• Title/Summary/Keyword: thermal runaway

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Thermal Resistant Characteristics of Accelerated Flowable Backfill Materials on Water Content (함수비에 따른 유동성 뒤채움재의 열저항 특성)

  • Oh, Gi-Dae;Kim, Dae-Hong
    • Proceedings of the Korean Geotechical Society Conference
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    • 2010.09a
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    • pp.1258-1263
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    • 2010
  • Backfill material of buried electrical transmission cable should dissipate the heat as rapidly as it is generated, or high temperatures will lead thermal runaway. These problems could raise thermal resistance and recude trasmission efficiency. So Backfill material of buried electrical transmission cable should have not only structual safty but good thermal property. So, in this study, we performed thermal resistancy test for various materials such as sand, weathered soil, clay and mixed soil to analyze the thermal characteristics of CLSM(controlled low strength materials) for water content.

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Thermal Hazards of Polystyrene Polymerization Process by Bulk Polymerization (벌크 중합법에 의한 폴리스티렌 중합공정의 열적위험성)

  • Han, In-Soo;Lee, Jung-Suk;Lee, Keun-Won
    • Journal of the Korean Institute of Gas
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    • v.17 no.4
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    • pp.1-8
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    • 2013
  • The aim of this study is to assess thermal hazards of polystyrene polymerization process by bulk polymerization with accelerating rate calorimeter(ARC) and Multimax reactor system(MM). From this study, we found out that the polymerization process should be operated at reaction temperature of $120^{\circ}C{\sim}130^{\circ}C$. At reaction temperature over $130^{\circ}C$, there was a runaway reaction hazard due to the temperature control failure following a viscosity increase of reaction products. With a cooling failure of a reactor in the early stage of process operation at the reaction temperature ($120^{\circ}C{\sim}130^{\circ}C$), there was a high thermal hazard of burst of a reactor's rupture disk or explosion of a reactor caused by the rapid rise of temperature and pressure to $340^{\circ}C$, 5.3 bar respectively within 30 - 50 minutes.

A study on the improvement of the thermal properties of ZnO arrester blocks (산화아연 피뢰기 소자의 열적 특성 향상을 위한 연구)

  • Kim, Dong-Seong;Lee, Su-Bong;Lee, Seung-Ju;Kim, Dong-Kyu;Yang, Soon-Man;Lee, Bok-Hee
    • Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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    • 2009.10a
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    • pp.335-338
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    • 2009
  • In this study, in order to investigate the thermal and electrical properties of ZnO arrester block against 60[Hz] AC voltage, the changes in leakage current were measured. The temperature distribution appearing on the ZnO arrester blocks was observed using a forward looking infrared camera. In particular, the correlation between the thermal and electrical properties of a ZnO arrester block was analyzed experimentally. From this analysis, the thermal phenomena resulting from the heat generation and dissipation of the ZnO arrester block were interpreted. The degradation and thermal runaway phenomena of ZnO arrester block are closely related to the temperature limit of the ZnO arrester block. The installation of an additional metal electrode has resulted in the decrease of the leakage current due to the heat dissipation.

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An Evaluation of Thermal Stability of Raw Materials in the Vinyl Acetate Polymerization Process (비닐아세테이트 중합공정에서 원료물질의 열적 안정성 평가)

  • Lee, Keun-Won;Han, In-Soo;Lee, Jung-Suk
    • Journal of the Korean Society of Safety
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    • v.25 no.3
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    • pp.61-65
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    • 2010
  • Most of the chemical reactions performed in the chemical industry are exothermic, meaning that thermal energy is released during the reaction. It is also important to understand the thermal hazards such as thermal stabilities and runaway reactions, which are governed by thermodynamics and reaction kinetics of the mixed materials. The paper was described the evaluation of thermal behavior caused by an exothermic batch process in manufacture of the vinyl acetate resin. The aim of the study was to evaluate the thermal stabilities of raw materials with operating conditions such as a reaction inhibitor, heating rate, reaction atmosphere and the mount of methanol charged in the vinyl acetate polymerization process. The experiments were performed in the differential scanning calorimeter(DSC), C 80 calorimeter, and thermal screening unit($TS^u$). It was suggested that we should provide the thermal characteristics for raw materials to present safe precautions with operating conditions in the vinyl acetate polymerization process.

Development of numerical model for estimating thermal environment of underground power conduit considering characteristics of backfill materials (되메움재 특성을 고려한 전력구 열환경 변화 예측 수치해석모델 개발)

  • Kim, Gyeonghun;Park, Sangwoo;Kim, Min-Ju;Lee, Dae-Soo;Choi, Hangseok
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.19 no.2
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    • pp.121-141
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    • 2017
  • The thermal analysis of an underground power conduit for electrical cables is essential to determine their current capacity with an increasing number of demands for high-voltage underground cables. The temperature rises around a buried cable, caused by excessive heat dissipation, may increase considerably the thermal resistance of the cables, leading to the danger of "thermal runaway" or damaging to insulators. It is a key design factor to develop the mechanism on thermal behavior of backfilling materials for underground power conduits. With a full-scale field test, a numerical model was developed to estimate the temperature change as well as the thermal resistance existing between an underground power conduit and backfill materials. In comparison with the field test, the numerical model for analyzing thermal behavior depending on density, moisture content and soil constituents is verified by the one-year-long field measurement.

Thermal Characteristics Simulation with Detecting Temperature for the Wearable Nylon-Yarn NOx Gas Sensors (웨어러블용 Nylon-Yarn NOx 가스 센서의 검출 온도 변화에 따른 열 특성 시뮬레이션)

  • Jang, Kyung-Uk
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.33 no.4
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    • pp.321-325
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    • 2020
  • Atmospheric environmental problems have a major impact on human health and lifestyle. In humans, inhalation of nitrogen oxides causes respiratory diseases, such as bronchitis. In this paper, thermal analysis of a gas sensor was carried out to design and fabricate a wearable nylon-yarn gas sensor for the detection of NOx gas. In the thermal analysis method, the thermal diffusion process was analyzed while operating the sensors at 40 and 60℃ to secure a temperature range that does not cause thermal runaway due to temperature in the operating environment. Thermal diffusion analysis was performed using the COMSOL software. The thermal analysis results could be useful for analyzing gas adsorption and desorption, as well as the design of gas sensors. The thermal energy diffusion rate increased slightly from 10.05 to 10.1 K/mm as the sensor temperature increased from 40 to 60℃. It was concluded that the sensor could be operated in this temperature range without thermal breakdown.

Surface modified ceramic fiber separators for thermal batteries

  • Cheong, Hae-Won;Ha, Sang-Hyeon;Choi, Yu-Song
    • Journal of Ceramic Processing Research
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    • v.13 no.spc2
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    • pp.308-311
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    • 2012
  • A wide range of possible hazards existing in thermal batteries are mainly caused by thermal runaway, which results in overheating or explosion in extreme case. Battery separators ensure the separation between two electrodes and the retention of ion-conductive electrolytes. Thermal runaways in thermal batteries can be significantly reduced by the adoption of these separators. The high operating temperature and the violent reactivity in thermal batteries, however, have limited the introduction of conventional separators. As a substitute for separators, MgO powders have been mostly used as a binder to hold molten salt electrolyte. During recent decades the fabrication technology of ceramic fiber, which has excellent mechanical strength and chemical stability, has undergone significant improvement. In this study we adopted wet-laid nonwoven paper making method instead of the electrospinning method which is costly and troublesome to produce in volume. Polymeric precursor can readily be coated on the surface of wet-laid ceramic paper, and be formed into ceramic film after heat treatment. The mechanical strength and the thermo-chemical stability as well as the wetting behaviors of ceramic separators with various molten salts were investigated to be applicable to thermal batteries. Due to their excellent chemical, mechanical, and electrical properties, wet-laid nonwoven separators made from ceramic fibers have revealed positive possibility as new separators for thermal batteries which operate at high temperature with no conspicuous sign of a short circuit and corrosion.

Thermal Resistivity Measurement of Recycled Aggregates and Comparison with Conventional Prediction Model (송배전관로 되메움용 순환골재의 열저항 측정 및 기존 열저항 예측 모델과의 비교)

  • Wi, Jihae;Hong, Sungyun;Choi, Hangseok
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.199.1-199.1
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    • 2010
  • Use of recycled aggregates that are constituents of concrete or asphalt-based structures has become popular because the recycling is an eco-friendly way to overcome the depletion of natural aggregates. In order to adopt the recycled aggregates for backfilling a power transmission pipeline trench, their thermal resistivity should be low enough to prevent thermal runaway in the transmission system. In this study, a series of laboratory tests with QTM-500 and KD2 Pro was performed to measure the thermal resistivity of recycled aggregates prepared from various sources. Relationships between the thermal resistivity of recycled aggregates and the water content have been obtained with consideration of compaction effort. Similar to natural soils, the thermal resistivity of the recycled aggregates decreases with increasing the water content. In addition, this study compared the experimental data with conventional prediction models for the thermal resistivity in the literature, which suggests the availability of the recycled aggregates as backfill material substituting for natural aggregates when backfilling the power transmission pipeline trench.

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Optimization of the Backfill Materials for Underground Power Cables considering Thermal Resistivity Characteristics (II) (열저항 특성을 고려한 지중송전관로 되메움재의 최적화(II))

  • Kim, You-Seong;Cho, Dae-Seong;Park, Young-Jun
    • Journal of the Korean Geosynthetics Society
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    • v.10 no.4
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    • pp.123-130
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    • 2011
  • In the precedent study it was presented that the comparison of thermal resistivity using various backfill materials including river sand regarding water content, dry unit weight and particle size distribution. Based on the precedent study, this study focused on developing the optimized backfill material that would improve the power transfer capability and minimize the thermal runaway due to an increase of power transmission capacity of underground power cables. When raw materials, such as river sand, recycled sand, crush rock and stone powder, are used for a backfill material, they has not efficient thermal resistivity around underground power cables. Thus, laboratory tests are performed by mixing Fly-ash, slag and floc with them, and then it is found that the optimized backfill material are required proper water content and maximum density. Through various experimental test, when coarse material, crush rock, is mixed with recycled sand, stone powder, slag or floc for a dense material, the thermal resistivity of it has $50^{\circ}C$-cm/Watt at optimum moisture content, and the increase of thermal resistivity does not happen in dry condition. The result of experiments approach the optimization of the backfill materials for underground power cables.

A Study on the Thermal Decomposition Characteristics of Intermediate of Saccharin (삭카린 중간체의 열분해 특성에 관한 연구)

  • 김관응;김영수;신창섭
    • Journal of the Korean Society of Safety
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    • v.13 no.4
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    • pp.180-185
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    • 1998
  • The evaluation of thermal and pressure hazard of chemicals on the manufacturing, transporting and storaging is important in the chemical industry for safety. In this study, the thermal decomposition characteristics of intermediate of Saccharin were investigated by using Accelerating Rate Calorimeter(ARC) and Differential Scanning Calorimeter(DSC). Experimental results showed that decomposition temperatures in p-TSA were about 280~$318^{\circ}C$ by DSC and $201^{\circ}C$ by ARC. In case of o-TSA were about $336^{\circ}C$~$360.8^{\circ}C$ by DSC and $299^{\circ}C$ by ARC. The decomposition temperature acquired by ARC was about $70^{\circ}C$ lower than that by DSC. The exothermic runaway reaction in case of p-TSA occured in 598 minute and o-TSA in 5 minute. For the safety in the chemical industry, we should consider the ARC data as well as DSC data in the handling and design of process.

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