• Title/Summary/Keyword: thin rod

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Improving Accident Tolerance of Nuclear Fuel with Coated Mo-alloy Cladding

  • Cheng, Bo;Kim, Young-Jin;Chou, Peter
    • Nuclear Engineering and Technology
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    • v.48 no.1
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    • pp.16-25
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    • 2016
  • In severe loss of coolant accidents (LOCA), similar to those experienced at Fukushima Daiichi and Three Mile Island Unit 1, the zirconiumalloy fuel claddingmaterials are rapidlyheateddue to nuclear decay heating and rapid exothermic oxidation of zirconium with steam. This heating causes the cladding to rapidly react with steam, lose strength, burst or collapse, and generate large quantities of hydrogen gas. Although maintaining core cooling remains the highest priority in accident management, an accident tolerant fuel (ATF) design may extend coping and recovery time for operators to restore emergency power, and cooling, and achieve safe shutdown. An ATF is required to possess high resistance to steam oxidation to reduce hydrogen generation and sufficient mechanical strength to maintain fuel rod integrity and core coolability. The initiative undertaken by Electric Power Research Institute (EPRI) is to demonstrate the feasibility of developing an ATF cladding with capability to maintain its integrity in $1,200-1,500^{\circ}C$ steam for at least 24 hours. This ATF cladding utilizes thin-walled Mo-alloys coated with oxidation-resistant surface layers. The basic design consists of a thin-walled Mo alloy structural tube with a metallurgically bonded, oxidation-resistant outer layer. Two options are being investigated: a commercially available iron, chromium, and aluminum alloy with excellent high temperature oxidation resistance, and a Zr alloy with demonstratedcorrosionresistance.Asthese composite claddings will incorporate either no Zr, or thin Zr outer layers, hydrogen generation under severe LOCA conditions will be greatly reduced. Key technical challenges and uncertainties specific to Moalloy fuel cladding include: economic core design, industrial scale fabricability, radiation embrittlement, and corrosion and oxidation resistance during normal operation, transients, and severe accidents. Progress in each aspect has been made and key results are discussed in this document. In addition to assisting plants in meeting Light Water Reactor (LWR) challenges, accident-tolerant Mo-based cladding technologies are expected to be applicable for use in high-temperature helium and molten salt reactor designs, as well as nonnuclear high temperature applications.

Morphological Transitions of MOCVD-Grown ZnO Thin Films (MOCVD로 성장된 ZnO 박막의 미세구조 변화)

  • 박재영;이동주;이병택;김상섭
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.11a
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    • pp.59-59
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    • 2003
  • ZnO는 상온에서 3.37 eV의 넓은 밴드갭을 가지는 직접천이형 반도체이다. 상온에서 60 meV의 큰 엑시톤 결합에너지를 가짐으로 인해 엑시톤 재결합에 의한 강한 UV 레이저 발진효과를 기대할 수 있다. 이러한 장점을 갖는 ZnO 박막을 이용하여 광소자 등에 응용하기 위하여 양질의 ZnO 박막성장이 필수적이며, 이를 위해 MBE, MOCVD, PLD, rf magnetron sputtering 등 다양한 증착방법을 통한 연구결과가 보고되고 있다. 또한 p형 불순물인 As과 N 도핑 및 Ga과 N의 co-doping 방법 등을 통하여 p형 ZnO 박막을 제조하였음이 보고되고 있으나 재현성 문제 등으로 인해 계속적인 연구가 진행되고 있다. 본 연구에서는 MOCVD를 이용하여 A1$_2$O$_3$(0001) 기판 위에 ZnO 박막을 성장시켰다. Zn 전구체로 DEZn을 사용하였으며, 산소 source로 $O_2$를 사용하였다. 증착온도, Ⅵ/II 비율, 반응기 압력 등 MOCVD의 중요한 공정변수들의 체계적인 변화에 따른 박막성장 양상을 조사하였다. 증착 조건에 따라 ZnO 입자의 모양이 주상(column), nano-rod, nano-needle, nano-wire 등으로 급격하게 변화됨을 확인하였으며, 이러한 입자의 모양과 결정성장 방향 및 광학적 특성과의 상관관계의 해석을 시도하였다.

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Synthesis and characterization of new liquid crystalline polymer for in-cell retardation film

  • Wang, Lei;Lim, Yeong-Jin;Kang, Hoon;Choi, Min-Oh;Lee, Seung-Hee;Lee, Myong-Hoon
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.1409-1411
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    • 2006
  • A new rod-like liquid crystalline monomer having divinyl terminal groups was synthesized and polymerized by using thiol-ene UV polymerization technique. High quality thin film with good retardation value was prepared on a rubbed alignment layer without the inert gas purging. The retardation value of the resulting film was controlled by experimental conditions such as spin speed, concentration, and spin time. From the retardation value and thickness measurement, ${\bigtriangleup}n$ was calculated to be 0.169 for the resulting film having thickness of 815.1 nm.

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STRUCTURE OF A MAGNETIC DECREASE OBSERVED IN A COROTATING INTERACTION REGION

  • LEE, ENSANG;PARKS, GEORGE K.
    • Journal of The Korean Astronomical Society
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    • v.49 no.1
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    • pp.19-23
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    • 2016
  • Magnetic decreases are often observed in various regions of interplanetary space. Many studies are devoted to reveal the physical nature and generation mechanism of the magnetic decreases, but still we do not fully understand magnetic decreases. In this study, we investigate the structure of a magnetic decrease observed in a corotating interaction region using multi-spacecraft measurements. We use three spacecraft, ACE, Cluster, and Wind, which were widely separated in the x- and y-directions in the geocentric solar ecliptic (GSE) coordinates. The boundaries of the magnetic decrease are the same at the three locations and can be identified as tangential discontinuities. A notable feature is that the magnetic decrease has very large dimension, ≳ RE, along the boundary, which is much larger than the size, ~ 6 RE, along the normal direction. This suggests that the magnetic decrease has a shape of a long, thin rod or a wide slab.

Effect of applying a DC voltage on the interfacial reactions at the zirconia to copper interface (접합계면반응에 미치는 직류전원부하의 영향)

  • Kim, Sung-Jin;Kim, In-Su;Oh, Myung-Hoon;Choi, Hwan
    • Proceedings of the KWS Conference
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    • 1996.05a
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    • pp.6-9
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    • 1996
  • The Joining of copper rod and zirconia tube was carried out in Ar gas atmosphere. There are two type of the joining. The one is the reaction bond consisting of Cu and zirconia was dominated by surface reaction wi th a undetctable very thin layer. It was found that copper elements were diffused to zirconia side, but that most of Z $r^{4+}$ ions were not diffused to copper side. This result means application of a DC voltage to migrate oxygen to the copper/zirconia interface can oxidize metal at the copper /zirconia interface, and the bonding reaction between zirconia and copper oxide may occur. The other is the reaction bonding was dominated by interdiffusion with a very thick interface layer. This result means application of a DC voltage can reduce zirconia at the interface. The bonding reaction is to be an alloying between Zr and Cr.

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Preparation of Leaf Epidermal Surfaces for Microscopic Examination (균류의 프레파라아트제작의 한 방법으로서 접착제의 이용)

  • 김종진
    • Korean Journal of Microbiology
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    • v.12 no.3
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    • pp.147-148
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    • 1974
  • A small amount of Duco cement or Elmer's clear cement was dropped on a slide glass and immediately spread with a glass rod or woden stick a thin film on the surface. After approximately 1 minute a small amount of rubber cement was spread on the top of the film of Duco cement using the same method as described earlier. It was important that the rubber cement be smeared before the Duco cement dried out. These two kinds of cements must not be mixed. It was better to make the film of the rubber cement slightly thicker than the film of Duco cement. This composite film may be used up to several months after preparation. The sample leaf was placted on the slide, prepared with adhesive and the leaf surface was passed on the film with the thumb. The pressing was done so the leaf surface was completely in contact with the film. Then the leaf was peeled from the slide.

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Displacement Current Characteristics of DLPC Lipid Monolayer (DLPC 인지질 단분자막의 변위전류 특성)

  • Chai, Yang-Sung;Sang, Jin-Won;Lee, Kyung-Sup
    • Proceedings of the KIEE Conference
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    • 2006.10a
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    • pp.10-11
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    • 2006
  • The azobenzene dendrimer is one of the dendrimeric macromolecules that include the azo-group exhibiting a photochromic character. Due to the presence of the charge transfer element of the azo-group and its rod-shaped structure, these compounds are expected to have potential interest in electronics and photoelectronics, especially in nonlinear optics. In the present paper, we give pressure stimulation to organic thin films and detect the induced displacement current. Functional photoisometrization organic molecular the photo-stimulus to organic monomolecular L films and LB films of dendrimer and SASH were performed. The SASH organic monolayer in case of pressure stimulus occurred that positive course but in case of the photo-stimulus compared positive and negative. It is assumed that generation forms of displacement current were measured when photo-stimulus for impression.

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Synthesis of SnO2Microrods by the Thermal Evaporation of Sn Powders

  • Kong, Myung-Ho;Kim, Hyoun-Woo
    • Korean Journal of Materials Research
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    • v.18 no.3
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    • pp.123-127
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    • 2008
  • The production of tin oxide ($SnO_2$) microrods on iridium (Ir)-coated substrates was achieved through the thermal evaporation of Sn powders in which a sufficiently high $O_2$ partial pressure was employed. Scanning electron microscopy revealed that the product consisted of microrods with diameters that ranged from 0.9 to $40\;{\mu}m$. X-ray diffraction, high-resolution transmission electron microscopy, and selected area electron diffraction indicated that the microrods were $SnO_2$ with a rutile structure. As the microrod tips were free of metal particles, it was determined that the growth of $SnO_2$ microrods via the present route was dominated by a vapor-solid mechanism. The thickening of rod-like structures was related to the utilization of sufficiently high $O_2$ partial pressure during the synthesis process, whereas low $O_2$ partial pressure facilitated the production of thin rods.

Defects analysis of RE : YAG (RE = Nd3+, Er3+) single crystal synthesized by Czochralski method (Czochralski법으로 성장된 RE : YAG(RE = Nd3+, Er3+) 단결정의 결함분석)

  • Park, Cheong Ho;Joo, Young Jun;Kim, Hye Young;Shim, Jang Bo;Kim, Cheol Jin
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.26 no.1
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    • pp.1-7
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    • 2016
  • RE : YAG ($RE=Nd^{3+}$, $Er^{3+}$) single crystals are laser diodes and generally grown by Czochralski method with controlling the various growth parameter. Since the defects occurred by temperature gradient or the rotation speed of solid-liquid growth interface act as the decline of crystal optical property during the growth procedure, crystalline quality improvement via defects analysis is necessary. The etch pit density (EPD) analysis was used to confirm the surface defect of grown RE : YAG single crystal and to select the area of transmission electron microscopy (TEM) analysis. Defects in the specimen produced by tripod polishing method such as buckling, rod shaped, bend contours by internal stress, segregation and others were observed by using 200 kV TEM and 300 kV FE-TEM.

EFFECTS OF FLUORIDE CONCENTRATION AND SEED MATERIAL ON SEEDED CRYSTAL GROWTH (불소의 농도와 Seed Material이 Crystal Growth에 미치는 영향)

  • Oh, Seung-Yeon;Jung, Il-Young;Kum, Kee-Yeon;Lee, Chan-Young
    • Restorative Dentistry and Endodontics
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    • v.22 no.2
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    • pp.560-574
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    • 1997
  • The present study was undertaken to investigate the crystal growth onto human enamel mineral and synthetic hydroxyapatite(HA) seeds in media resembling the enamel fluid composition. Effects of fluoride at high concentrations on the precipitation were also examined in a bench-top crystal growth model adopting a miniaturized reaction column. The Ca, P and F concentrations and pH values of the inlet and outlet solutions were determined. The recovered solid samples were weighed to assess the amount of minerals precipitated during the experimental period, and finally viewed under a scanning electron microscope. Remarkable findings were that 1) both biological and synthetic seeds with the same total surface areas yielded similar amounts of crystal growth, 2) the amount of crystal growth was accelerated in a manner depending on fluoride concentrations in the media, 3) SEM observations disclosed that without the addition of fluoride, precipitation of thin, plate-like OCP crystals became prominent, but by increasing the fluoride concentration(beyond 1ppm F), rod-like crystals having a pointed edge were most frequently observed, without any evidence for precipitation of the plate-like crystals. Furthermore, the dimension of rod-like crystals was increased in proportion to fluoride concentrations, 4) there was no difference in the morphological feature of precipitated mineral phase upon seeding between human enamel seed and synthetic HA seed. The overall results support the view that the seeded crystal growth model is of value to gain insight into the mechanism of enamel crystal growth under fluoride regimens.

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