• 대한화학회지
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• 제58권3호
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• pp.251-257
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• 2014

Poly(methyl acrylate)-poly(acrylonitrile) 공중합체의 응력완화 실험은 용매기를 부착한 인장 시험기를 사용하여 여러 온도의 공기 중, 증류수 용액에서 실행하였다. Eyring-Halsey 모델의 이론적인 응력완화식에 응력완화 실험 결과를 적용하여 여러 가지 유동 파라메타를 계산하였다. 비결정성 영역에서의 유동단위의 고찰을 위하여 유동 파라메타와 결정크기로부터 섬유고분자 물질의 자체확산, 홀 부피, 점성, 열역학파라메타 등을 계산하였다. 이들 시료의 유동 파라메타는 유동 단위의 홀부피, 자체확산, 유동 열역학 파라메타와 직접적인 연관을 갖는 것으로 규명되었다.

• Bulletin of the Korean Chemical Society
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• 제22권7호
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• pp.779-781
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• 2001

• 대한화학회지
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• 제10권2호
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• pp.103-108
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• 1966

The effect of temperature on the critical micelle concentration of dodecylpyridinium chloride has been determined by electrical conductance method over the range from $5^{\circ}C\;to\;50^{\circ}C$. The values of the change in heat content, ${\Delta}H_m$, and the other thermodynamic parameters have been estimated using the equation of temperature dependence on the critical micelle concentration for the same temperature range. The significance of these thermodynamic quantities and their relations to the various current theories of micelle forming processes were discussed.

• Bulletin of the Korean Chemical Society
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• 제22권6호
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• pp.641-643
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• 2001

• 대한기계학회:학술대회논문집
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• 대한기계학회 2003년도 추계학술대회
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• pp.256-260
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• 2003

A computer program to calculate thermodynamic properties of oxygen is developed. Procedures for the calculation is briefly discussed. The program calculates unknown thermodynamic properties fixing the state with two independent input properties. If input value by user is inappropriate, it displays an error message. In addition user can change units with easy. The program developed in this work can be utilized to calculate parameters required for the simulation and design of an equipment using oxygen.

• Journal of applied mathematics & informatics
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• 제26권3_4호
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• pp.519-530
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• 2008

This paper studies the multi-domain coupled system of one dimensional Arctic temperature field and establishes identification model about the thermodynamic parameters of sea ice (heat storage capacity, density and conductivity) by the so-called output least-square estimate according to the temperature data acquired by a monitor buoy installed in the Arctic ocean. By the optimal control theory, the existence and dependability of weak solution and the identifiability of identification model have been given. Moreover, necessary optimality condition is proposed. Furthermore, the optimal algorithm for the identification model is constructed. By using the optimal thermodynamic parameters of Arctic sea ice, the numerical simulation is implemented, and the numerical results of temperature distribution of Arctic sea ice are demonstrated.

• 한국주조공학회지
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• 제41권5호
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• pp.445-453
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• 2021

다양한 합금계에 대한 계산열역학은 CALPHAD 기법으로 잘 알려져있다. 실험적으로 측정된 열역학 특성들을 활용하여 각 상에 대한 Gibbs 에너지 모델 파라미터들을 구하여, 주로 실험적으로 측정되지 못한 영역에 대한 예측이나 실험 결과에 대한 열역학 해석에 활용되고 있다. 본 연구에서는 내열 주조 합금 (IN-657)이 장시간 사용 후에 일정 영역에서 파괴되는 현상의 열역학적 해석을 위해 Ni-Cr-Nb-C 사원계 시스템의 열역학 모델링을 수행하였고, Cr 함량에 따른 시스템의 안정상, 온도에 따른 상분율 및 Ni₂Cr상의 long range ordering 파라미터를 계산하였고 실험결과와 비교하였다. 계산된 열역학 물성들은 실험으로 보고된 파괴온도 영역 및 해당 영역에서 생성된 안정상에 대한 결과를 잘 설명한다. CALPHAD 기법을 통한 열역학 모델링은 다양한 주조 합금의 열역학적 거동을 해석하고 예측하는데 유용하게 사용될 수 있을 것으로 기대된다.

• 한국초전도저온공학회:학술대회논문집
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• 한국초전도저온공학회 1999년도 제1회 학술대회논문집(KIASC 1st conference 99)
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• pp.165-168
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• 1999

Thermodynamic cycle analysis has been performed for the power generation systems to utilize the cold energy of liquefied natural gas (LNG). Among many possible configurations of the cycle, the open Rankine cycle, the closed Rankine cycle, and the closed Brayton cycle are selecte for the analysis because of their practical importance. The power output per unit mass of LNG has been analytically calculated for various design parameters. The optimal conditions for the parameters to maximize the power output are presented and some of the design considerations are discussed.

• 대한화학회지
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• 제8권1호
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• pp.15-19
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• 1964

Basicities of nine dimethylanilines have been determined in 50, 70, and 90 volume % ethanol, at $25^{\circ},\;30^{\circ},\;35^{\circ},\;and\;40^{\circ}C$. Temperature coefficients were found to be independent of solvent composition, while they showed a linear correlation with basicities of the compounds. Thermodynamic parameters obtained have been used in the discussion of substituent and solvent effects in conjunction with the general equation derived in the preceding papers.

• Bulletin of the Korean Chemical Society
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• 제15권10호
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• pp.852-856
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• 1994

A series of aliphatic hydrocarbons, methane to hexane in the liquid state, are modeled with the molecular mechanical potential parameters treating all hydrogen degrees of freedom explicitly. Thermodynamic properties (heat capacities and heats of vaporization) are calculated from relatively short (20ps) molecular dynamics trajectories. The liquid state structures are also examined through various radial distribution functions. Molecular dynamics simulations reproduce experimentally measured properties within a few percent errors, thus indicate that the present set of all-hydrogen parameters is suitable for simulating macromolecular systems in bulk.