• 접착 및 계면
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• 제16권2호
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• pp.63-68
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• 2015

본 연구에서는 carboxylic acid group이 도입된 열가소성 폴리우레탄(thermoplastic polyurethane, TPU)과 동적 가교형 TPV (thermoplastic vulcanizate)계 열가소성 탄성체를 제조하였으며, 탄성체 분자구조 내 acid group의 도입에 따른 기계적 물성, 그립성, 데브리스, 접촉각 및 접착특성 변화에 대해서 평가하였다. 연구결과 acid group이 도입된 경우 수소결합의 증가로 인해 기계적 물성과 wet slip 특성이 향상되었으며, 카르복시산에 의해 표면 극성이 증가되었기 때문에 접착력 또한 향상되었다. 그리고 acid group이 도입된 TPU를 사용해서 TPV를 제조한 결과 TPU 자체에 비해 감성특성과 데브리스(debris) 특성이 향상되었다.

• Advances in materials Research
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• 제3권3호
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• pp.175-183
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• 2014

Natural rubber bound phenolic antioxidant, 2,6-di-tert-butyl-4-vinylphenol (2,6-DBVP), was prepared from natural rubber and 2,6-DBVP in both solution and melt state. The 2,6-DBVP had been synthesized from 3,5-di-tert-butyl-4-hydroxybenzaldehyde and methyltriphenylphosphonium iodide ($MePPh_3I$) by Wittig reaction ($0^{\circ}C$ for 2 hrs, $N_2$ atmosphere). The conditions for preparation of natural rubber bound 2,6-DBVP (NR-DBVP) were optimized for both solution state (1 phr BPO and 8 phr 2,6-DBVP at $70^{\circ}C$ for 2 hrs) and for melt state (1 phr BPO and 8 phr 2,6-DBVP at $70^{\circ}C$ for 10 mins, with rotor speed of 60 rpm). A thermoplastic vulcanizate was obtained using a compatibilizer, polypropylene modified with phenolic resin (PhHRJ-PP), in a closed mixer ($180^{\circ}C$ for 3 mins, rotor speed 60 rpm). The antioxidant properties of vulcanized NR-DBVP, using phenolic as the vulcanization system, were similar to NR with the conventional antioxidant BHT. In addition, the antioxidant, water leaching property of the thermoplastic vulcanizate of NR-DBVP/PP were good in comparison to a NR blend with BHT; the morphologies of these thermoplastic vulcanizates were similar.

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2007년도 춘계학술대회 논문집
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• pp.179-182
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• 2007

In recent, recycling of plastic material has became a major issue due to the landfills and environmental problem. This study investigated fluidity of thermoplastic vulcanizate(TPV), which is for automobile component parts such as weather strip in order to replace ethylene propylene rubber (EPDM). So, using the spiral flow test mold and panel cover mold, we conducted an experiment on fluidity of TPV with injection molding. As results of injection molding experiment, the recycled TPV's flow length was a little bit longer than virgin TPV and a case of panel cover, the filled weight was almost same quantity.

• 소성∙가공
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• 제16권1호
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• pp.31-35
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• 2007

Automotive weather strip should have good weather ability, sealability, durability, etc. to perform its duty as body sealing for vehicles under different harsh environments. Due to its comprehensive properties, thermoplastic vulcanizate(TPV) is widely employed in weather strip as alternative for ethylene propylene diene rubber(EPDM). In this study, the influences of the recycled TPV on the tensile strength and hardness were investigated. As results of the injection molding experiment, the recycled TPV's tensile strength and hardness were higher than the virgin TPV and recycled TPV's extension was improve. The morphology showed that recycled TPV's rubber particles became smaller than virgin TPV's rubber particles.

• 소성∙가공
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• 제16권4호
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• pp.271-275
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• 2007

These days, recycling of plastic material has become a major issue due to the landfills and environmental problem. This study investigates the fluidity of thermoplastic vulcanizate(TPV), which can be used for an automobile part such as a weather strip, in order to replace ethylene propylene rubber(EPDM). Injection molding experiments with the spiral flow test mold and panel cover mold are conducted to examine the fluidity of TPV during injection molding. It is found out that the recycled TPV's flow length is a little bit longer than the virgin TPV. However, the filling weight for a panel cover parts by a recycled TPV is almost the same as that by a virgin TPV.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2006년도 춘계학술대회 논문집
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• pp.407-408
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• 2006

Almost all injection molds have multi-cavity, which are designed with geometrically balanced runner system in order to made filling balance between cavity to cavity during injection molding. However, filling imbalance has been existed in the geometrically balanced runner system. In this study, we made an experiment and surveyed that are filling balanced variation according to molding condition with thermoplastic vulcanizate (TPV). Also, we conducted experiments in order to know the influence of filling balance for runner core pin (RC pin).

• 한국정밀공학회지
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• 제24권2호
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• pp.41-46
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• 2007

Recently, the study for filling imbalance in thermoplastic polymer has gradually been increased. However, it is hard to find the researches for filling imbalance of thermoplastic elastomer(TPE). The experiment of filling imbalance was conducted for the three kinds of thermoplastic vulcanizes(TPVs) in the mold with geometrically balanced runner system. In this experiment, the effects of the melt temperature and injection speed on the filling imbalance were investigated. To solve the filling imbalance, Runner Core pin(RC pin) in the experimental mold was adopted and it's effects was tested. In this paper, we present that the insert length of RC pin is dependent to each polymers for optimal filling balance.

• 한국기계가공학회지
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• 제5권1호
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• pp.27-32
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• 2006

Thermoplastic elastomer(TPE) has many advantages such as high flexibility, high elasticity and high elongation, etc. TPE is easily molded as plastic materials, therefore, many TPE parts are applied as home appliances and mechanical parts. However, its mechanical properties would be changed by injection molding conditions such as melt temperature, mold temperature, injection pressure and holding pressure, etc. In this study, the influences of the injection molding condition on the mechanical properties as tensile strength, hardness of thermoplastic vulcanizates(TPVs), which is one of the TPE, were investigated. By the injection molding experiment, the molding's tensile strength and hardness was influenced on the melt temperature and composition ratio of PP and EPDM. The morphology of moldings were shown by the scanning electron microscope.

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2005년도 추계학술대회 논문집
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• pp.265-268
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• 2005

Thermoplastic elastormer (TPE) has many advantages such as high flexibility, high elasticity and high elongation, etc. TPE is easily molded such as plastic materials, therefore, many TPE parts are applied as home appliances and mechanical parts. However, if TPE is once molded, its mechanical properties are changed by injection molding conditions such as melt temperature, mold temperature, injection pressure and holding pressure, etc. In this study, the influences of the injection molding condition on the mechanical properties of thermoplastic vulcanizates(TPVs), which is one of the TPE, were investigated. By the injection molding experiment, as increasing the melt temperature, the tensile strength, shrinkage and hardness decreased. By the scanning electron microscope (SEM) analyzing the TPVs' crystallization, the morphology was affected by the melt temperature.

• Design & Manufacturing
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• 제1권1호
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• pp.39-44
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• 2007

In recent, recycling of plastic material has became a major issue due to the landfills and environmental problem. This study investigated fluidity and hardness of thermoplastic vulcanizate(TPV), which is used for automobile component parts such as weather strip in order to replace ethylene propylene rubber (EPDM). So, using the spiral flow test mold, we conducted an experiment on fluidity and hardness of TPV according to injection molding conditions. As results of injection molding experiment, the recycled TPV's flow length was a little bit longer than virgin TPV and the hardness was decreased in case of using the recycled resin. Also, we investigated the morphology study by SEM photo.