• Korean Journal of Materials Research
• /
• v.28 no.6
• /
• pp.330-336
• /
• 2018

In this study, a membrane electrode assembly(MEA) composed of three electrodes(anode, cathode, and reference electrode) is designed to investigate the effects of methanol concentration on the overpotentials of anode and cathode in direct methanol fuel cells(DMFCs). Using the three-electrode cell, in-situ analyses of the overpotentials are carried out during direct methanol fuel cell operation. It is demonstrated that the three-electrode cell can work effectively in transient state operating condition as well as in steady-state condition, and the anode and cathode exhibit different overpotential curves depending on the concentration of methanol used as fuel. Therefore, from the real-time separation of the anode and cathode overpotentials, it is possible to more clearly prove the methanol crossover effect, and it is expected that in-situ analysis using the three-electrode cell will provide an opportunity to obtain more diverse results in the area of fuel cell research.

• 한국정보디스플레이학회:학술대회논문집
• /
• 2009.10a
• /
• pp.20-23
• /
• 2009

The efficacy improvement issues in a unit discharge cell have been approached from the structural considerations. The tested cell designs include (a) a coplanar type with annular auxiliary electrode buried in barrier ribs, (b) a coplanar type with split auxiliary electrodes also burred in barrier ribs and (c) a coaxial type with a floating electrode stacked on the base electrode. From spatiotemporally resolved optical images of near-IR emission taken by a gated-ICCD camera and relative VUV emission intensity estimated by laser absorption spectroscopy, the differences in the discharge and light emission performances of those three cell types have been compared and discussed.

• Journal of Microbiology and Biotechnology
• /
• v.17 no.1
• /
• pp.110-115
• /
• 2007

Electrochemically active bacteria were successfully enriched in an electrochemical cell using a positively poised working electrode. The positively poised working electrode (+0.7 V vs. Ag/AgCl) was used as an electron acceptor for enrichment and growth of electrochemically active bacteria. When activated sludge and synthetic wastewater were fed to the electrochemical cell, a gradual increase in amperometric current was observed. After a period of time in which the amperometric current was stabilized (generally 8 days), linear correlations between the amperometric signals from the electrochemical cell and added BOD (biochemical oxygen demand) concentrations were established. Cyclic voltammetry of the enriched electrode also showed prominent electrochemical activity. When the enriched electrodes were examined with electron microscopy and confocal scanning laser microscopy, a biofilm on the enriched electrode surface and bacterium-like particles were observed. These experimental results indicate that the electrochemical system in this study is a useful tool for the enrichment of an electrochemically active bacterial consortium and could be used as a novel microbial biosensor.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
• /
• 2001.05a
• /
• pp.215-219
• /
• 2001

• Macromolecular Research
• /
• v.10 no.4
• /
• pp.181-186
• /
• 2002

The displacement of carbon black to polypyrrole as a catalyst supporter in the fuel electrode of a direct methanol fuel cell was investigated. Polypyrrole was obtained as a black powder by the chemical polymerization of pyrrole with three different oxidants. The synthesized polypyrroles were pasted on carbon paper and transformed to the fuel electrodes with electrochemically deposited platinum. The prepared fuel electrode was assembled and mounted in a unit cell using a membrane and cathodic electrode film. In comparison with the carbon black fuel electrode, the performance of the unit cell was analyzed in relation to the state of the catalyst, the type of oxidant, and the morphology of the polypyrrole powder.

• The Transactions of the Korean Institute of Electrical Engineers P
• /
• v.63 no.3
• /
• pp.212-217
• /
• 2014

The electric power output characteristics of magnesium fuel cell were investigated with regard to internal resistance. A equivalent circuit with the series-connected three internal resistance was introduced to analyze of the response to change of power. The power output analysis was employed in order to investigate the effect of internal resistances for the electrolyte concentration, air electrode area, Mg electrode area and distance between the electrodes. It was confirmed that internal resistance is generated by the electrolyte, air electrode and metal electrode, then those Internal resistances had a significant effect on the power output decrease. The power output was a maximum when the load resistance maches the internal resistance of the magnesium fuel cell. The fuel efficiency was only 50% at maximum power output. Higher fuel efficiency was achieved when the load resistance is greater than the internal resistance.

• Journal of Information Display
• /
• v.3 no.2
• /
• pp.13-18
• /
• 2002

Numerical simulation is one of the most useful tools to study gas discharge phenomena that occur in alternating current plasma display panel (AC-PDP) cell. Most PDP cell simulations have been performed for two-dimensional cell, is cross-section along the address electrode. We developed a three-dimensional PDP simulator and applied it to a T-shaped electrode cell in order to show the effects of sustain electrode shape that cannot be included in two-dimensional simulation. The dependence of power consumption on electrode shape and area in the simulation showed the same trend as experiment.

• Polymer(Korea)
• /
• v.27 no.1
• /
• pp.46-51
• /
• 2003

In this work, the electrode far fuel cell was fabricated by mixing carbon blacks with activated carbon fibers (ACFs) in order to form the proper three phase distribution, and then the change of electrode in three phase distribution was investigated. Pt loading yield with ACF content and Pt particle size were determined by AAS and XRD measurements, respectively. And the pore structures, including specific surface area ($S_{BET}$), microporosity, and pore size distribution (PSD) for each electrode were systematically investigated by BET volumetric measurement. The morphology of electrode in three phase distribution was determined by SEM. As an experimental result, it was observed that Pt loading yield was not influenced on the content of ACF. While, the electrode in three phase distribution was largely improved in the case of 30% ACF addition on carbon blacks. These results were probably explained by the increase of the portion of micropores, resulting in increasing the active sites of catalyst.

• 한국정보디스플레이학회:학술대회논문집
• /
• 2008.10a
• /
• pp.404-407
• /
• 2008

Several ITO-less PDP cell structures are presented to improve luminous efficacy. The ITO-less PDP have been applied recently at actual panel manufacture. The influence of ITO-less PDP cell structure on the discharge characteristics has been investigated by using three-dimensional fluid simulation. The variations of electrode geometry parameters such as gap distance, cross bar length, and hump length are investigated for the optimization of cell design.

• Journal of Microbiology and Biotechnology
• /
• v.9 no.2
• /
• pp.127-131
• /
• 1999

Anaerobically grown cells of an Fe(III)-reducing bacterium, Shewanella putrefaciens IR-l, were electrochemically active with an apparent reduction potential of about 0.15 V against a saturated calomel electrode in the cyclic voltammetry. The bacterium did not grow fermentatively on lactate, but grew in an anode compartment of a three-electrode electrochemical cell using lactate as an electron donor and the electrode as the electron acceptor. This property was shared by a large number of Fe(III)-reducing bacterial isolates. This is the first observation of a direct electrochemical reaction by an intact bacterial cell, which is believed to be possible due to the electron carrier(s) located at the cell surface involved in the reduction of the natural water insoluble electron acceptor, Fe(III).