• Journal of Energy Engineering
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• v.7 no.1
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• pp.73-80
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• 1998

Zinc titanate sorbents were prepared and regeneration of used sorbents for high temperature desulfurization of fuel gases was studied. Zn/Ti molar ratio of prepared sorbents was 1.5 and quartz fixed-bed reactors with 1 cm and 3 cm diameters were used. Regeneration of zinc titanate sorbents at high temperature is exothermic reaction; that brings about deterioration of sorbents. Therefore, we experimented regeneration reaction of zinc titanate sorbents for the purpose of obtaining the most suitable regeneration conditions by changing experimental parameters such as reaction temperature, oxygen concentration, flow rate and steam content. $H_2S$ and $SO_2$ breakthrough curves were obtained during desulfurization-regeneration. Also, properties of the sorbents before and after regeneration were analyzed using SEM, XRD, Hg-porosimetry and BET method. From such results, we obtained the most suitable regeneration conditions including regeneration temperature of 650$^{\circ}$C, $O_2$ content of 5% and steam content of 10% in the gas stream.

• Korean Journal of Materials Research
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• v.7 no.2
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• pp.93-101
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• 1997

Lead titanate박막을 $Pt/Ti/SiO_{2}/Si(Pt/Ti기판)와\;Pt/Ta/SiO_{2}/SiO_{2}$Si(Pt/Ta 기판) 위에서 전자 사이크로트론 공명플라즈마 화학증착법(ECR PECVD)으로 증착하였다. 증착온도, 산소유입량, MO source유입비등의 증착변수에 따른 lead titanate박막의 조성과 미세구조를 주사전자현미경(SEM), 투과전자현미경(TEM), X선 회절법(XRD)으로 조사하였다. 산소유입량이 적을 경우,Tisource와 Pb source의 산소화의 반응성 차이 때문에 Pb 농도가 부족한 화학양론비가 잘 맞는 박막이 증착되었다. Pt/ti기판은 lead titanate박막증착도중 기판의 Ti층과 Pt층의 확산으로 기판변형이 발생하는 반면, Pt/Ta기판은 기판변형이 일어나지 않았다. Pt/Ta기판에서 페롭스카이트 화학양론비를 갖는 매우 평탄한 lead titanate박막을 증착 하였는데, 산소유입량이 lead titanate박막의 결정성을 크게 지배하였다.

• Journal of the Korean Chemical Society
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• v.29 no.3
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• pp.319-327
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• 1985

The effect of titanate coupling agents on the electrical and mechanical properties of conductive poly (vinyl chloride)-nickel composite was studied as functions of filler concentration, the variation of the amount of titanate coupling agents and the type of titanate coupling agents. It was found that the electrical and mechanical properties of PVC-Ni system were improved by the treatment of titanate coupling agents, but the excessive use of titanate coupling agents influenced to give worse properties.

• The Korean Journal of Ceramics
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• v.1 no.1
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• pp.1-6
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• 1995

Submicrometer, monosized ceramic powder of $Al_2TiO_5$$Al_2O_3$ ethanolic solutions. All particles produced by sol-gel-process were amprphous, monodispersed and with a narrow particle-size distribution. Compacts fired above $1300^{\circ}C$ formed aluminium titanate. Mullite formed first at $1480^{\circ}C$. After decomposition test at $1100^{\circ}C$, and cyclic thermal decomposition test at 750-1400-$750^{\circ}C$ for 100hrs., aluminium titanate was well stablized by composition with mullite.

• Journal of the Korean Ceramic Society
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• v.22 no.6
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• pp.9-14
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• 1985

When the barium titanate is Synthesized in Solid-solid reaction the abnormal expansion occurs at about 110$0^{\circ}C$. The mixture was made of corresponding to the theoretical composition of barium titanate. The mixture was fired at various temperature from 90$0^{\circ}C$ to 130$0^{\circ}C$, After that the specimen was tested closely with XDR dilatometer and SEM. The results indicate that 1, The activation energy of barium titanate formation was 42 Kcal/mole. 2, Thermal expansion up to to 90$0^{\circ}C$ was mainly caused by $CO_2$ whereas it was mainly caused by the formation of the secondary phase above 100$0^{\circ}C$. 3. Thermal expansion was not influenced by the forming pressure up to 1000kg/$cm^2$ but it was largely influenced bythe forming pressure above 200kg/$cm^2$.

• Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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• 1999.11a
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• pp.213-218
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• 1999

Friction and wear characteristics of novolac resin-based friction materials reinforced with aramid pulp and potassium titanate were investigated by using a pad-on-disk type friction tester. Friction properties such as friction stability, surface morphology, and wear rate varied according to the relative amount of aramid pulp and potassium titanate. The friction materials reinforced with both aramid pulp and potassium titanate showed superior friction stability and wear resistance due to the formation of durable transfer layer.

• Tribology and Lubricants
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• v.15 no.4
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• pp.314-320
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• 1999

Friction and wear characteristics of phenolic resin-based friction materials reinforced with aramid pulp and potassium titanate were investigated using a pad-on-disk type friction tester. Friction characteristics such as friction stability, thermal stability, and wear rate varied according to the type of phenolic resins and the relative amount of aramid pulp and potassium titanate. The modified novolac resin-based friction materials showed better heat resistance and friction stability than those with the unmodified(straight) novolac resin. Compared with friction materials filled with potassium titanate or aramid pulp only, the friction materials reinforced with both aramid pulp and potassium titanate showed good friction stability and wear resistance. Increment of aramid pulp from 10 to 20 vol.% however, showed little difference in friction stability.

• Journal of Sensor Science and Technology
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• v.5 no.1
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• pp.9-14
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• 1996

The effect on the microwave properties was investigated for the barium titanate doped with impurity of $WO_{3}$ 0.230 mole% produced by conventional solid state reaction method. Microwave resistance, reactance and impedance of the barium titanate were measured with 2-port s-parameter method by using network analyzer, in the range of room temperature to $160^{\circ}C$ and of frequency 300 kHz to 300 MHz. And possibility of frequency sensor and temperature sensor was estimated with barium titanate doped with $WO_{3}$.

• Proceedings of the Korean Powder Metallurgy Institute Conference
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• 2006.09a
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• pp.440-441
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• 2006

Several titanate powders ($Al_2TiO_5,\;SrTiO_3$, etc.) were synthesized by an ethylene glycol solution route. Titanium isopropoxide and nitrate salts were dissolved in stoichiometric proportions in liquid-type ethylene glycol without any precipitation. The parent precursor sols were dried to porous gels, and then the gels were calcined and crystallized. All synthesized titanate powders had stable crystallization behavior at low temperature and high specific surface area after a simple ball-milling process. A three-component PZT $(Pb(Zr_{0.52}{\cdot}Ti_{0.48})O_3)$ powder was also synthesized successfully by the ethylene glycol method. In this study, the characteristics of the multi-component titanate powders by the ethylene glycol method are examined.

• Journal of the Korean Ceramic Society
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• v.40 no.1
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• pp.5-10
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• 2003

Porous barium-strontium titanate ceramics were fabricated by adding corn- or potato-starch (are referred to as starch). The effect of sintering temperature on the microstructure and electrical properties of the porous ceramics was investigated. The room-temperature electrical resistivity of the barium-strontium titanate ceramics decreased with sintering temperature. The porosity and pore size were decreased and the grain size was increased with increasing the sintering temperature. The porosity and grain size of the barium-strontium titanate ceramics with corn-starch sintered at 1300 and 1450$^{\circ}C$ were 28.5, 22.6% and 3.2, 6.2 $\mu\textrm{m}$, respectively. The average pore sizes of the barium-strontium titanate ceramics with corn-starch sintered at 1300, 1400 and 1450$^{\circ}C$ were 0.5, 0.3 and 0.2 $\mu\textrm{m}$, respectively. The decrease in the room-temperature resistivity with increasing sintering temperature is attributed mainly due to the increase of grain size and the decrease of the electrical barrier height of grain boundaries as well as the partial decrease of porosity.