• /
• pp.65-77
• /
• 2022

A study was conducted in Korea on the leaching behavior and possibility of recovery of vanadium and other valuable metals from domestic vanadium titanomagnetite (VTM) by direct acid leaching. In this study, a VTM concentrate containing 0.8% V₂O₅ was used, and the ratio of magnetite to ilmenite was calculated as 1.9:1 by using the HSC program. The leaching behavior of vanadium from the VTM was similar to that of iron, and it was affected by the concentration of sulfuric acid and temperature. Further, titanium could be leached in the form of TiOSO₄ at a temperature higher than 75℃. To improve the leaching efficiency of V, Fe, and Ti in VTM, reductive sulfuric acid and oxidative sulfuric acid leaching were performed. When Na₂SO₃ was used as a reducing agent, the leaching rate of vanadium was 80% of that in that case of leaching by sulfuric acid. Similarly, the leaching rate of titanium increased from 20% to 50%. When Na₂S₂O₈ was used as an oxidation agent, most of the vanadium was leached, and the main residue found by XRD analysis was ilmenite. In studies on the possibility of recovering valuable metals, the selective extraction of metals is hardly achieved by solvent extraction from oxidation leaching solutions; however, in this study, Cyanex 923, a solvation extractant from reductive leaching solutions, could selectively extract Ti.

• Journal of the Korean earth science society
• /
• v.28 no.3
• /
• pp.324-342
• /
• 2007

This study reports petrography and geochemical characteristics of the basalt lava flows in Seongsan-Ilchulbong area, the easternpart of Jeju island, Korea, to understand the evolutionary processes of magma. Basalt lavas are classified into the Pyoseon-ri basalt and the Seongsan-ri basalt. The Pyoseon-ri basalt is dark-gray colored with many vescicles, and mainly consists of olivine, feldspar and rarely of clinopyroxene as phenocrysts. The Seongsan-ri basalt is largely aphanitic basalt and bright-gray colored, divided into two lava-flow units: lower lava flow (B1) and upper lava flow (B2) by the intercalated yellowish lapillistone and paleosol. The lavas plotted into sub-alkaline tholeiitic basalt and alkaline basalt series. The tholeiitic basalts have characteristically higher $SiO_2,\;FeO^T$, and CaO contents, but lower $TiO_2,\;K_2O,\;P_2O_5$ and other incompatible elements compared to the alkali basalts. The tholeiitic basalts have higher $SiO_2$ to the same MgO contents than the alkalic basalts. The contents of Ni, Cr, and MgO show a strong positive correlation, which indicates that low-MgO phases like plagioclase and titanomagnetite were important during the differentiation of magma. The contents of incompatible elements against that of Th show a strong positive correlation. The chondrite-nomalized REE patterns of tholeiitic and alkalic basalts are subparallel each other. LREEs contents of the former are lower than, but HREEs contents are similar to the latter. They both are similar to their K/Ba ratios. The primitive-mantle normalized spider diagram demonstrates that the contents of Ba and Th of all basaltic magma are enriched, and yet Cr, Ni are depleted. The tholeiitic and alkalic basalts may be originated from a different degree of the partial melting of the same mantle material source, and one shows a higher degree of the partial melting than the other.

• Journal of the Korean earth science society
• /
• v.21 no.5
• /
• pp.553-562
• /
• 2000

Daejeonsa basalt in the Mt. Juwang area is composed of 12 lava flows alternate with 9 peperites, and each lava and peperite has variable thickness. Globular peperites yielded in Daejeonsa basalt are mixed basalt clasts with reddish shale. Based on field description, when lava flows over unconsolidated wet shale or injectes into unconsolidated wet shale, peperites were formed at the contacts between lava and shale. Daejeonsa basalt are massive lava flows with rare vesicules: some vesicules are found in upper part of a flow unit. The basalt has mainly pseudomorphs of olivine as phenocryst, and also plagioclase and clinopyroxene phenocrysts in rocks with higher Mg-number. Matrix is mainly subophitic texture, sometimes showing ophitic and intergranular textures due to different cooling rate. Clinopyroxene is augite(Wo$_{41.6}$En$_{45.1}$Fs$_{13.3}$), and plagioclase is mostly labradorite(An$_{55.0}{\sim}_{67.7}$), but some is andesine(An$_{44.3}$) and bytownite(An$_{74.5}$). Oxide minerals are composed of titanomagnetite and ilmenite.

• Economic and Environmental Geology
• /
• v.56 no.6
• /
• pp.781-797
• /
• 2023

Recently, there has been a rapid response from mineral-demanding countries for securing critical minerals in a high tech industries. Graphite, while overwhelmingly dominated by China in production, is changing in global supply due to the exponential growth in EV battery sector, with active exploration in East Africa. Rare earth elements are essential raw materials widely used in advanced industries. Globally, there are ongoing developments in the production of REEs from three main deposit types: carbonatite, laterite, and ion-adsorption clay types. While China's production has decreased somewhat, it still maintains overwhelming dominance in this sector. Recent changes over the past few years include the rapid emergence of Myanmar and increased production in Vietnam. Nickel has been used in various chemical and metal industries for a long time, but recently, its significance in the market has been increasing, particularly in the battery sector. Worldwide, nickel deposits can be broadly classified into two types: laterite-type, which are derived from ultramafic rocks, and ultramafic hosted sulfide-type. It is predicted that the development of sulfide-type, primarily in Australia, will continue to grow, while the development of laterite-type is expected to be promoted in Indonesia. This is largely driven by the growing demand for nickel in response to the demand for lithium-ion batteries. The global lithium ores are produced in three main types: brine lake (78%), rock/mineral (19%), and clay types (3%). Rock/mineral type has a slightly higher grade compared to brine lake type, but they are less abundant. Chile, Argentina, and the United States primarily produce lithium from brine lake deposits, while Australia and China extract lithium from both brine lake and rock/mineral sources. Canada, on the other hand, exclusively produces lithium from rock/mineral type. Vanadium has traditionally been used in steel alloys, accounting for approximately 90% of its usage. However, there is a growing trend in the use for vanadium redox flow batteries, particularly for large-scale energy storage applications. The global sources of vanadium can be broadly categorized into two main types: vanadium contained in iron ore (81%) produced from mines and vanadium recovered from by-products (secondary sources, 18%). The primary source, accounting for 81%, is vanadium-iron ores, with 70% derived from vanadium slag in the steel making process and 30% from ore mined in primary sources. Intermediate vanadium oxides are manufactured from these sources. Vanadium deposits are classified into four types: vanadiferous titanomagnetite (VTM), sandstone-hosted, shale-hosted, and vanadate types. Currently, only the VTM-type ore is being produced.