• Bulletin of the Korean Chemical Society
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• v.34 no.10
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• pp.3055-3058
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• 2013

Methanesulfonic acid (MSA) was used as catalyst to remove trace organic sulfur (thiophene) from Fluid Catalytic Cracking gasoline (FCC) via alkylation with olefins. The reactions were conducted in Erlenmeyer flask equipped with a water-bath under atmospheric pressure. The influence of the temperature, the reaction time, and the mass ration of MSA were investigated. After a 60 min reaction time at 343 K, the thiophene conversion of 98.7% was obtained with a mass ration of MSA to oil of 10%. The catalyst was reused without a reactivation treatment, and the thiophene conversion reached 92.9% at the third time. The method represents an environmentally benign route to desulfur, because MSA could easily be separated from the reaction mixture via decantation and it could be reused.

• Structural Engineering and Mechanics
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• v.36 no.4
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• pp.513-527
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• 2010

This paper presents a three-dimensional finite element method based structural analysis model for structural analysis of reinforced concrete high-rise buildings during construction. The model considered the time-dependency of the structural configuration and material properties as well as the effect of the construction rate and shoring stiffness. Uniaxial compression tests of young concrete within 28 days of age were conducted to establish the time-dependent compressive stress-strain relationship of concrete, which was then used as input parameters to the structural analysis model. In-situ tests of a RC high-rise building were conducted, the results of which were used for model verification. Good agreement between the test results and model predictions was achieved. At the end, a parametric study was conducted using the verified model. The results indicated that the floor position and construction rate had significant effect on the shore load, whereas the influence of the shore removal timing and shore stiffness have much smaller. It was also found that the floors are more prone to cracking during construction than is ultimate bending failure.

• International Journal of Highway Engineering
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• v.5 no.1 s.15
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• pp.1-10
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• 2003

The objective of pavement design, just as with the design of other structures, is to obtain the most economical designs at specified levels of reliability. Methods that yield designs with different levels of reliability are undesirable, and over the course of time design approaches in the U.S. and Europe have converged toward the Load and Resistance Factor Design (LRFD) format in order to assure uniform reliability. At present the LRFD format has been implemented in concrete, steel, wood and bridge design specifications. In this paper, reliability theories are used to illustrate the development of an LRFD format for Mechanistic-Empirical (M-E) design of flexible pavements as an alternative of its reliability module. It is shown in this paper that ten candidate pavement sections designed with a reliability level using the AASHTO design guide (1986) do not have uniform structural reliability in terms of pavement mechanistic distress such as fatigue cracking and the uniform reliability can be achieved by using the LRFD format.

• Nuclear Engineering and Technology
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• v.46 no.6
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• pp.869-874
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• 2014

It was discovered in a Korean PWR that an extensive number of very short and shallow cracks in the SG tubes were undetectable by eddy current in-service-inspection because of the masking effect of sludge deposits. Axial stress corrosion cracks at the outside diameter of the steam generator tubes near the line contacts with the tube support plates are the major concern among the six identical Korean nuclear power plants having CE-type steam generators with Alloy 600 high temperature mill annealed tubes, HU3&4 and HB3~6. The tubes in HB3&4 have a less susceptible microstructure so that the onset of ODSCC was substantially delayed compared to HU3&4 whose tubes are most susceptible to ODSCC among the six units. The numbers of cracks detected by the eddy current inspection jumped drastically after the steam generators of HB4 were chemically cleaned. The purpose of the chemical cleaning was to mitigate stress corrosion cracking by removing the heavy sludge deposit, since a corrosive environment is formed in the occluded region under the sludge deposit. SGCC also enhances the detection capability of the eddy current inspection at the same time. Measurement of the size of each crack using the motorized rotating pancake coil probe indicated that the cracks in HB4 were shorter and substantially shallower than the cracks in HU3&4. It is believed that the cracks were shorter and shallower because the microstructure of the tubes in HB4 is less susceptible to ODSCC. It was readily understood from the size distribution of the cracks and the quantitative information available on the probability of detection that most cracks in HB4 had been undetected until the steam generators were chemically cleaned.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.36 no.9
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• pp.1047-1052
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• 2012

Primary water stress corrosion cracking (PWSCC) instances have been reported in the Alloy 600 reactor pressure vessel head penetration nozzle and the Alloy 82/182 dissimilar metal butt weld nozzle in several PWRs. Therefore, in-service inspection programs have been adopted worldwide to prevent failure at the weld region. If a PWSCC is observed at the dissimilar metal weld region during inspection, its structural integrity should be evaluated; however, this requires considerable time and effort, and this might lead to a decrease in the plant utilization coefficient. To prevent this, KHNP-CRI have established integrity assessment criteria and developed a computer program for the fast evaluation and judgment of PWSCC. In this paper, the results and current status of the same are presented. Through this study, criteria for the structural integrity evaluation of PWSCC have been established, and a computer program has been developed to realize technical means for the evaluation of PWSCC structural integrity.

• Advances in concrete construction
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• v.14 no.1
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• pp.45-55
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• 2022

In this article, the flexural and shear capacity of ultra-high-performance fiber-reinforced concrete beams (UHPFRC) using two kinds of rebars, including GFRP and steel rebars, are experimentally investigated. For this purpose, six UHPFRC beams (250 × 300 × 1650 mm) with three reinforcement ratios (ρ) of 0.64, 1.05, and 1.45 were constructed using 2% steel fibers by volume. Half of the specimens were made of UHPFRC reinforced with GFRP rebars, while the other half were reinforced with conventional steel rebars. All specimens were tested to failure in four-point bending. Both the load-deformation at mid-span and the failure pattern were studied. The results showed that utilizing GFRP bars increases the flexural strength of UHPFRC beams in comparison to those made of steel bars, but at the same time, it reduces the post-cracking strain hardening. Furthermore, by increasing the percentage of longitudinal bars, both the post-cracking strain hardening and load-bearing capacity increase. Comparing the experiment results with some of the available equations and provisions cited in the valid design codes reveals that some of the equations to predict the flexural strength of UHPFRC beams reinforced with conventional steel and GFRP bars are reasonably conservative, while Khalil and Tayfur model is un-conservative. This issue makes it essential to modify the presented equations in this research for predicting the flexural strength of UHPFRC beams using GFRP bars.

• Korean Chemical Engineering Research
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• v.43 no.6
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• pp.745-750
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• 2005

Naphtha cracking bottoms(NCB) oil was reformed by varying the heat treatment temperature, treatment time, and nitrogen flow rate in preparation of precursor pitch for isotropic pitch-based carbon fibers and activated carbon fibers. The reformed pitches were investigated in the yield, softening point, elementary analysis, and molecular weight distribution, and then the precursors reformed were melt spun to certify the optimum reforming conditions. The optimum precursor pitch was prepared when the NCB oil was reformed at $380^{\circ}C$, 3 h and 1.25 vvm $N_2$, and it's the softening point was around $240^{\circ}C$. The reforming resulted in product yield of 21 wt％. The C/H mole ratio of the precursor pitch increased from 1.07 to 1.34, the aromaticity increased from 0.85 to 0.88. The insolubles in benzene and quinoline were 30.0 wt％ and 1.5 wt％, respectively. The spinning temperature was about $50^{\circ}C$ higher than the softening point. The molecular weights of the precursor components were distributed from 250 to 1250, and 80％ of them were in the range of 250 to 700.

• International Journal of Highway Engineering
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• v.12 no.2
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• pp.9-16
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• 2010

Roughness is the most important factor to maintain the road performance, and affects greatly on the design life in Jointed Plain Concrete pavements. Also, the factors the evaluate pavement‘s commonality is the three method such as functionality, safety and structural performance. In evaluating function of road, representative factors is the roughness, which has been used to determine maintenance time as key standard. As research for roughness is absence in pavement design. Applied roughness-model had a low-reliability in Korea. Therefore, it is needed to develop reliable model in road roughness. In this research, uniform specific is applied to distribute them after selecting the concrete pavements. Concrete pavement is divided by sections of 238. Total length of this sections has 281km and account for 16% of total road length in korean concrete pavements for selected sections. Considering the korean roughness-model, the evaluation of roughness is performed for the freezing index, average annual rainfall, condition for the base, the amount of traffic as well as spalling(%), cracking(%), age(year) at the selected section at the selected section. Also, additional sections is selected to evaluate various age which affects on the roughness. As a result of the analysis, it showed that spalling(%), cracking(%), age(year), and the condition of the base affected road roughness. When the correlation with the road roughness was analyzed, the reliable model for road roughness was proposed, and the ratio that can explain road roughness was R2-68.8% and P value-0 which is statistically meaningful.

• Journal of Surface Science and Engineering
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• v.36 no.2
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• pp.155-160
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• 2003

The effect of the temperature, current density and deposit time on hard chromium deposition in trivalent chromium bath was investigated. Cathode current efficiency increased with increasing current density. Increasing bath temperature from $20^{\circ}C$ to $50^{\circ}C$, chromium deposits were produced in higher current density and the maximum current efficiency was increased. At the plating conditions of $40^{\circ}C$, $30A/dm\m^2$, the deposition thickness increased in proportion to increasing electrolysis time The rate is$ 90\mu\textrm{m}$/hrs. for 2 hours. Microhardness of chromium deposits increased with increasing bath temperature and decreasing current density, and it was constant with electrolysis time. All of bath conditions, microstructure of chromium deposits has nodular structure with some cracking pattern and nodule size increased with increasing deposit thickness.

• Korean Journal of Materials Research
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• v.9 no.7
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• pp.695-700
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• 1999

Effects of two-step aging treatment on the stress corrosion cracking(SCC) resistance of 7050 Al alloy were investigated by transmission electron microscopy, electrical conductivity measurement and stress corrosion facter(SCF) evaluation. It was found that η', principal hardening phase, transformed to η during over aging above maximum hardness, and SCC resistance was improved by increasing of the size and interspacing of η particles in matrix and grain boundary. The electrical conductivity increased with aging time, but SCF decreased due to the decrease of yield strength. This results mean increase of SCC resistance The optimum two-step aging condition in forged 7050 Al alloy was to be first aged at $120^{\circ}C$ for 6h and then finally aged at $175^{\circ}C$ for 12h.