• 제목/요약/키워드: thermodynamic equations

검색결과 154건 처리시간 0.027초

다항식 형태의 증기압 상관식의 성능 평가 (Performance Evaluation of Vapor Pressure Correlations in a Polynomial Expression)

  • 박경근
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2003년도 춘계학술대회
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    • pp.1401-1406
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    • 2003
  • Performance of two vapor pressure correlation equations in a polynomial expression is compared. These are the Wagner-type equation and the Inverted form equation. The equations are fitted to correlate the data in the ASHRAE tables and from NIST Chemistry WebBook for 17 pure substances. Some observations on the exponents in the two polynomial equations are made, which results in a proposal of a new closed form vapor pressure equation. The new equation yields the accuracy comparable to that of the Wagner-type equation and better than that of the Inverted form equation.

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Fundamental thermodynamic concepts for the constitutive modeling of damaged concrete

  • 박대효;박재민;안태송
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2004년도 춘계 학술발표회 제16권1호
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    • pp.648-651
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    • 2004
  • Many damage models has been developed to express the degradation of materials. However, only minor damage model for concrete has been developed because of the heterogeneity of it unlike metals. To model the damaged behavior of concrete, this peculiarity as well as a load-induced anisotropic feature must be considered. In this paper, basic concepts of the thermodynamic theory is investigated to model the behavior of the damaged concrete in the phenomenological viewpoint. And the general constitutive relations and damage evolution equations are investigated too.

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증발기 열원으로 태양열을 이용하며 LiSCN+LiBr 수용액을 사용하는 흡수식 2중효용 난방시스템의 열역학적 해석 (Thermodynamic Analysis of a Double-Effect Absorption Heating System Using Water-LiBr-LiSCN Solution with Solar Evaporator Heating)

  • 원승호
    • 한국태양에너지학회 논문집
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    • 제25권3호
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    • pp.27-35
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    • 2005
  • In this paper, a thermodynamic analysis was performed to provide design data for a double-effect absorption heating system with water-LiBr-LiSCN mixture which utilizes solar energy as evaporator heat source. In addition, a comparative study of the water-LiBr-LiSCN mixture against the water-LiBr pair was conducted by a computer simulation. The computer simulation is based on mass, material and heat balance equations for each part of the system. Coefficients of performance and flow ratios for effects of different operating temperatures are investigated. It is found that the heating COP is higher for the water-LiBr-LiSCN mixture than for the water-LiBr pair, and FR is lower for the former.

Transport Behaviour of Electroactive Species in Ionic Compounds: A Focus on Li Diffusion through Transition Metal Oxide in Current Flowing Condition

  • Lee, Sung-Jai;Pyun, Su-Il
    • 전기화학회지
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    • 제12권1호
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    • pp.1-10
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    • 2009
  • This article reviewed transport behaviours of electroactive species in ionic compounds, focusing on chemical diffusion of Li through the transition metal oxide in a current flowing condition. For this purpose, a distinction has been first briefly made between migration and diffusion with respect to current, driving force and charge of electroactive species considered. Then, the equations for chemical diffusion are derived theoretically in open-circuit and current flowing conditions. Finally, the experimental methods such as ac impedance spectroscopy and current (potential) transient techniques are described in details for characterising chemical diffusion. In addition, the role of the thermodynamic enhancement factor in chemical diffusion is discussed.

가변속 스크롤 압축기의 운전조건의 변화에 따른 성능 해석 (Performance Analysis on the Variable Speed Scroll Compressor with Operating Conditions)

  • 박홍희;박윤철;김용찬
    • 설비공학논문집
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    • 제12권7호
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    • pp.649-658
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    • 2000
  • Thermodynamic modeling of low-pressure scroll compressor was developed by combining continuity and energy conservation equation. Suction gas heating was considered using energy balance inside the low pressure shell. Pressure, temperature and mass of refrigerant-22 as a function of orbiting angle were calculated by solving the governing equations using fourth order Rung-Kutta scheme. Motor efficiency was taken by experiments with a variation of frequency. The developed model was applied to the analysis of an inverter driven scroll compressor with a variation of frequency, pressure ratio and operating conditions. The model was verified with the experimental results at the same operating conditions. The developed model was adequate to predict performance of the inverter driven scroll compressor as a function of operating conditions. Calculated parameters from the model were discharge temperature, mass flow rate, power input, COP, and thermodynamic properties with respect to orbiting angle. To enhance the performance of a scroll compressor, it is essential to diminish leakage at low frequency level and improve the mechanical efficiency at high frequency level.

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집단 기여법에 의한 냉매의 특성인자 예측 (Estimation of characteristic parameters of refrigerants by group contribution method)

  • 김영일
    • 설비공학논문집
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    • 제11권1호
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    • pp.125-132
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    • 1999
  • Studies are being done to replace conventional refrigerants with alternatives that have low or no ozone depletion and greenhouse warming Potentials, yet possess appropriate pro perties for a refrigeration cycle. To achieve this goal, a consistent set of thermodynamic properties of the working fluid is required. A common problem with the possible alternative refrigerants is that sufficient experimental data do not exist, thus making it difficult to develp complete equations of state that can predict properties in all regions including the vapor-liquid equilibrium. One solution is the use of the generalized equation of state correlations that can predict thermodynamic properties with a minimum number of characteristic parameters. Characteristic parameters required for the generalized equation of state are, in general, critical temperature, critical pressure, critical volume and normal boiling temperature. In this study, estimation of these characteristic parameters of refrigerants by group contribution method is developed.

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이행형 토치에서의 아크 플라즈마의 물리적 거동에 관한 연구 (A study on the physical behavior of arc plasmas in transferred-type Torch)

  • 김외동;고광철;강형부
    • 대한전기학회논문지
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    • 제45권3호
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    • pp.415-425
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    • 1996
  • This study presents an analytical method of solving the behaviors of arc plasma in a nozzle constricting transferred-type torch and purposes to obtain the basic data for the design of a plasma torch, which can be obtained from the temperature, pressure, velocities and voltage distributions. We have to solve some conservation equations simultaneously and need to know the exact thermal gas properties in order to obtain the correct behaviors of arc plasma. It is also necessary to give the relevant physical or geometric boundary conditions. For the simplicity of analysis, we assumed that (a) the plasma flow is laminar, (b)the local thermodynamic equilibrium, i.e. LTE, prevails over the entire arc column region. The electrode sheath effects were neglected and the nozzle area was excluded from the analysis by assuming that the current flow into the nozzle is zero. We solved the momentum transfer equation including the self-magnetic pinch effect, and obtained the temperature distribution from the energy conservation equation. From this temperature, we could get arc voltage distribution. (author). refs., figs., tabs.

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흡수식 2중효용 시스템의 증발기 열원으로 태양열을 이용하는 LiCl 수용액 난방시스템 해석 (Analysis of Thermodynamic Design Data of Double-Effect Absorption System for Heating using LiCl-water for Evaporator Heating Source of Solar Energy)

  • 원승호
    • 한국태양에너지학회 논문집
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    • 제24권3호
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    • pp.39-46
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    • 2004
  • In this paper, thermodynamic design data for heating of double-effect absorption system using LiCl-water for evaporator heating source of sofar energy are investigated for the water-LiCl pair and a comparative study of the water-LiCl pair with the water-LiBr pair is given used for the computer simulation. The computer simulation is based on mass, material and heat balance equations for each part of the system. Coefficients of performance and flow ratios for effects of different operating temperatures are investigated. It is found that the heating COP is higher for the water -LiCl pair than for the water-LiBr pair, and FR is lower for the water-LiCl pair than for the water LiBr pair.

충격 압축에 의한 제논 가스의 이온화 특성 연구 (A Study of the Ionization Characteristics of Xenon Gas by Shock Compression)

  • 이대성;신재렬;최정열;최윤수;김형원
    • 한국군사과학기술학회지
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    • 제13권3호
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    • pp.493-502
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    • 2010
  • In this paper, the ionization characteristics of noble gases are studied numerically behind strong shock waves. As a first step, the equilibrium ionization mechanism of noble gases is modeled in wide ranges of temperature and pressure. As a next step the equilibrium ionization model is coupled with fluid dynamic equations to analyze the local thermodynamic equilibrium(LTE) ionization process at high temperature and pressure conditions behind the strong imploding shock waves. The ionization characteristics of xenon gas is studied in a wide range of test conditions with thermal radiation effects. Hence, the results give optimal conditions of maximum ionization and radiation behind the imploding shock waves.

Performance Simulation of a Ramjet Using Visual C++ Program

  • Owino, George Omollo;Kong, Chang-Duk
    • 한국추진공학회:학술대회논문집
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    • 한국추진공학회 2008년 영문 학술대회
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    • pp.499-502
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    • 2008
  • This paper presents on research findings of how Visual C++ program can be used to generate codes capable of performing ramjet engine simulation To understand the diversity and applicability of this tool an arbitrary ramjet model will be considered for which generated output values will be compared with those from a commercial program GASTURB 9 iterated under the same input parameters. Several governing thermodynamic equations will first be discussed in order that we understand the fundamental idea behind values printed out on the GUI. C++ compiler was chosen as a tool of use due to its availability, ease of use, ability to compute functions faster and uniquely possible to make a stand alone GUI executable in DOS mode. The program is developed in such a way that given the ambient flight conditions, burner exit temperature and several geometry areas the program generates its own input values used in the succeeding stations. A close resemblance of output values that define performance and thermodynamic state of the engine was realized between GASTURB 9 and using this code made from C++ compiler.

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