• Title/Summary/Keyword: thermal softening

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The Effects of a Filler with a High Coefficient of Thermal Expansion on a Sealant for High-Temperature (750 ~ 850℃) SOFCs (고온 (750 ~ 850℃) SOFC용 밀봉재의 특성에 미치는 고열팽창계수를 갖는 필러의 영향)

  • Kim, Bit Nam;Lee, Mi Jai;Hwang, Jong Hee;Lim, Tae Young;Kim, Jin Ho;Hwang, Hae Jin;Kim, Il Won;Chung, Woon Jin
    • Journal of the Korean Ceramic Society
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    • v.50 no.6
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    • pp.470-475
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    • 2013
  • In this study, we report that effects of a filler with a high coefficient of thermal expansion on a sealant for high-temperature ($750{\sim}850^{\circ}C$) SOFC. We designed a $SiO_2-BaO-ZnO-B_2O_3-Al_2O_3$ glass system with a softening temperature higher than $750^{\circ}C$. The properties of the glass system show not only low volumetric shrinking but also low swelling. The glass system did not create a crystal phase during along-term heat treatment. We fabricated a seal gasket with 0, 10, 15, and 20 wt% cristobalite added as filler materials with glass powder. The coefficient of thermal expansion of the seal gasket increased according to cristobalite content. During along-term heat treatment, the leak rate decreased by about 5% after a heat treatment in an oxidizing atmosphere at $750^{\circ}C$ for 2000 h, also decreasing by about 6% after a heat treatment in a reducing atmosphere at $750^{\circ}C$ for 1000 h.

Modification of Coal-Tar-Pitch and Carbon Fiber Properties by Polymer Additives (고분자 첨가에 의한 콜타르 핏치의 결정성 및 탄소섬유 물성 변화)

  • Kim, Jung-Dam;Yun, Jae-Min;Lim, Yun-Soo;Kim, Myung-Soo
    • Korean Journal of Materials Research
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    • v.26 no.4
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    • pp.173-181
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    • 2016
  • In order to use coal tar pitch (CTP) as a raw material for carbon fibers, it should have suitable properties such as a narrow range of softening point, suitable viscosity and uniform optical properties. In this study, raw CTP was modified by heat treatment with three types of polymer additives (PS, PET, and PVC) to make a spinnable pitch for carbon fibers. The yield, softening point, C/H ratio, insoluble yield, and meso-phase content of various modified CTPs with polymer additives were analyzed by changing the type of polymer additive and the heat treatment temperature. The purpose of this study was to compare the properties of CTPs modified by polymer addition with those of a commercial CTP. After the pitch spinning, the obtained green fibers were stabilized and carbonized. The properties of the respective fibers were analyzed to compare their uniformity, diameter change, and mechanical properties. Among three polymer additives, PS220 and PET261 pitches were found to be spinnable, but the carbon fibers from PET261 showed mechanical properties comparable with those of a commercial CTP produced by an air-blowing method (OCI284). The CTPs modified with polymer additive had higher ${\beta}$-resin fractions than the CTP with only thermal treatment indicating a beneficial effect of carbon fiber application.

Thermal Characteristics of Non-Pb Glass Frit and Electrical Characteristics with Ag Powder For High Efficiency Silicon Solar Cells (실리콘 태양전지의 고효율 특성을 위한 Ag 분말 특성 및 Non Pb계 glass frit 열특성)

  • Park, Ki Bum;Lee, Jung Woong;Yang, Seung Jin;Yun, Mi Kyoung;Park, Seong Yong
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.101.3-101.3
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    • 2010
  • Glass frit은 실리콘 태양전지의 Ag/Si contact을 위해 필수적이다. 태양전지의 고효율 특성 구현 때문에, Contact resistance(Rc)가 우수한 Pb-frit의 사용이 불가피한 상황이다. 본 연구는 기존의 Pb계를 무연화함과 동시에 동등수준의 효율을 목표로 하였다. Ag 분말 size 및 glass frit의 열적 거동 특성이 SiNx 코팅층 침투와 Ag re-crystallites에 미치는 영향에 대해 평가하였다. 6 inch 다결정 실리콘 웨이퍼를 사용하였으며, softening temperture(Sp)별로 4종의 Bi계 glass frit을 제조 하였고, 분말 size가 다른 3종의 Ag powder를 선정하였다. Glass frit Sp가 $460^{\circ}C$ 이상의 경우에는 효율이 10% 미만이였으나 Sp $460^{\circ}C$ 이하에서는 16% 수준의 효율을 확인할 수 있었다.

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Quasi-Static and Dynamic Loading Responses of Ti-6Al-4V Titanium Alloy: Experiments and Constitutive Modeling

  • Suh, Yeong-Sung;Akhtar S. Khan
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2003.10a
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    • pp.191-194
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    • 2003
  • The results from a systematic study of the response of a Ti-6Al-4V alloy under quasi-static and dynamic loading at different strain rates and temperatures are presented. It has been shown that the work-hardening rate decreased as the strain rate and the strain increased. The correlations and predictions using modified KHL (Khan-Huang-Liang) viscoplastic constitutive model are compared with those from JC (Johnson-Cook) model and experimental observations. Overall, KHL model correlations and predictions compared much more favorably than the corresponding JC model predictions and correlations.

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Fabrication of Pb Free Solder Glass for Electronic Packaging Application (전자 패키징용 Pb Free 저융점 유리의 제조)

  • 최승철;이창식;유재륜;정경원
    • Journal of the Korean Ceramic Society
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    • v.38 no.7
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    • pp.628-633
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    • 2001
  • 전자 패키징에 적용 가능한 저융점 유리 중에서 납성분이 포함되어 있지 않는 Bi계 유리의 연구를 행하였다. 기판과의 일체화를 위한 유리의 응용으로, 소자와의 반응 억제와 열응력 완화를 위해 유리의 저융점화 및 열팽창계수를 제어하였다. 본 연구에서 제조된 Bi계 유리는 DTA와 TMA의 열분석을 통해 5$50^{\circ}C$ 부근에서 연화점이 있고, 열팽창계수는 7.52~12.09$\times$$10^{-6}$/$^{\circ}C$의 범위였으며, 비유전율은 9~13이었다. 본 연구의 납성분을 포함되어 있지 않는 유리조성은 우수한 내산성을 나타내었다.

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Modeling of Coking Process in a Coke Oven (코크스 공정에서의 열유동 현상 모델링)

  • Yang, Kwang-Heok;Yang, Won;Choi, Sang-Min
    • Proceedings of the KSME Conference
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    • 2004.11a
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    • pp.1184-1189
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    • 2004
  • Coking process is the thermal decomposition of bituminous coal with final temperature of about $900^{\circ}C$ Because coke plays important roles in ironmaking process in a blast furnace it's essential for developing modeling of coke oven. In this study, An unsteady 2-dimesional model is proposed to simulate coking process in a coke oven. In this model, gas and solid phase are assumed homogeneous continnum and solid bed is assumed as porous media . The model contains governing equations for the solid phase and the gas phase. Complicated phenomena such as swelling, softening, resolidification and shrinkage are neglected and mass loss by drying and devolatilization is reflected by generation of internal pores. Drying, devolatilization, heat transfer and generation of internal pores are also reflected in source terms. Calulated results are compared with experimental data

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Analysis of Overlapping Heat Zones in Laser-Assisted Machining (레이저보조가공에서 중첩열원에 관한 해석 연구)

  • Baek, Jong-Tae;Lee, Choon-Man
    • Journal of the Korean Society for Precision Engineering
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    • v.32 no.12
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    • pp.1023-1029
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    • 2015
  • Laser-assisted machining (LAM) is one of the most effective methods for enhancing the machinability of difficult-to-cut materials, such as titanium alloys and various ceramics, and has been studied by many researchers. LAM is a method that facilitates machining by softening a workpiece using a laser heat source. The advantages of the LAM process are decreases in tool wear, cutting force, and surface roughness. However, when the material is over-heated, melting or burning can occur. This study analyzed the heat source distribution with regard to overlapping of preheating on the laser heating path with an acute angle, a right angle and obtuse angles. Then, a power reduction method was proposed to reduce the melting and burning of the workpiece.

The structure and properties of $50SnO_2-(50-x)P_2O_5-xB_2O_3$ for component materials of PDP

  • An, Yong-Tae;Choi, Byung-Hyun;Ji, Mi-Jung;Ko, Young-Soo;Kim, Hyung-Sun
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.359-361
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    • 2008
  • Glasses in the $SnO_2-(50-x)P_2O_5-xB_2O_3$ system were examined as potential replacement for the PbO glass frits with low firing temperature for component materials of a plasma display panel. The glasses were evaluated for their structural and the thermal expansion coefficient, glass transition and glass softening temperatures and Vickers hardness as a function of the $B_2O_3$ content.

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The Study on Texture-Softening of Tentatively Thermal Processed Orange Sac (Orange Sac 1차 가공품의 조직연화에 관한 연구)

  • 장재권
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.27 no.4
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    • pp.653-658
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    • 1998
  • In order to provide orange sac for off-season processing of sac-suspended orange juice, orange was treatee into intermediate production of orange sac and segment, stored at 2$0^{\circ}C$ during 3 months for assessment of sac-quality providing various processing conditions. Lowering the pH of syrup and sterilization temperature reduced the deterioration of sac quality in terms of intensity and destruction of sac. Sugar content of syrup had little relation with intensity of orange sac at pH 6.5, whereas in the range of pH 3.0~3.8, the increase of sugar content increased intensity of sac. The storage of segment form maintained better quality than that of sac form. The absorbance of syrup was linearly inverse to sac intensity. The deterioration of sac quality may be related to effulence of some materails in sac. Sac product sterilized at below $65^{\circ}C$ had possibility to be contaminated by microbes.

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Layered model of aging concrete. General concept and one-dimensional applications

  • Truty, Andrzej;Szarlinski, Jan;Podles, Krzysztof
    • Computers and Concrete
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    • v.17 no.6
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    • pp.703-721
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    • 2016
  • A novel approach to modeling concrete behavior at the stage of its maturing is presented in this paper. This approach assumes that at any point in the structure, concrete is composed of a set of layers that are activated in time layer by layer, based on amount of released heat that is produced during process of the concrete's maturing. This allows one to assume that each newly created layer has nominal stiffness moduli and tensile/compressive strengths. Hence introduction of explicit stiffness moduli and tensile/compressive strength dependencies on time, or equivalent time state parameter, is not needed. Analysis of plain concrete (PC) and reinforced concrete (RC) structures, especially massive ones, subjected to any kind of straining in their early stage of existence, mostly due to external loads but especially by thermal loading and shrinkage, is the goal of the approach. In this article a simple elasto-plastic softening model with creep is used for each layer and a general layered model behavior is illustrated on one-dimensional (1D) examples.